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  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">AMT</journal-id>
<journal-title-group>
<journal-title>Atmospheric Measurement Techniques</journal-title>
<abbrev-journal-title abbrev-type="publisher">AMT</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Meas. Tech.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1867-8548</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/amt-9-2357-2016</article-id><title-group><article-title>OCRA radiometric cloud fractions for GOME-2 on MetOp-A/B</article-title>
      </title-group><?xmltex \runningtitle{OCRA for GOME-2A/B}?><?xmltex \runningauthor{R. Lutz et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Lutz</surname><given-names>Ronny</given-names></name>
          <email>ronny.lutz@dlr.de</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Loyola</surname><given-names>Diego</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-8547-9350</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Gimeno García</surname><given-names>Sebastián</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Romahn</surname><given-names>Fabian</given-names></name>
          
        </contrib>
        <aff id="aff1"><institution>German Aerospace Center (DLR), Remote Sensing Technology Institute (IMF), 82234 Weßling, Germany</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Ronny Lutz (ronny.lutz@dlr.de)</corresp></author-notes><pub-date><day>30</day><month>May</month><year>2016</year></pub-date>
      
      <volume>9</volume>
      <issue>5</issue>
      <fpage>2357</fpage><lpage>2379</lpage>
      <history>
        <date date-type="received"><day>23</day><month>November</month><year>2015</year></date>
           <date date-type="rev-request"><day>18</day><month>December</month><year>2015</year></date>
           <date date-type="rev-recd"><day>29</day><month>April</month><year>2016</year></date>
           <date date-type="accepted"><day>3</day><month>May</month><year>2016</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016.html">This article is available from https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016.html</self-uri>
<self-uri xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016.pdf">The full text article is available as a PDF file from https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016.pdf</self-uri>


      <abstract>
    <p>This paper describes an
approach for cloud parameter retrieval (radiometric cloud-fraction
estimation) using the polarization measurements of the Global Ozone
Monitoring Experiment-2 (GOME-2) onboard the MetOp-A/B satellites. The core
component of the Optical Cloud Recognition Algorithm (OCRA) is the
calculation of monthly cloud-free reflectances for a global grid (resolution
of 0.2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> in longitude and 0.2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> in latitude) to derive
radiometric cloud fractions. These cloud fractions will serve as a priori
information for the retrieval of cloud-top height (CTH), cloud-top pressure
(CTP), cloud-top albedo (CTA) and cloud optical thickness (COT) with the
Retrieval Of Cloud Information using Neural Networks (ROCINN) algorithm. This
approach is already being implemented operationally for the GOME/ERS-2 and
SCIAMACHY/ENVISAT sensors and here we present version 3.0 of the OCRA
algorithm applied to the GOME-2 sensors.</p>
    <p>Based on more than five years of GOME-2A data (April 2008 to June 2013),
reflectances are calculated for <inline-formula><mml:math display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 35 000 orbits. For each
measurement a degradation correction as well as a viewing-angle-dependent and
latitude-dependent correction is applied. In addition, an empirical
correction scheme is introduced in order to remove the effect of oceanic sun
glint. A comparison of the GOME-2A/B OCRA cloud fractions with colocated
AVHRR (Advanced Very High Resolution Radiometer) geometrical
cloud fractions shows a general good agreement with a mean difference of
<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.15 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.20.</p>
    <p>From an operational point of view, an advantage of the OCRA algorithm is its
very fast computational time and its straightforward transferability to
similar sensors like OMI (Ozone Monitoring Instrument), TROPOMI (TROPOspheric
Monitoring Instrument) on Sentinel 5 Precursor, as well as Sentinel 4 and
Sentinel 5.</p>
    <p>In conclusion, it is shown that a robust, accurate and fast radiometric cloud-fraction estimation for GOME-2 can be achieved with OCRA using
polarization measurement devices (PMDs).</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>The importance of clouds is not only manifested in the Earth's climate system
due their significant influence on radiation processes, but also in the
retrieval of atmospheric trace gases. Partially cloudy scenes may affect the
retrieval of atmospheric species due to increased albedo, altered lower
reflecting boundaries and modified photon path lengths. It is therefore
necessary to accurately know the basic macrophysical cloud parameters (cloud
fraction, cloud pressure, cloud height, cloud optical thickness) for
providing reliable trace-gas columns. In this paper, we report the retrieval
of a radiometric cloud fraction from GOME-2 level-1b data using version 3.0
of the OCRA (Optical Cloud Recognition Algorithm).</p>
      <p>The first Meteorological Operational satellite (MetOp-A), operated by the
European Organisation for the Exploitation of Meteorological Satellites
(EUMETSAT), was launched in October 2006 and follows a polar, sun-synchronous
orbit with a descending node equatorial crossing time at 09:30 LST. It carries
a GOME-2 instrument which is referred to as GOME-2A throughout this paper.
