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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0"><?xmltex \makeatother\@nolinetrue\makeatletter?>
  <front>
    <journal-meta><journal-id journal-id-type="publisher">AMT</journal-id><journal-title-group>
    <journal-title>Atmospheric Measurement Techniques</journal-title>
    <abbrev-journal-title abbrev-type="publisher">AMT</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Atmos. Meas. Tech.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1867-8548</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/amt-12-977-2019</article-id><title-group><article-title>Trend quality ozone from NPP OMPS: the version 2 processing</article-title><alt-title>Trend quality ozone from NPP OMPS: the version 2 processing</alt-title>
      </title-group><?xmltex \runningtitle{Trend quality ozone from NPP OMPS: the version 2 processing}?><?xmltex \runningauthor{R. McPeters et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>McPeters</surname><given-names>Richard</given-names></name>
          <email>richard.d.mcpeters@nasa.gov</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Frith</surname><given-names>Stacey</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Kramarova</surname><given-names>Natalya</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-6083-8548</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Ziemke</surname><given-names>Jerry</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Labow</surname><given-names>Gordon</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>NASA Goddard Space Flight Center, Greenbelt, Maryland, USA</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Science Systems and Applications Inc., Lanham, Maryland, USA</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>GESTAR, Morgan State University, Baltimore, Maryland, USA</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Richard McPeters (richard.d.mcpeters@nasa.gov)</corresp></author-notes><pub-date><day>14</day><month>February</month><year>2019</year></pub-date>
      
