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<front>
<journal-meta>
<journal-id journal-id-type="publisher">AMT</journal-id>
<journal-title-group>
<journal-title>Atmospheric Measurement Techniques</journal-title>
<abbrev-journal-title abbrev-type="publisher">AMT</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Meas. Tech.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1867-8548</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/amt-4-425-2011</article-id>
<title-group>
<article-title>A broadband optical cavity spectrometer for measuring weak near-ultraviolet absorption spectra of gases</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Chen</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Venables</surname>
<given-names>D. S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Chemistry Department, University College Cork, Cork, Ireland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Environmental Research Institute, University College Cork, Cork, Ireland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>01</day>
<month>03</month>
<year>2011</year>
</pub-date>
<volume>4</volume>
<issue>3</issue>
<fpage>425</fpage>
<lpage>436</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2011 J. Chen</copyright-statement>
<copyright-year>2011</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://amt.copernicus.org/articles/4/425/2011/amt-4-425-2011.html">This article is available from https://amt.copernicus.org/articles/4/425/2011/amt-4-425-2011.html</self-uri>
<self-uri xlink:href="https://amt.copernicus.org/articles/4/425/2011/amt-4-425-2011.pdf">The full text article is available as a PDF file from https://amt.copernicus.org/articles/4/425/2011/amt-4-425-2011.pdf</self-uri>
<abstract>
<p>Accurate absorption spectra of gases in the near–ultraviolet (300 to 400 nm)
are essential in atmospheric observations and laboratory studies. This
paper describes a novel incoherent broadband cavity-enhanced absorption
spectroscopy (IBBCEAS) instrument for measuring very weak absorption spectra
from 335 to 375 nm. The instrument performance was validated against the
&lt;sup&gt;3&lt;/sup&gt;B&lt;sub&gt;1&lt;/sub&gt;-X&lt;sup&gt;1&lt;/sup&gt;A&lt;sub&gt;1&lt;/sub&gt; transition of SO&lt;sub&gt;2&lt;/sub&gt;. The measured
absorption varied linearly with SO&lt;sub&gt;2&lt;/sub&gt; column density and the resulting
spectrum agrees well with published spectra. Using the instrument, we report
new absorption cross-sections of O&lt;sub&gt;3&lt;/sub&gt;, acetone, 2-butanone, and
2-pentanone in this spectral region, where literature data diverge
considerably. In the absorption minimum between the Huggins and Chappuis
bands, our absorption spectra fall at the lower range of reported ozone
absorption cross-sections. The spectra of the ketones agree with prior
spectra at moderate absorptions, but differ significantly at the limits of
other instruments&apos; sensitivity. The collision-induced absorption of the
O&lt;sub&gt;4&lt;/sub&gt; dimer at 360.5 nm was also measured and found to have a maximum
cross-section of ca. 4.0&amp;times;10&lt;sup&gt;&amp;minus;46&lt;/sup&gt; cm&lt;sup&gt;5&lt;/sup&gt; molecule&lt;sup&gt;−2&lt;/sup&gt;. We
demonstrate the application of the instrument to quantifying low
concentrations of the short-lived radical, BrO, in the presence of stronger
absorptions from Br&lt;sub&gt;2&lt;/sub&gt; and O&lt;sub&gt;3&lt;/sub&gt;.</p>
</abstract>
<counts><page-count count="12"/></counts>
</article-meta>
</front>
<body/>
<back>
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