Another GOME-2 instrument is also mounted on MetOp-B, which was launched in
September 2012 and is referred to as GOME-2B in the following. The
descending node equatorial crossing time of MetOp-B is also at 09:30 LST. In
orbit, MetOp-A and MetOp-B are placed 48 min apart.</p>
      <p>The GOME-2 heritage instrument GOME (Global Ozone Monitoring Experiment, see
<xref ref-type="bibr" rid="bib1.bibx3" id="altparen.1"/>) onboard ERS-2 (European Remote Sensing 2
Satellite) also provided PMD (polarization measurement device) measurements. Further satellites also carrying
passive nadir-viewing instruments suited for an OCRA-like cloud-fraction
retrieval comprise OMI (Ozone Monitoring Instrument, see
<xref ref-type="bibr" rid="bib1.bibx13 bib1.bibx5 bib1.bibx20" id="altparen.2"/>) on
the NASA Aura Satellite, TROPOMI (TROPOspheric
Monitoring Instrument, see
<xref ref-type="bibr" rid="bib1.bibx27" id="text.3"/>) onboard the ESA Sentinel 5 Precursor mission as well
as the Sentinel 4 and Sentinel 5 missions
<xref ref-type="bibr" rid="bib1.bibx21 bib1.bibx2" id="paren.4"/>.</p>
      <p>Besides OCRA/ROCINN <xref ref-type="bibr" rid="bib1.bibx14 bib1.bibx15" id="paren.5"/>, some other current cloud
retrieval algorithms for UVN spectrometers are FRESCO+
<xref ref-type="bibr" rid="bib1.bibx28" id="paren.6"/>, SACURA <xref ref-type="bibr" rid="bib1.bibx12" id="paren.7"/> or HICRU
<xref ref-type="bibr" rid="bib1.bibx8" id="paren.8"/>. The algorithms mentioned above all retrieve a radiometric or effective cloud fraction instead of a
geometric one. The most significant difference between OCRA and the quoted
algorithms on the other hand is the wavelength range in which the respective
algorithm is operating. While OCRA uses broadband measurements (or
measurements averaged over a very broad wavelength region) to determine the
cloud fraction, much narrower wavelength bands are used by the other
algorithms, e.g., the O2A-band for FRESCO<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> and narrow bands around 382 or
519 nm for HICRU in the case of GOME-2 data.</p>
      <p>In this paper we present the latest version 3.0 of the OCRA algorithm and the
results obtained using GOME-2 data.</p>
      <p>The basic idea of OCRA is to separate a scene into a contribution of clouds
and a cloud-free background. In the context of the independent pixel
approximation (IPA), the pixel reflectance can be expressed as the sum of the
reflectances of the true cloudy part (i.e., geometrical cloud fraction) and
the cloud-free part. Since these parts cannot be clearly separated given the
PMD footprint resolution, OCRA computes a radiometric cloud fraction instead
of a geometric one. The cloud-free background is calculated offline and
provides reflectances in the absence of clouds for each month of the year for
a global grid in a given resolution. For GOME-2, a global grid with a
resolution of 0.2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> in both latitude and longitude was chosen. For
each measured scene, OCRA takes the spectral information from the UV-VIS-NIR
part and transforms the radiances of three predefined spectral ranges to
three reflectances or RGB colors: R in the red part of the spectrum, G in
the green part and B in the blue part. The cloud-free background maps are
calculated for each of these three colors. OCRA further assumes that clouds
have higher reflectivity than the surrounding underground and that clouds
have a negligible spectral dependency in the regarded optical wavelength
range, meaning that clouds appear white in the context of the RGB color
scheme since all colors contribute the same amount. The radiometric
cloud fraction is then finally determined by comparison of the measured
reflectance of a given scene with its corresponding cloud-free reflectance
from the cloud-free background. As shown in <xref ref-type="bibr" rid="bib1.bibx26" id="text.9"/>, possible
errors in the OCRA cloud fraction are compensated for in the ROCINN cloud-albedo
retrieval resulting in a neglectable net effect on the trace-gas retrieval.</p>
      <p>This paper is organized as follows: the data selection and preprocessing are
found in Sect. <xref ref-type="sec" rid="Ch1.S2"/>. The latter includes reflectance
corrections for several instrumental and noninstrumental effects. The
methods specific to the OCRA algorithm are described in
Sect. <xref ref-type="sec" rid="Ch1.S3"/>, which also contains the treatment of sun glint.
The results are covered in Sect. <xref ref-type="sec" rid="Ch1.S4"/> and include
intercomparisons of OCRA for both GOME-2 instruments as well as comparisons
with FRESCO and AVHRR cloud fractions. In the following, the OCRA performance
over snow/ice conditions is discussed in Sect. <xref ref-type="sec" rid="Ch1.S5"/>. We
finally close with the conclusions.</p>
</sec>
<sec id="Ch1.S2">
  <title>Data selection and preprocessing</title>
      <p>The GOME-2 nadir-viewing optical spectrometer <xref ref-type="bibr" rid="bib1.bibx19" id="paren.10"/> senses
Earth's backscattered radiance and solar irradiance at UV-VIS-NIR wavelengths
in the range 240–790 nm at a spectral resolution between 0.2 and 0.4 nm.