      <volume>12</volume>
      <issue>2</issue>
      <fpage>977</fpage><lpage>985</lpage>
      <history>
        <date date-type="received"><day>27</day><month>June</month><year>2018</year></date>
           <date date-type="rev-request"><day>31</day><month>July</month><year>2018</year></date>
           <date date-type="rev-recd"><day>23</day><month>October</month><year>2018</year></date>
           <date date-type="accepted"><day>30</day><month>November</month><year>2018</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2019 Richard McPeters et al.</copyright-statement>
        <copyright-year>2019</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019.html">This article is available from https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019.html</self-uri><self-uri xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019.pdf">The full text article is available as a PDF file from https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019.pdf</self-uri>
      <abstract>
    <p id="d1e130">A version 2 processing of data from two ozone monitoring
instruments on Suomi NPP, the OMPS nadir ozone mapper and the OMPS nadir
ozone profiler, has now been completed. The previously released data were
useful for many purposes but were not suitable for use in ozone trend
analysis. In this processing, instrument artifacts have been identified and
corrected, an improved scattered light correction and wavelength registration
have been applied, and soft calibration techniques were implemented to
produce a calibration consistent with data from the series of SBUV/2
instruments. The result is a high-quality ozone time series suitable for
trend analysis. Total column ozone data from the OMPS nadir mapper now agree
with data from the SBUV/2 instrument on NOAA 19 with a zonal average bias of
<inline-formula><mml:math id="M1" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula> % over the 60<inline-formula><mml:math id="M2" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S to 60<inline-formula><mml:math id="M3" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N latitude zone.
Differences are somewhat larger between OMPS nadir profiler and N19 total
column ozone, with an average difference of <inline-formula><mml:math id="M4" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula> % over the 60<inline-formula><mml:math id="M5" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S to 60<inline-formula><mml:math id="M6" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N latitude zone and a residual seasonal variation of about
2 % at latitudes higher than about 50<inline-formula><mml:math id="M7" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. For the profile retrieval,
zonal average ozone in the upper stratosphere (between 2.5 and 4 hPa) agrees
with that from NOAA 19 within <inline-formula><mml:math id="M8" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula> % and an average bias of <inline-formula><mml:math id="M9" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula> %.
In the lower stratosphere (between 25 and 40 hPa) agreement is within <inline-formula><mml:math id="M10" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula> % with an average bias of <inline-formula><mml:math id="M11" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula> %. Tropospheric ozone produced by
subtracting stratospheric ozone measured by the OMPS limb profiler from total
column ozone measured by the nadir mapper is consistent with tropospheric
ozone produced by subtracting stratospheric ozone from MLS from total ozone
from the OMI instrument on Aura. The agreement of tropospheric ozone is
within 10 % in most locations.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p id="d1e246">NASA has been measuring ozone from space since the launch of the Backscatter
Ultraviolet (BUV) instrument on Nimbus 4 in 1970. The series of follow-on
instruments, SBUV (Solar Backscatter Ultraviolet) and TOMS (Total Ozone
Mapping Spectrometer) on Nimbus 7 and SBUV/2 instruments on NOAA 9, 11, 14,
16, 17, 18, and 19 produced a long-term time series of global ozone
observations. Under NASA's MEaSUREs (Making Earth System data records for
Use in Research Environments) program, data from this series of instruments
were re-processed to create a coherent ozone time series. Inter-instrument
comparisons during periods of overlap as well as comparisons with data from
other satellite- and ground-based instruments were used to evaluate the
consistency of the record and make careful calibration adjustments as needed
(McPeters et al., 2013). The result is an ozone data record suitable for
trend studies that we designated the Merged Ozone Data (MOD) time series
(Frith et al., 2014). Ozone instruments on the Suomi NPP spacecraft and the
planned series of JPSS (Joint Polar Satellite System) spacecraft will now be
used to continue this series of measurements in order to document long-term
ozone change.</p>
      <p id="d1e249">The Suomi National Polar-orbiting Partnership (Suomi NPP) is a joint
NOAA–NASA mission that collects and distributes remotely sensed land, ocean,
and atmospheric data to the meteorological and global climate change
communities. Suomi NPP was launched 28 October 2011. The Ozone Mapper
Profiler Suite (OMPS) on NPP consists of three instruments – the ozone total
column
nadir mapper (NM), an instrument similar to the TOMS and OMI ozone
mapping instruments, the nadir profiler (NP), an instrument similar to the
SBUV and SBUV/2 profilers, and the limb profiler<?pagebreak page978?> (LP), an instrument that
measures the ozone vertical distribution using light scattered from the
Earth's limb. Details of the OMPS instruments and mission are given by Flynn
et al. (2006).</p>
      <p id="d1e252">The purpose of the version 2 processing of data from the two OMPS nadir
sensors, which is the subject of this paper, is to correct various
instrument artifacts and to apply an updated calibration that will be
consistent with data from earlier instruments. Only the reprocessed version
2 data from the two nadir instruments will be discussed here. While some
comparisons with data from the limb profiler will be shown in this paper,
detailed LP validation results will be discussed in other papers.</p>
</sec>
<sec id="Ch1.S2">
  <title>The OMPS nadir mapper and nadir profiler</title>
      <p id="d1e261">The OMPS nadir mapper (NM) is a nadir-viewing, wide-swath,
ultraviolet–visible imaging spectrometer that provides daily global
measurements of the solar radiation backscattered by the Earth's atmosphere
and surface, along with measurements of the solar irradiance. It shares a
telescope with the OMPS nadir profiler (NP) spectrometer. A dichroic filter
splits light from the telescope into two streams. Most of the 310–380 nm
light is transmitted to the NM instrument, while most of the 250–300 nm
light is reflected to the NP instrument. The transition between reflection
and transmission occurs between 300 and 310 nm, the wavelength overlap
region. The detector for each instrument is a 340 pixel <inline-formula><mml:math id="M12" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 740 pixel CCD (charge-coupled device).
For more details on the instruments and sensors see Seftor
et al. (2013).</p>
      <p id="d1e271">Unlike the heritage TOMS instruments which measured ozone using a
photomultiplier detector at six discrete wavelengths (from 306 to 380 nm,
depending on the instrument), the NM instrument measures the complete
spectrum from 300 to 380 nm at an average spectral resolution of 1.1 nm. The
OMPS NM sensor has a 110<inline-formula><mml:math id="M13" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> cross-track field of view, with 35 discrete
cross-track bins. The 0.27 <inline-formula><mml:math id="M14" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m along-track slit width produces a 50 km
spatial resolution near nadir. An algorithm (Bhartia, 2007) uses the
radiance and irradiance measurements to infer total column ozone. As
illustrated in Fig. 1, the OMPS NM makes 400 individual scans per orbit
with 35 across-track measurements in each scan, which provides full global
coverage of the sunlit Earth every day. Resolution of a single FOV at nadir
is 50 km by 50 km, while the full swath width covers approximately 2000 km.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1"><caption><p id="d1e293">Each orbit of NM data measures a swath of total column ozone: 35
individual ozone measurements (see example near the Equator) are made for each
scan line.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f01.png"/>

