Articles | Volume 9, issue 3
Atmos. Meas. Tech., 9, 1025–1037, 2016
https://doi.org/10.5194/amt-9-1025-2016
Atmos. Meas. Tech., 9, 1025–1037, 2016
https://doi.org/10.5194/amt-9-1025-2016

Research article 14 Mar 2016

Research article | 14 Mar 2016

Size distribution of particle-associated polybrominated diphenyl ethers (PBDEs) and their implications for health

Yan Lyu1, Tingting Xu1, Xiang Li1, Tiantao Cheng1, Xin Yang1, Xiaomin Sun2, and Jianmin Chen1 Yan Lyu et al.
  • 1Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science & Engineering, Fudan University, Shanghai 200032, China
  • 2Environment Research Institute, Shandong University, Jinan 250100, China

Abstract. In order to better understand the size distribution of particle-associated PBDEs and their deposition pattern in the human respiratory tract, we carried out a 1-year campaign during 2012–2013 for the measurement of size-resolved particles at the urban site of Shanghai. The results showed that particulate PBDEs exhibited a bimodal distribution with a mode peak in the accumulation particle size range and the second mode peak in the coarse particle size ranges. As the number of bromine atoms in the molecule increases, accumulation-mode peak intensity increased while coarse-mode peak intensity decreased. This change was consistent with the variation of PBDEs' subcooled vapor pressure. Absorption and adsorption processes dominated the distribution of PBDEs among the different size particles. The evaluated deposition flux of Σ13 PBDEs was 26.8 pg h−1, in which coarse particles contributed most PBDEs in head and tracheobronchial regions, while fine-mode particles contributed major PBDEs in the alveoli region. In association with the fact that fine particles can penetrate deeper into the respiratory system, fine-particle-bound highly brominated PBDEs can be inhaled more deeply into human lungs and cause a greater risk to human health.

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Short summary
This study presents the particle size distribution of PBDEs in the atmosphere of a megacity and evaluates the contribution of size-fractionated PBDEs' deposition in the human respiratory tract.