In addition, GOME-2 also measures the state of linear polarization of the
backscattered earthshine radiances in two perpendicular directions (parallel
and perpendicular to the entrance slit) via the so-called polarization
measurement devices (PMDs). The PMD data are taken at 15 spectral bands which
cover the spectral region from 312 to 800 nm. A nominal full GOME-2 swath
has a width of 1920 km in the direction perpendicular to the flight
direction and a single scan line has an extension of 40 km in the flight
direction. A full GOME-2 scan consists of 256 PMD measurements (192 in the
forward scan direction from east to west and 64 in the backscan from west to
east). Since the backscan PMD pixels have a coarser spatial resolution
compared to the forward scan pixels (due to different integration times), for
the radiometric cloud retrieval with OCRA, only the PMD measurements of the
forward scan are used. This results in 192 PMD pixels in the across-track
direction, with each pixel having a footprint of 10 km <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 40 km. Further
information about GOME-2 can be found in the GOME-2 fact sheet
<xref ref-type="bibr" rid="bib1.bibx6" id="paren.11"/>.</p>
      <p>All data considered in this section are from nominal 1920 km swath
observations, excluding data in narrow swath mode or other modes like nadir
static, PMD raw, calibration, etc. Our time base for GOME-2A data is
1 February 2007 to 30 September 2014 and for GOME-2B data it is
1 January 2013 to 30 September 2014. In order to construct the cloud-free
background maps, we only use GOME-2A data from 1 April 2008 to
30 June 2013. The time before is excluded in this case because of another
definition for the PMD bands which significantly affects the reflectance.
Hence, for the cloud-free background maps, we only use data with PMD Def
v3.1, which was uploaded to orbit on 12 March 2008, replacing the former PMD
Def v1.0. An overview of the PMD band definitions v3.1 is given in
Table <xref ref-type="table" rid="Ch1.T1"/>. The time after 30 June 2013 is excluded,
because the nominal swath for GOME-2A was changed from 1920 to 960 km. From
this time on, the tandem mode operation of both GOME-2 instruments was set to
a 960 km swath for GOME-2A and a 1920 km swath for GOME-2B. This tandem-mode
operation provides a gapless daily global coverage even at the equator.
Other specific events occurring in the considered time frame are a key data
update to the MetOp-A instrument model FM3 on 3 July 2012 as well as solar
eclipses which might affect the data due to their ground shadow track. It is
particularly important to avoid solar eclipses for the construction of the
cloud-free composite maps because the abnormally low reflectance of a scene
affected by the ground shadow track would falsely contribute to the maps.
Therefore we discarded all orbits which might be affected by solar eclipses.
A list of MetOp-A/B orbits which are affected by solar eclipses may be found
in Appendix B of the Algorithm Theoretical Basis Document for the GOME-2
surface LER product <xref ref-type="bibr" rid="bib1.bibx25" id="paren.12"/>.</p>
      <p>The following subsections provide a detailed description of the steps we
applied in order to derive the cloud-free reflectance composites, beginning
with the definition of colors which are mapped from the PMD reflectances and
followed by various reflectance corrections. Afterwards, the basic concept of
the OCRA algorithm is presented along with an empirical approach to identify
scenes affected by sun glint and to correct the influence of those scenes on
the cloud-fraction determination.</p>
<sec id="Ch1.S2.SS1">
  <title>Extraction of PMD reflectances</title>
      <p>In a first step, we determine the top-of-atmosphere (TOA) reflectance of each
PMD measurement. The reflectance <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> of a measurement at
wavelength <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> is obtained.
            <disp-formula id="Ch1.E1" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="italic">π</mml:mi><mml:mo>⋅</mml:mo><mml:mi>I</mml:mi></mml:mrow><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>⋅</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="normal">Θ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>I</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> denotes the upwelling radiance measured by the satellite,
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> denotes the solar irradiance and <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="normal">Θ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the solar
zenith angle (SZA). The wavelengths of the PMDs as defined for GOME-2 are
listed in Table <xref ref-type="table" rid="Ch1.T1"/>.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1"><caption><p>GOME-2 PMD band definitions (v3.1). For GOME-2A, these settings
have applied to the data since 11 March 2008. The PMD band definitions for GOME-2B
differ slightly (mostly below one nm) and can be found in the GOME-2
fact sheet <xref ref-type="bibr" rid="bib1.bibx6" id="paren.13"/>.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="right"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry namest="col2" nameend="col3" align="center">Band-P </oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry namest="col5" nameend="col6" align="center">Band-S </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">no.</oasis:entry>  