      </fig>

      <p id="d1e302">The OMPS nadir profiler (NP) has a 16.6 <inline-formula><mml:math id="M15" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m cross-track slit and a
0.26 <inline-formula><mml:math id="M16" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m along-track slit width, producing a ground FOV cell size of
250 km by 250 km when exposed for a 38 s sample time. The OMPS NP
instrument makes 80 measurements per orbit, resulting in full global
coverage approximately every 6 days. The NP measures the complete spectrum
from 250 to 310 nm with a 1.1 nm bandpass. Because the NP itself only makes
measurements up to a maximum wavelength of 310 nm, the longer wavelengths
that are needed in the retrievals at high latitudes must be taken by
averaging the overlap cells from the NM instrument, the five central cross-track cells in five along-track scans.</p>
</sec>
<sec id="Ch1.S3">
  <title>The version 2 processing</title>
      <p id="d1e327">The goal of the version 2 processing is to produce ozone data sufficiently
accurate to be used to continue the Merged Ozone Data (MOD) time series.
This time series is a unified multi-instrument ozone data set created by
merging data from a series of SBUV and SBUV/2 instruments beginning with the
original BUV instrument launched on Nimbus 4 in 1970 and extending to the
SBUV/2 instrument on NOAA 19, which continues to operate. Data from these
instruments were recently reprocessed as version 8.6 with a consistent
calibration to create a coherent ozone time series (McPeters et al., 2013).
The MOD data set created from this series is described in detail by Frith et
al. (2014). Figure 2 shows the MOD fit to data from three recent SBUV/2
instruments, on NOAA 16, 18, and 19, for which good data are available
during the OMPS observation period. Comparison with ozone from ground
networks shows that total ozone in the MOD series is consistent to within
about a percent for the recent data. Data from the OMPS NP and NM
instruments will be used to extend this MOD data record.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><caption><p id="d1e332">OMPS ozone will be compared with MOD (merged ozone data) ozone
created by merging data from recent SBUV/2 instruments. Monthly average
ozone for 60<inline-formula><mml:math id="M17" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S–60<inline-formula><mml:math id="M18" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N is plotted.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f02.png"/>

