Ground-based remote sensing of O3 by high- and medium-resolution FTIR spectrometers over the Mexico City basin
Abstract. We present atmospheric ozone (O3) profiles measured over central Mexico between November 2012 and February 2014 from two different ground-based FTIR (Fourier transform infrared) solar absorption experiments. The first instrument offers very high-resolution spectra and contributes to NDACC (Network for the Detection of Atmospheric Composition Change). It is located at a mountain observatory about 1700 m above the Mexico City basin. The second instrument has a medium spectral resolution and is located inside Mexico City at a horizontal distance of about 60 km from the mountain observatory. It is documented that the retrieval with the high- and medium-resolution experiments provides O3 variations for four and three independent atmospheric altitude ranges, respectively, and the theoretically estimated errors of these profile data are mostly within 10 %. The good quality of the data is empirically demonstrated above the tropopause by intercomparing the two FTIR O3 data, and for the boundary layer by comparing the Mexico City FTIR O3 data with in situ O3 surface data. Furthermore, we develop a combined boundary layer O3 remote sensing product that uses the retrieval results of both FTIR experiments, and we use theoretical and empirical evaluations to document the improvements that can be achieved by such a combination.