         <oasis:entry namest="col2" nameend="col3" align="center">range in nm </oasis:entry>  
         <oasis:entry colname="col4">no.</oasis:entry>  
         <oasis:entry namest="col5" nameend="col6" align="center">range in nm </oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">0</oasis:entry>  
         <oasis:entry colname="col2">311.537</oasis:entry>  
         <oasis:entry colname="col3">313.960</oasis:entry>  
         <oasis:entry colname="col4">0</oasis:entry>  
         <oasis:entry colname="col5">311.709</oasis:entry>  
         <oasis:entry colname="col6">314.207</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">1</oasis:entry>  
         <oasis:entry colname="col2">317.068</oasis:entry>  
         <oasis:entry colname="col3">318.983</oasis:entry>  
         <oasis:entry colname="col4">1</oasis:entry>  
         <oasis:entry colname="col5">316.762</oasis:entry>  
         <oasis:entry colname="col6">318.720</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">2</oasis:entry>  
         <oasis:entry colname="col2">321.603</oasis:entry>  
         <oasis:entry colname="col3">329.267</oasis:entry>  
         <oasis:entry colname="col4">2</oasis:entry>  
         <oasis:entry colname="col5">321.389</oasis:entry>  
         <oasis:entry colname="col6">329.139</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">3</oasis:entry>  
         <oasis:entry colname="col2">330.744</oasis:entry>  
         <oasis:entry colname="col3">334.560</oasis:entry>  
         <oasis:entry colname="col4">3</oasis:entry>  
         <oasis:entry colname="col5">330.622</oasis:entry>  
         <oasis:entry colname="col6">334.443</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">4</oasis:entry>  
         <oasis:entry colname="col2">336.157</oasis:entry>  
         <oasis:entry colname="col3">340.302</oasis:entry>  
         <oasis:entry colname="col4">4</oasis:entry>  
         <oasis:entry colname="col5">336.037</oasis:entry>  
         <oasis:entry colname="col6">340.161</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">5</oasis:entry>  
         <oasis:entry colname="col2">361.054</oasis:entry>  
         <oasis:entry colname="col3">378.204</oasis:entry>  
         <oasis:entry colname="col4">5</oasis:entry>  
         <oasis:entry colname="col5">360.703</oasis:entry>  
         <oasis:entry colname="col6">377.873</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">6</oasis:entry>  
         <oasis:entry colname="col2">380.502</oasis:entry>  
         <oasis:entry colname="col3">384.049</oasis:entry>  
         <oasis:entry colname="col4">6</oasis:entry>  
         <oasis:entry colname="col5">380.186</oasis:entry>  
         <oasis:entry colname="col6">383.753</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7</oasis:entry>  
         <oasis:entry colname="col2">399.921</oasis:entry>  
         <oasis:entry colname="col3">429.239</oasis:entry>  
         <oasis:entry colname="col4">7</oasis:entry>  
         <oasis:entry colname="col5">399.581</oasis:entry>  
         <oasis:entry colname="col6">428.585</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">8</oasis:entry>  
         <oasis:entry colname="col2">434.779</oasis:entry>  
         <oasis:entry colname="col3">492.569</oasis:entry>  
         <oasis:entry colname="col4">8</oasis:entry>  
         <oasis:entry colname="col5">434.083</oasis:entry>  
         <oasis:entry colname="col6">492.066</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">9</oasis:entry>  
         <oasis:entry colname="col2">495.272</oasis:entry>  
         <oasis:entry colname="col3">549.237</oasis:entry>  
         <oasis:entry colname="col4">9</oasis:entry>  
         <oasis:entry colname="col5">494.780</oasis:entry>  
         <oasis:entry colname="col6">548.756</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">10</oasis:entry>  
         <oasis:entry colname="col2">552.967</oasis:entry>  
         <oasis:entry colname="col3">556.769</oasis:entry>  
         <oasis:entry colname="col4">10</oasis:entry>  
         <oasis:entry colname="col5">552.474</oasis:entry>  
         <oasis:entry colname="col6">556.262</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">11</oasis:entry>  
         <oasis:entry colname="col2">568.628</oasis:entry>  
         <oasis:entry colname="col3">613.680</oasis:entry>  
         <oasis:entry colname="col4">11</oasis:entry>  
         <oasis:entry colname="col5">568.070</oasis:entry>  
         <oasis:entry colname="col6">612.869</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">12</oasis:entry>  
         <oasis:entry colname="col2">618.711</oasis:entry>  
         <oasis:entry colname="col3">662.990</oasis:entry>  
         <oasis:entry colname="col4">12</oasis:entry>  
         <oasis:entry colname="col5">617.867</oasis:entry>  
         <oasis:entry colname="col6">661.893</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">13</oasis:entry>  
         <oasis:entry colname="col2">745.379</oasis:entry>  
         <oasis:entry colname="col3">769.553</oasis:entry>  
         <oasis:entry colname="col4">13</oasis:entry>  
         <oasis:entry colname="col5">744.112</oasis:entry>  
         <oasis:entry colname="col6">768.269</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">14</oasis:entry>  
         <oasis:entry colname="col2">795.364</oasis:entry>  
         <oasis:entry colname="col3">804.351</oasis:entry>  
         <oasis:entry colname="col4">14</oasis:entry>  
         <oasis:entry colname="col5">794.080</oasis:entry>  
