Articles | Volume 3, issue 2
https://doi.org/10.5194/amt-3-387-2010
https://doi.org/10.5194/amt-3-387-2010
25 Mar 2010
 | 25 Mar 2010

First eddy covariance flux measurements by PTR-TOF

M. Müller, M. Graus, T. M. Ruuskanen, R. Schnitzhofer, I. Bamberger, L. Kaser, T. Titzmann, L. Hörtnagl, G. Wohlfahrt, T. Karl, and A. Hansel

Abstract. The recently developed PTR-TOF instrument was evaluated to measure methanol fluxes emitted from grass land using the eddy covariance method. The high time resolution of the PTR-TOF allowed storing full mass spectra up to m/z 315 with a frequency of 10 Hz. Three isobaric ions were found at a nominal mass of m/z 33 due to the high mass resolving power of the PTR-TOF. Only one of the three peaks contributed to eddy covariance fluxes. The exact mass of this peak agrees well with the exact mass of protonated methanol (m/z 33.0335). The eddy covariance methanol fluxes measured with PTR-TOF were compared to virtual disjunct eddy covariance methanol fluxes simultaneously measured with a conventional PTR-MS. The methanol fluxes from both instruments show excellent agreement.