      </fig>

      <p id="d1e359">In the version 2 processing we use the latest version of the Level 1 data,
the data set of
calibrated radiance measurements from NM and NP that
implements a refined calibration for both instruments (Seftor et al., 2014)
and corrects for<?pagebreak page979?> several instrument effects. Both the NM and NP L1b data now
use an improved set of calibration coefficients that exhibit smoother
wavelength-to-wavelength behavior and provide a wavelength registration that
accounts for intra-orbital (for the NM) and intra-seasonal (for the NP)
shifts that were identified in analysis of the data. A small bandpass error
in the NP instrument near 295 nm was corrected, and errors in the pre-launch
calibration measurements in the dichroic transition region (300–310 nm)
for both instruments were identified and corrected. The daily dark current
correction has been refined for each instrument.</p>
      <p id="d1e362">Soft (in orbit) calibration techniques were used to refine the instrument
calibration. The NM pre-launch calibration of the 331 nm channel, which is
used to determine reflectivity, was not adjusted at nadir since the measured
radiance over ice matched the expected radiance (determined from other
instruments such as Earth Probe TOMS and OMI) to within 1 %. Cross-track
adjustments to this channel to “flatten” the 331 nm reflectivity calculation
over ice were then determined and applied. Similarly, the nadir radiance at
317 nm, which is the channel used to determine ozone, was not changed; the
off-nadir radiances were then adjusted to take out any cross-track ozone
dependence. The 317 and 331 nm NM nadir radiances are also used in the NP
algorithm retrieval, with no adjustments applied. For the NM radiances at
312 nm, which are used in the NP algorithm but not in the NM algorithm, an
adjustment was determined and applied to minimize the final retrieval
residuals. Similarly, the NP 306 nm radiances were adjusted to minimize the
final residuals. The calibrations were not explicitly adjusted to agree with
the NOAA 19 SBUV/2 calibration, so NOAA 19 comparisons can be used for
validation.</p>
      <p id="d1e366">The algorithm used to retrieve total column ozone from the NM is very
similar to the v8.5 algorithm used in the processing of data from Aura OMI
instrument as described by Bhartia (2007) and Bhartia et al. (2004). The
basic algorithm uses two wavelengths to derive total column ozone, one
wavelength with weak ozone absorption (331 nm) to characterize the
underlying surface and clouds, and the other at a wavelength with strong
ozone absorption (317 nm). The ozone retrieval algorithms for both the NP
and NM instruments now use the Brion–Daumont–Malicet ozone cross sections
(Brion et al., 1993) to be consistent with other data sets in the MOD time
series.</p>
      <p id="d1e369">The NP retrieval algorithm uses 12 discrete wavelengths to retrieve ozone
profiles employing Rodgers' optimal estimation technique (Bhartia et al.,
2013). It is very similar to the v8.6 algorithm used to reprocess the SBUV
and SBUV/2 data sets (McPeters et al., 2013) used in the MOD time series.
While the vertical resolution of an OMPS NP ozone retrieval is somewhat
coarse in comparison with the LP sensor, about 8 km resolution in the
stratosphere, NP provides valuable data for the continuation of the
historical SBUV/2 ozone data record, and for validation of the OMPS LP
retrievals.</p>
</sec>
<sec id="Ch1.S4">
  <title>Total column ozone comparisons</title>
      <p id="d1e378">The accuracy and stability of the OMPS ozone data record has been evaluated
through comparisons with ground-based observations and comparisons with
other satellite data sets. The worldwide network of Dobson and Brewer
stations has been used for years for ground-based validation of total column
ozone. For satellite validation of total ozone, comparisons with the MOD
data set are used as a primary standard for this evaluation. Validation of
profile ozone (in Sect. 5) will use data from balloon sondes, data from
the currently operating SBUV/2 instrument on NOAA 19, and data from the
microwave limb sounder (MLS) on the Aura spacecraft.</p>
      <p id="d1e381">Figure 3 compares average ozone from 52 ground-based Brewer and Dobson
stations in the Northern Hemisphere with coincident observations of ozone
measured by the NM instrument over the individual stations (Labow et al.,
2013). Comparison with ozone from the NOAA 19 SBUV/2 is also shown (in blue)
since these data are the basis of much of the NM and NP validation. Northern
Hemisphere comparisons are shown because the network density is much better
in the Northern Hemisphere than in the Southern Hemisphere, and comparisons in a single
hemisphere will illuminate any seasonally dependent errors. Such comparisons
have been shown to be capable of detecting instrument changes over the long term
of a few tenths of a percent (McPeters et al., 2008). The comparison covers
the period from April 2012 through the end of 2016. Figure 3 shows that the
agreement of NM total ozone is mostly within half a percent. The linear fit
in Fig. 3 shows that OMPS NM has very little drift in ozone relative to
the ground observations (0.8 % per decade) and an average bias of less
than 0.2 %.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><caption><p id="d1e386">A comparison of OMPS NM ozone (in black) and NOAA 19 SBUV (in
blue) with average ozone from an ensemble of 52 Northern Hemisphere Dobson
and Brewer stations. A linear fit to the NM data is also shown. Weekly mean
percent difference of satellite ozone minus ground-based ozone is plotted.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f03.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><caption><p id="d1e398">For average ozone in the 60<inline-formula><mml:math id="M19" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S–60<inline-formula><mml:math id="M20" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N
latitude zone <bold>(b)</bold>, the average bias of NM ozone relative to MOD
<bold>(a)</bold> was reduced from 0.99 % in version 1 to <inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.20</mml:mn></mml:mrow></mml:math></inline-formula> % in the
version 2 processing.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f04.png"/>

      </fig>

      <?pagebreak page980?><p id="d1e441">The comparison of ozone from the NM instrument with ozone from the MOD
(merged ozone data set) time series shown in Fig. 4 illustrates the
improved accuracy of the version 2 processing. The monthly zonal average
ozone, area weighted for the latitude zone from 60<inline-formula><mml:math id="M22" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S to
60<inline-formula><mml:math id="M23" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, is plotted. Because ozone is derived from measurements of
backscattered sunlight, data are not always available in winter months at
latitudes above 60<inline-formula><mml:math id="M24" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. MOD ozone for this time period is based on
combining ozone from SBUV/2 instruments on three satellites: NOAA 16, 18,
and 19. For the period from March 2014 to 2017 only the instrument on NOAA
19 was operational. Figure 4b shows the NM monthly average
ozone for the old version 1 processing (dashed red curve) and the new
version 2 processing (solid blue curve) along with MOD average ozone (orange
curve). Figure 4a shows the percent difference of version 1 and
version 2 ozone from MOD ozone. While in version 1 NM ozone was on average
1 % higher relative to MOD, in the version 2 processing it is 0.2 % lower.
There is a small relative trend between NM and MOD of 0.8 % per decade.
This relative trend could be due to either NM or to an aging NOAA 19 SBUV/2
instrument in a drifting orbit. Further comparisons will be needed to
distinguish between the two possibilities.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><caption><p id="d1e473">A similar plot for the OMPS nadir profiler shows that the large
bias in the released version 1 data is reduced in the version 2 processing.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f05.png"/>