         <oasis:entry colname="col6">803.072</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><caption><p>OCRA definition of RGB-colors. The PMD numbers refer to the definitions given in Table <xref ref-type="table" rid="Ch1.T1"/>. </p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">mean reflectance of PMD numbers</oasis:entry>  
         <oasis:entry colname="col3">range in nm (Band-P)</oasis:entry>  
         <oasis:entry colname="col4">range in nm (Band-S)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">OCRA color R</oasis:entry>  
         <oasis:entry colname="col2">11 to 14</oasis:entry>  
         <oasis:entry colname="col3">568.628–804.351</oasis:entry>  
         <oasis:entry colname="col4">568.070–803.072</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">OCRA color G</oasis:entry>  
         <oasis:entry colname="col2">7 to 10</oasis:entry>  
         <oasis:entry colname="col3">399.921–556.769</oasis:entry>  
         <oasis:entry colname="col4">399.581–556.262</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">OCRA color B</oasis:entry>  
         <oasis:entry colname="col2">2 to 6</oasis:entry>  
         <oasis:entry colname="col3">321.603–384.049</oasis:entry>  
         <oasis:entry colname="col4">321.389–383.753</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p>Instrumental degradation for GOME-2A as a function of time for the
RGB OCRA colors. The examples shown here are only for P-pol data and for
three VZA bins. <bold>(a)</bold> VZA bin 0: eastern swath edge at <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>55<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>,
<bold>(b)</bold> VZA bin 55: near-nadir center of swath and <bold>(c)</bold> VZA bin
109: western swath edge at <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>55<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. The solid lines are polynomial
fits of third order and the time base is from 1 February 2007 to
30 September 2014.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f01.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><caption><p>GOME-2A degradation factors as a function of time for the 110
across-track VZA bins for <bold>(a)</bold> color PB, <bold>(b)</bold> color PG and
<bold>(c)</bold> color PR. The time runs in days starting on 1 February 2007
to 30 September 2014 in the positive y-axis direction. Yearly intervals
are separated by horizontal solid lines. VZA bin 0 represents the eastern edge
of the swath (VZA of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>55 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>50<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>), VZA bin 55 is close to nadir
and VZA bin 109 represents the western edge of the swath (VZA of 50 to
55<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>). The VZA bins 0–20 and 89–109 are no longer occupied after
the GOME-2A swath reduction from 1920 to 960 km in July 2013. This is seen
as the white data gaps at the top of the panels. The calculation of the
degradation factors is therefore based on two different data sets
(February 2007 to July 2013 for VZA bins 0–20 and 89–109 and
February 2007 to September 2014 for VZA bins 21–88), which leads to the
slight discontinuity at the transition zones seen in the plot. Note that the
color bar has the same scale in the three panels in order to allow a direct
comparison of the three colors.</p></caption>
          <?xmltex \igopts{width=298.753937pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f02.jpg"/>

        </fig>

      <p>Since OCRA uses a RGB-color approach, we need to map the 15 PMD bands to the
three colors R, G and B. Throughout this paper we define the color B, or
blue, as the mean of the reflectances of PMDs 2 to 6 (0-based), G, or green,
as the mean of the reflectances of PMDs 7 to 10 (0-based) and R, or red, as
the mean of the reflectances of PMDs 11 to 14 (see
Table <xref ref-type="table" rid="Ch1.T2"/>). This mapping is done for both possible
polarization states: linear-parallel and linear-perpendicular polarization.
For GOME-2, these two states are denoted by P and S. Hence, for
each measurement, we denote the colors based on linear-parallel polarization
as PB, PG and PR and those based on linear-perpendicular polarization as SB,
SG and SR. The solar zenith angle in our reflectance determination is
restricted to <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 89<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <title>Reflectance corrections and normalization</title>
      <p>Since instruments on a satellite happen to be in a very harsh environment,
they cannot be perfectly stable and may therefore be subject to instrumental
degradation. This instrumental degradation will, as a function of time,
affect the measured reflectances; hence we need to correct for this
effect.</p>
      <p>Another aspect to be considered is a geometrical one: the mean reflectances
for the swath edges will differ from those close to the nadir position of the
swath. The same is true for different latitudinal positions, e.g., close to the
equator or close to the poles. Finally, seasonal variations of the surface
(predominantly variations of snow and ice cover) will have an impact on the
measured mean reflectances. In the following, we account for these effects
mentioned above by calculating correction factors for the reflectances as a
function of time (and/or season), latitude and viewing zenith angle (VZA).
