Articles | Volume 7, issue 10
Atmos. Meas. Tech., 7, 3295–3305, 2014
Atmos. Meas. Tech., 7, 3295–3305, 2014

Research article 06 Oct 2014

Research article | 06 Oct 2014

Retrieval of tropospheric column-averaged CH4 mole fraction by solar absorption FTIR-spectrometry using N2O as a proxy

Z. Wang1, N. M. Deutscher1,2, T. Warneke1, J. Notholt1, B. Dils3, D. W. T. Griffith2, M. Schmidt4, M. Ramonet4, and C. Gerbig Z. Wang et al.
  • 1Institute of Environmental Physics, University of Bremen, Germany
  • 2School of Chemistry, University of Wollongong, Wollongong, Australia
  • 3Belgian Institute for Space Aeronomy, Brussels, Belgium
  • 4Laboratoire des Sciences du Climat et de l'Environnement (LSCE), Gif-Sur-Yvette, France

Abstract. Tropospheric column-averaged CH4 mole fractions were derived from ground-based column absorption measurements. The method uses stratospheric N2O columns to correct for the stratospheric contribution to the CH4 total column. The method was applied to four Total Carbon Column Observing Network (TCCON) sites covering locations from the Northern Arctic to the tropics. It performs well for all sites. The derived tropospheric CH4 concentrations were compared with profiles measured by aircraft at three sites. The results indicate an inter-site consistency within 6 ppb (~0.3%). With aircraft profiles up to 3 km, the seasonal behavior of the derived tropospheric CH4 concentration was also checked, revealing a difference of around 20 ppb. The mean relative uncertainty of the four sites, as estimated from the daily standard deviations, is 0.23%.