      </fig>

      <p id="d1e482">Figure 5 is the same plot but for total column ozone measured by the NP
instrument. NP total column ozone is derived by integrating the retrieved
ozone profiles. In principle, this should be more accurate over a broad
range of solar zenith angles than ozone derived from the limited wavelength
range of the NM instrument. Here the average relative bias of about
<inline-formula><mml:math id="M25" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.4</mml:mn></mml:mrow></mml:math></inline-formula> % in version 1 is reduced to <inline-formula><mml:math id="M26" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.05</mml:mn></mml:mrow></mml:math></inline-formula> % in version 2. This bias
disagreement between NM and NP means that there is a small inconsistency
between the two instruments that has not been resolved. This issue of the
relative calibration inconsistency is being studied. There is a relative
drift of NP ozone relative to MOD that is similar to that for the NM
instrument, of 0.5 % per decade. To the extent that the NP and NM
instruments have independent calibrations, this suggests that the small
relative drift is due to the NOAA 19 SBUV/2 instrument calibration and the
effect of the drifting orbit.</p>
      <p id="d1e505">Figure 6 shows the latitude dependence relative to MOD of the version 2
ozone from the mapper and from the profiler. Figure 6b plots ozone
averaged for five Marches from 2013 through 2016, while Fig. 6a
shows the percent difference from MOD for the same months. The latitude
dependence of ozone varies by season so it is useful to examine individual
months, and latitude coverage is maximum near an equinox. The NM instrument
has very little latitude dependence except at the highest southern latitudes
where ozone is<?pagebreak page981?> low. The NP instrument has the bias as noted in Fig. 5 and
likewise has little latitude dependence at low to midlatitudes. The higher
ozone (by 2 % to 3 %) for retrievals at latitudes greater than
50<inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> may be a solar zenith angle dependent manifestation of what is
possibly an NP calibration error.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6"><caption><p id="d1e520">In version 2 the 4-year average of March ozone latitude
dependence (2013–2016) is shown in <bold>(b)</bold> for the mapper (dashed
blue curve) and for the profiler (solid red curve). Percent differences from
MOD are shown in <bold>(a)</bold>.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f06.png"/>

      </fig>

</sec>
<sec id="Ch1.S5">
  <title>Ozone profile comparisons</title>
      <p id="d1e542">The long-term behavior of ozone as a function of altitude is in some ways
more interesting than the behavior of total column ozone because it can be
used to confirm the accuracy of various model predictions. However, the
accuracy of these measurements is more difficult to validate (Hassler et
al., 2014). Data from the ozone sonde network can be used to validate the
profile in the troposphere and lower stratosphere, while satellite data can
be used to validate the middle to upper stratospheric results. There are
ground-based measurements of the ozone vertical distribution by lidar and by
microwave sounders, but such measurements are very sparse. There are
<italic>Umkehr</italic>
measurements by Dobson and Brewer instruments, but vertical resolution is
coarse and uncertainty is high, especially when aerosols are present.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7"><caption><p id="d1e550">An average of ozone sonde data from Hilo, Hawaii, is compared with
OMPS NP version 2 ozone profiles for coincident days, with percent difference
plotted in <bold>(b)</bold>. The NP profile integrates to 274.1 DU, while the
sonde profile integrates to 272.5 DU when a climatological stratospheric
amount is added.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f07.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8"><caption><p id="d1e564">The NP ozone anomaly, the difference from NOAA 19 ozone, for
midlatitudes
and low latitudes is shown as a function of time for total column ozone, the
lower stratosphere, and the upper stratosphere. Ozone from the version 1
processing (in red) and the version 2 processing (in green) is shown.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f08.png"/>