VZA is used instead of the across-track PMD pixel position because the
latter would lead to ambiguities when dealing with different swath widths
(e.g., 1920 km vs. 960 km swaths).</p>
      <p>The correction factors are based on statistically representative measurements
which are assumed to describe a certain process well enough, e.g., global
daily mean reflectances for degradation or monthly zonal mean reflectances
for seasonal scan angle dependencies. For all corrections, the reference
measurements are from 1 February 2007 for GOME-2A and 1 January 2013 for
GOME-2B. We apply correction factors in two subsequent steps:
the first step covers instrumental degradation as a function of time and VZA
and the second step covers geometrical aspects as a function of VZA, latitude
and month (i.e., time). These two correction steps are outlined in the
following two sections.</p>
<sec id="Ch1.S2.SS2.SSS1">
  <title>Instrumental degradation</title>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><caption><p>Instrumental degradation for GOME-2B as a function of time for the
RGB OCRA colors. The examples shown here are only for P-pol data and for
three VZA bins: <bold>(a)</bold> VZA bin 0: eastern swath edge at <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>55<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>,
<bold>(b)</bold> VZA bin 55: near-nadir center of swath and <bold>(c)</bold> VZA bin
109: western swath edge at <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>55<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. The solid lines are linear fits
and the time base is from 1 January 2013 to 30 September 2014.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f03.png"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><caption><p>GOME-2B degradation factors as a function of time for the 110
across-track VZA bins for <bold>(a)</bold> color PB, <bold>(b)</bold> color PG and
<bold>(c)</bold> color PR. The time runs in days starting on 1 January 2013 and
ending on 30 September 2014 in the positive <inline-formula><mml:math display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis direction. Yearly intervals are
separated by horizontal solid lines. VZA bin 0 represents the eastern edge of
the swath (VZA of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>55 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>50<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>), VZA bin 55 is close to nadir and
VZA bin 109 represents the western edge of the swath (VZA of 50 to 55<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>).
Note that the color bar has the same scale in the three panels in order to
allow a direct comparison of the three colors.</p></caption>
            <?xmltex \igopts{width=298.753937pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f04.jpg"/>

          </fig>

      <p>Following the approach of <xref ref-type="bibr" rid="bib1.bibx23" id="text.14"/>, we calculate a global
daily mean reflectance for each of the 192 PMD pixels. In a subsequent step we
map each PMD pixel to a VZA. The 192 PMD pixels are mapped to 110 viewing
zenith angle bins of 1-degree width, which cover the region from
<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>55<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (eastern edge of swath) to <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>55<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (western edge of swath) in
VZA. Each global daily mean reflectance is comprised of all measurements
within the latitude range from 60<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N to 60<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S. For the
whole data baseline, examples of the temporal evolution of the GOME-2A
degradation are shown in Fig. <xref ref-type="fig" rid="Ch1.F1"/> for the colors PB,
PG and PR for three selected VZA bins: VZA bin 0 (eastern edge of swath, VZA
[<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>55, <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>50] degrees), VZA bin 55 (nadir part of swath, VZA [0, 5] degrees)
and VZA bin 109 (western edge of the swath, VZA [50, 55] degrees).</p>
      <p>Short-term periodic components in both cases are interpreted as variations
due to seasonal changes, e.g., seasonal changes in snow and ice coverage,
vegetation, foliage etc. (all resulting from the Earth's obliquity against
the orbital plane). In contrast, the long-term component in both cases,
GOME-2A and GOME-2B, is attributed to instrumental
degradation. For GOME-2A we chose a polynomial component of third degree and
for GOME-2B a linear component (linear instead of third degree because the
GOME-2B data only cover one and a half years and a third order polynomial
would also fit the seasonal component. A more appropriate degradation model
for GOME-2B will replace the linear model as soon as a sufficient temporal
coverage of at least several annual cycles is reached).</p>
      <p>We calculate degradation factors as a function of time and VZA by normalizing
the polynomial (GOME-2A) or linear (GOME-2B) component to the reference
measurements from 1 February 2007 for GOME-2A and 1 January 2013 for GOME-2B.
Further, correction factors to be multiplied with the reflectances are
calculated as the inverse of the degradation factors and stored in look-up
tables (LUTs). Figures <xref ref-type="fig" rid="Ch1.F1"/> and
<xref ref-type="fig" rid="Ch1.F2"/>, respectively, show the instrumental
degradation and degradation factors for GOME-2A. The same is presented for
GOME-2B in Figs. <xref ref-type="fig" rid="Ch1.F3"/> and
<xref ref-type="fig" rid="Ch1.F4"/>. It is clear that the degradation of
the reflectances does not follow a similar pattern but instead strongly
depends on wavelength range (OCRA color) and viewing zenith angle. Also,
depending on the degradation in the solar port compared to the Earth port,
the degradation of the reflectance can be positive or negative.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><caption><p>Comparison of degradation for GOME-2A and GOME-2B for color PB.
Panel <bold>(a)</bold> shows the PMD pixel 0 at the eastern swath edge,
<bold>(b)</bold> shows PMD pixel 95 near nadir and <bold>(c)</bold> shows PMD pixel
191 at the western swath edge. Blue dots represent GOME-2A data, black dots
represent GOME-2B data and grey dots represent GOME-2B data time-shifted such
that it can be compared to the in-orbit time of GOME-2A.</p></caption>
            <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f05.png"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><caption><p>Comparison of degradation for GOME-2A and GOME-2B for color PG.
Panel <bold>(a)</bold> shows the PMD pixel 0 at the eastern swath edge,
<bold>(b)</bold> shows PMD pixel 95 near nadir and <bold>(c)</bold> shows PMD pixel
191 at the western swath edge. Green dots represent GOME-2A data, black dots
represent GOME-2B data and grey dots represent GOME-2B data time-shifted such
that it can be compared to the in-orbit time of GOME-2A.</p></caption>
            <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f06.png"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><caption><p>Comparison of degradation for GOME-2A and GOME-2B for color PR.