      </fig>

      <p id="d1e574">Looking at ground-based comparisons of ozone in the lower stratosphere
first, Fig. 7 compares NP ozone profiles with ozone measured by ECC ozone
sondes from one station, Hilo, Hawaii (20<inline-formula><mml:math id="M28" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 155<inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), a
subtropical station with a good time series of sonde launches. The sonde
data are from the SHADOZ network, under which the sonde data were reprocessed
to apply the most recent corrections (Witte et al., 2016). For this figure,
all 33 of the sondes launched in 2016 were averaged. The coincident profiles
measured by NP were usually within 1<inline-formula><mml:math id="M30" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> of latitude and within 15<inline-formula><mml:math id="M31" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> of longitude. The comparison shows that in the lower stratosphere NP
agrees with sonde data to within <inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> %. Only altitudes between 10
and 50 hPa (approximately 20 to 32 km) are shown because the SBUV nadir
ozone retrieval algorithm produces little profile information on the
distribution of ozone below 20 km. But it should be noted that the column
amount of ozone in the troposphere is retrieved accurately (Bhartia et al.,
2013), as evidenced by the fact that total column ozone from an SBUV
retrieval is accurate to 1 % or better (McPeters et al.,<?pagebreak page982?> 2013). This
accuracy is critical to the derivation of tropospheric ozone discussed in
Sect. 6.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9"><caption><p id="d1e625">OMPS NP version 2 June zonal average ozone profiles (2012–2016) compared
with NOAA 19 SBUV/2 profiles, MLS profiles, and profiles from the OMPS LP.
OMPS NP version 2 percent differences from N19, MLS, and LP are plotted on the
right.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f09.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F10"><caption><p id="d1e636">The time dependence of the version 2 ozone anomaly relative to NOAA 19
shown for low to midlatitudes.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f10.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F11"><caption><p id="d1e647">The time dependence of the version 2.0 ozone anomaly relative to NOAA 19
shown for high latitudes.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f11.png"/>

      </fig>

      <p id="d1e657">For the middle to upper stratosphere, monthly zonal mean comparison with
other satellite observations of the ozone vertical distribution is the best
approach for evaluating the accuracy of the version 2 NP results. Figure 8
shows the time-dependent difference of NP from the NOAA 19 SBUV/2 retrievals
averaged over low to middle latitudes (40<inline-formula><mml:math id="M33" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S to 40<inline-formula><mml:math id="M34" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N),
for the upper stratosphere (2.5–4 hPa), lower stratosphere (25–40 hPa),
and total column ozone. Comparing with N19 only rather than MOD gives a bit
more uniformity for the time-dependent profile comparison. In both the upper
stratosphere and lower stratosphere the version 2 ozone agrees with the N19
ozone to within about 1 %, where in the NP version 1 retrievals,
ozone was higher by 4 % and 6 % respectively. There is no evidence of a
significant time-dependent difference in total ozone, but in the middle
stratosphere there appears to be a small increase in ozone of about 2 %
over 6 years. There is the bias in total column ozone as noted earlier of a
bit over 1 %. While the use of NM wavelengths in the NP retrieval
may contribute to the bias, the bigger problem appears to be a wavelength-dependent calibration error in the NP itself. This possibility is being
studied.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F12" specific-use="star"><caption><p id="d1e680">The time series of tropospheric ozone shown for four locations.
Tropospheric ozone derived by subtracting OMPS LP stratospheric ozone from
NM total column ozone is shown in the blue solid curve, while tropospheric
ozone derived by subtracting MLS stratospheric ozone from OMI total column
ozone is shown in the dashed red curve.</p></caption>
        <?xmltex \igopts{width=355.659449pt}?><graphic xlink:href="https://amt.copernicus.org/articles/12/977/2019/amt-12-977-2019-f12.png"/>