Panel <bold>(a)</bold> shows the PMD pixel 0 at the eastern swath edge,
<bold>(b)</bold> shows PMD pixel 95 near nadir and <bold>(c)</bold> shows PMD pixel
191 at the western swath edge. Red dots represent GOME-2A data, black dots
represent GOME-2B data and grey dots represent GOME-2B data time-shifted such
that it can be compared to the in-orbit time of GOME-2A.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f07.png"/>

          </fig>

      <p>Figures <xref ref-type="fig" rid="Ch1.F5"/>,
<xref ref-type="fig" rid="Ch1.F6"/> and
<xref ref-type="fig" rid="Ch1.F7"/> compare the instrumental
degradation for GOME-2A and GOME-2B. Daily mean reflectances in the latitude
range from 60<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N to 60<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S are plotted against time for the
three OCRA colors PB (Fig. <xref ref-type="fig" rid="Ch1.F5"/>),
PG (Fig. <xref ref-type="fig" rid="Ch1.F6"/>) and PR
(Fig. <xref ref-type="fig" rid="Ch1.F7"/>) for the PMD pixels 0
(eastern edge of swath, panel a), 95 (near nadir, panel b) and 191 (western edge of
swath, panel c). The reference measurement for GOME-2A is 1 February 2007
(MetOp-A orbit 1483) and for GOME-2B 1 January 2013 (MetOp-B orbit 1497),
resulting in a similar in-orbit time at the reference points. The time
difference between the two reference points for GOME-2A and GOME-2B is 2161
days. The colored dots represent GOME-2A data while the black dots represent
GOME-2B data in the same timeline as GOME-2A, i.e., the GOME-2B timeline plus
2161 days. The grey circles represent GOME-2B data shifted such that they can
be compared to the initial degradation of GOME-2A. The left dashed line marks
the transition from PMD Def v1.0 to PMD Def v3.1 on 12 March 2008 for GOME-2A
(which mainly affects PB, but to a negligible extend PG and PR) and the right
dashed line represents the FM3 key data upgrade for MetOp-A on 3 July 2012,
which does not seem to affect any of the colors.</p>
      <p>The left hand sides of the figures allow us to estimate the effects of the PMD
Definition version on the RGB reflectances. Left of the dashed line, PMD Def
v1.0 was used for GOME-2A and right of the dashed line PMD Def v3.1 was
applied to GOME-2A. The effect is significant for PB, while they are minor for
PG and PR. Also, the GOME-2B reflectances, shifted to match the in-orbit time
of GOME-2A, align very well with the GOME-2A reflectances after 12 March 2008.
This is because the PMD Definitions for GOME-2B are very close to the PMD Def
v3.1 of GOME-2A.</p>
      <p>The right hand side of the figures allows for an estimation of the effect of
degradation and demonstrates that it is nontrivial, and they depend not
only on time but also on wavelength range (here colors PB, PG or PR) and
viewing zenith angle (here PMD pixels 0, 95 and 191). It is further noted
that PG and PR show a positive degradation for all three cases (east, nadir
and west), meaning that the measured reflectances decreased over time. In
contrast, PB shows a negative degradation associated with an increase of the
reflectance over time. A common feature for all three colors is that the
degradation (positive or negative) is strongest at the eastern swath edge
(pixel 0) and weakest at the western swath edge (pixel 191). The sign of the
degradation of the reflectance is also influenced by the degradation of the
solar port. We presume that a negative degradation in the reflectance (as
seen for PB) may be associated with a faster positive degradation of the
solar channel compared to the Earth channel.</p>
</sec>
<sec id="Ch1.S2.SS2.SSS2">
  <title>Dependencies on viewing angles, latitudes and seasons</title>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8" specific-use="star"><caption><p>GOME-2A monthly mean reflectances for <bold>(a)</bold> OCRA color PB,
<bold>(b)</bold> OCRA color PG and <bold>(c)</bold> OCRA color PR in February 2007 in
14 latitude bands. The bands have a bin size of 10<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> in the latitude
range from 60<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N to 60<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S and a bin size of 30<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> for
the polar regions [60, 90 N] and [60, 90<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S]. The filled circles
represent the northern hemisphere and the open circles represent the southern
hemisphere.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f08.jpg"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><caption><p>Same as Fig. <xref ref-type="fig" rid="Ch1.F8"/>, but for GOME-2B and
January 2013.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f09.jpg"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F10" specific-use="star"><caption><p>Temporal evolution of correction factors for scan angle and
latitudinal dependencies for <bold>(a)</bold> GOME-2A and <bold>(b)</bold> GOME-2B.