      </fig>

      <p id="d1e689">Ozone agreement as a function of altitude is shown in Fig. 9 where ozone
in low to middle latitudes is averaged for five Junes from 2012 through
2016. Selecting a single month for this comparison allows us to see any
seasonal effect that might be suppressed in the annual average. As will be
shown later, there are seasonal variations in NP ozone at high latitudes.
The stratospheric ozone mixing ratio is plotted for OMPS NP version 2, for NOAA
19 SBUV/2, for the Aura microwave limb sounder (MLS) (Froidevaux et al., 2008),
and for the OMPS limb profiler (LP). The right panel shows the agreement of
the OMPS NP version 2 ozone profile with each of the three other profile
measurements by plotting the percent difference from each. Agreement is
almost always within <inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> %, which experience has shown to be fairly
good agreement for profile comparisons. While agreement in the upper
stratosphere and lower stratosphere shown in Fig. 8 was good, Fig. 9
shows that there is a significant underestimate of ozone relative to NOAA
19, MLS and LP in the 6 to 10 hPa region. This is likely the source of much
of the disagreement in total column ozone. It has been noted in other
comparisons (Hassler et al., 2014) that NOAA 19 ozone is<?pagebreak page983?> a bit high in the upper
stratosphere relative to MLS profiles, and a similar result is seen here for
the NP retrievals.</p>
      <p id="d1e702">The NP version 2 ozone has a somewhat different behavior at low to midlatitudes
than at high latitudes. The ozone anomaly, the percent difference of NP
ozone from the NOAA 19 SBUV ozone, is shown for low to midlatitudes
(<inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mi mathvariant="italic">&lt;</mml:mi><mml:mn mathvariant="normal">45</mml:mn></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M37" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>) in Fig. 10, and for higher latitudes
(<inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:mi mathvariant="italic">&gt;</mml:mi><mml:mn mathvariant="normal">45</mml:mn></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M39" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>) in Fig. 11. For each figure the anomaly is
shown for total column ozone (lower panel), for lower stratospheric ozone
(layer from 25 to 40 hPa) in the middle panel, and for upper
stratospheric ozone (layer from 2.5 to 4 hPa) in the upper panel. Figure 10 shows that version 2 ozone at latitudes below 45<inline-formula><mml:math id="M40" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> agrees well with
N19 ozone, while Fig. 11 shows that at latitudes at 50<inline-formula><mml:math id="M41" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> and
above ozone has a significant seasonal dependence that differs from that of
N19 with about 2 % to 4 % amplitude. This difference is likely another
manifestation of a possible NP calibration error. While this error is small,
we are working to resolve it in order to produce a better NP ozone product.</p>
</sec>
<sec id="Ch1.S6">
  <title>Tropospheric ozone from OMPS</title>
      <p id="d1e765">Ziemke et al. (2011, 2014, and references therein) have shown that
tropospheric ozone can be derived by subtracting stratospheric ozone from
total column ozone. This technique has most recently been applied by
subtracting stratospheric ozone measured by the Aura MLS instrument from
total column ozone measured by the Aura OMI instrument. The OMI/MLS
tropospheric ozone time series currently spans over 12 years and has been a
central data product for each of the BAMS State of the Climate Reports since
2013 and will be used in the upcoming international Tropospheric Ozone
Assessment Report.</p>
      <p id="d1e768">The OMPS ozone measurements can also be used to calculate tropospheric ozone
and continue the current OMI/MLS time series of measurements should either
of the Aura instruments fail. Because the OMPS instrument suite includes
both a total ozone mapper (NM) and a limb profiler (LP), a similar technique
can be applied as with OMI/MLS. Figure 12 shows the tropospheric ozone time
series for two locations in the tropics, Java and Brazil, and two locations
at northern midlatitudes, Beijing and Washington DC. In each case the red
dashed curve shows tropospheric ozone derived by subtracting MLS
stratospheric ozone from OMI total column ozone. For comparison, the blue
solid curve shows the same tropospheric ozone derived by subtracting
stratospheric ozone from the OMPS LP from total column ozone from the NM.
While there are some small differences the overall agreement is quite good.
Data on tropospheric ozone from the NP plus LP combination can be used to
continue the tropospheric ozone time series.</p>
</sec>
<?pagebreak page984?><sec id="Ch1.S7" sec-type="conclusions">
  <title>Conclusions</title>
      <p id="d1e777">The OMPS nadir mapper (NM) has proven to be a very stable instrument.
Comparison with a network of 52 Northern Hemisphere ground-based Dobson and
Brewer instruments shows very good agreement over the four years of
operation, agreeing within <inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula> % with near-zero trend. Total
column ozone from the OMPS nadir mapper agrees with MOD ozone and with NOAA
19 SBUV/2 ozone with a bias of <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula> % and a small time-dependent drift of
0.8 % per decade. It is possible that this time dependence could be due to
the aging NOAA 19 instrument and its drifting orbit.</p>
      <p id="d1e800">The nadir profiler (NP) has likewise been very stable. NP total column ozone
has a time dependence of only 0.5 % per decade relative to MOD or NOAA 19.
The bias of <inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula> % (60<inline-formula><mml:math id="M45" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S–60<inline-formula><mml:math id="M46" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N) is small but
inconsistent with ozone from NM. This bias seems to be generated in part by
the negative bias in the 6–10 hPa region. The calibration of the NP
instrument near 300 nm is being examined to understand this inconsistency.
NP ozone in the upper stratosphere (2.5–4 hPa) and in the lower
stratosphere (25–40 hPa) agrees well with ozone from NOAA 19 profiler,
with an average difference of <inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula> % and <inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula> % respectively at
latitudes below 50<inline-formula><mml:math id="M49" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. The retrievals for higher latitudes exhibit
a strong seasonal variation of about <inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula> %, both in layer ozone and
in total column ozone.</p>
      <p id="d1e871">Ozone data from these instruments can now be considered “trend quality” –
usable to extend the data record from previous instruments to create an
accurate time series. Data from NP at latitudes above 50<inline-formula><mml:math id="M51" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> appear
to be stable but must be used with a bit of caution because of its residual
seasonal variation and because the bias, while small, can be different than
at lower latitudes.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability">

      <p id="d1e887">NPP OMPS version
2 data are now available online from the Goddard
DISC: <uri>https://disc.gsfc.nasa.gov</uri> (last access: 13 February 2019). Data for the NM mapper and the NP profiler
are currently being converted to HDF5 format for inclusion in the DISC data
archive. The calibrated L1 data are also available from the Goddard DISC.
The OMPS NM ozone data are also available in ASCII form from our
site: <uri>https://acd-ext.gsfc.nasa.gov/anonftp/toms/</uri> (last access: 13 February 2019) in the
subdirectory omps_tc. Data from the NOAA 19 SBUV/2 can also
be found here under subdirectory sbuv. The v8.6 MOD data used as our
standard for comparison are available from
<uri>https://acdb-ext.gsfc.nasa.gov</uri> (last access: 13 February 2019):
click on “Data_services” and then on “Merged ozone data”.</p>
  </notes><notes notes-type="competinginterests">

      <p id="d1e902">The authors declare that they have no conflict of
interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e908">The OMPS nadir profiler and nadir mapper were built by Ball Brothers for
flight on the joint NASA–NOAA NPP satellite. We thank the many people who
have worked over the years to understand the behavior of the OMPS
instrument. The Ozone Processing Team has carefully maintained the
calibration of the nadir instruments through both hard and soft calibration
techniques.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: Diego Loyola<?xmltex \hack{\newline}?>
Reviewed by: two anonymous referees</p></ack><ref-list>
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    <!--<article-title-html>Trend quality ozone from NPP OMPS: the version 2 processing</article-title-html>
<abstract-html><p>A version 2 processing of data from two ozone monitoring
instruments on Suomi NPP, the OMPS nadir ozone mapper and the OMPS nadir
ozone profiler, has now been completed. The previously released data were
useful for many purposes but were not suitable for use in ozone trend
analysis. In this processing, instrument artifacts have been identified and
corrected, an improved scattered light correction and wavelength registration
have been applied, and soft calibration techniques were implemented to
produce a calibration consistent with data from the series of SBUV/2
instruments. The result is a high-quality ozone time series suitable for
trend analysis. Total column ozone data from the OMPS nadir mapper now agree
with data from the SBUV/2 instrument on NOAA 19 with a zonal average bias of
−0.2&thinsp;% over the 60°&thinsp;S to 60°&thinsp;N latitude zone.
Differences are somewhat larger between OMPS nadir profiler and N19 total
column ozone, with an average difference of −1.1&thinsp;% over the 60°&thinsp;S to 60°&thinsp;N latitude zone and a residual seasonal variation of about
2&thinsp;% at latitudes higher than about 50°. For the profile retrieval,
zonal average ozone in the upper stratosphere (between 2.5 and 4&thinsp;hPa) agrees
with that from NOAA 19 within ±3&thinsp;% and an average bias of −1.1&thinsp;%.
In the lower stratosphere (between 25 and 40&thinsp;hPa) agreement is within ±3&thinsp;% with an average bias of +1.1&thinsp;%. Tropospheric ozone produced by
subtracting stratospheric ozone measured by the OMPS limb profiler from total
column ozone measured by the nadir mapper is consistent with tropospheric
ozone produced by subtracting stratospheric ozone from MLS from total ozone
from the OMI instrument on Aura. The agreement of tropospheric ozone is
within 10&thinsp;% in most locations.</p></abstract-html>
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Seftor, C. J., Jaross, G., Kowitt, M., Haken, M., Li, J., and Flynn, L.,
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