The example is for color PB and VZA bin 21, which corresponds to viewing
zenith angles in the range [<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>34, <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>33] degrees. The times are given in years
from February 2007 and January 2013 for the respective panels and the vertical black
lines separate yearly intervals.</p></caption>
            <?xmltex \igopts{width=469.470472pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f10.png"/>

          </fig>

      <p>After the correction for the instrumental degradation, we calculated monthly
mean reflectances for each PMD pixel (or VZA bin). The monthly mean
reflectance depends not only on the viewing angle (PMD pixel) but also
on the latitude (see Figs. <xref ref-type="fig" rid="Ch1.F8"/> and
<xref ref-type="fig" rid="Ch1.F9"/> for GOME-2A and GOME-2B, respectively). We
consider a total of 14 latitude bands. Twelve bands with a width of
10<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> between [<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>60, <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>60] and two bands with a width of
30<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> for latitudes <inline-formula><mml:math display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 60 and <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>60 (i.e., towards the poles). To
estimate the effect of the viewing angle and the latitude on the measured
mean reflectance and to correct for it, we do the following procedure for
each month considered. For each PMD pixel <inline-formula><mml:math display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> the mean reflectance of every
latitude band <inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:math></inline-formula> is calculated for a whole month of data and
fitted with a fourth order polynomial:
              <disp-formula id="Ch1.E2" content-type="numbered"><mml:math display="block"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>mean</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">β</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub><mml:mo>⋅</mml:mo><mml:mi>x</mml:mi><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">γ</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub><mml:mo>⋅</mml:mo><mml:msup><mml:mi>x</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">δ</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub><mml:mo>⋅</mml:mo><mml:msup><mml:mi>x</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">ϵ</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub><mml:mo>⋅</mml:mo><mml:msup><mml:mi>x</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msup><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
            where <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">β</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">γ</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">δ</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ϵ</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> are the fit parameters for the corresponding
pixel <inline-formula><mml:math display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> (PMD pixels from 0 to 191) and latitude band <inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:math></inline-formula>. The
correction factor <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> for the reflectance measurement at
pixel <inline-formula><mml:math display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> and latitude band <inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:math></inline-formula> is calculated by normalization to
the mean reflectance of the close-to-nadir pixel (PMD pixel 95 of 191) of the
corresponding latitude band:
              <disp-formula id="Ch1.E3" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>mean</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>mean</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:mn>95</mml:mn><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mo>)</mml:mo></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
            <?xmltex \hack{\newpage}?><?xmltex \hack{\noindent}?>To get the correction factor <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> for an arbitrary latitude
<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, we apply a linear interpolation between the correction factors
<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> of the 14 latitude bands <inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi mathvariant="italic">φ</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover></mml:math></inline-formula> for each of the
across-track PMD pixels <inline-formula><mml:math display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula>. If the VZA is used instead of the across-track
PMD pixel position, the <inline-formula><mml:math display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> in Eqs. (<xref ref-type="disp-formula" rid="Ch1.E2"/>) and
(<xref ref-type="disp-formula" rid="Ch1.E3"/>) has to be replaced by the VZA and the nadir pixel
95 in the denominator of Eq. (<xref ref-type="disp-formula" rid="Ch1.E3"/>) has to be replaced by
the VZA bin 55 which is the VZA bin closest to nadir.</p>
      <p>For each month considered, the fitting parameters for calculating the pixel- and
latitude-dependent correction values for all OCRA colors and polarizations
are then stored in LUTs. The same is done in the case of the VZA- and
latitude-dependent correction values. The viewing angle and latitudinal
dependencies for GOME-2A are shown for the example of the month of February 2007
for the P-pol data in Fig. <xref ref-type="fig" rid="Ch1.F8"/> and for GOME-2B for
the month of January 2013 in Fig. <xref ref-type="fig" rid="Ch1.F9"/>. The general
shape is very similar in all other months. As can be seen as a general
feature, the monthly mean reflectances are larger at the swath edges than at
the nadir position for all three colors or more generally at the central
part of the swath. Similarly, the monthly mean reflectances are larger in
polar and subpolar latitudes and smaller in tropical latitudes. Also the
curvature is slightly different in different months throughout the year. It
is stronger in winter months and weaker in summer months (not shown here).</p>
      <p>Similarly to the degradation correction, the correction factors for the
dependencies on viewing angles, latitudes and seasons are also stored in LUTs
for all combinations of colors and polarization state. See
Fig. <xref ref-type="fig" rid="Ch1.F10"/> for the temporal evolution of the
correction factors for viewing angle and latitudinal dependencies for GOME-2A
(February 2007 to September 2014) and GOME-2B (January 2013 to
September 2014), respectively. The annual periodicity is clearly visible.</p>
</sec>
</sec>
</sec>
<sec id="Ch1.S3">
  <title>Methods</title>
      <p>As outlined in the introduction, the basic idea of OCRA is to separate a
scene into a contribution of clouds and a cloud-free background. The
following subsections explain in detail the initial step of generating the
cloud-free reflectance background, the cloud-fraction determination
with OCRA and finally an improved approach for the removal of sun glint.</p><?xmltex \hack{\newpage}?>
<sec id="Ch1.S3.SS1">
  <title>Construction of cloud-free reflectance composites</title>

      <?xmltex \floatpos{t}?><fig id="Ch1.F11" specific-use="star"><caption><p>GOME-2A cloud-free background maps for <bold>(a)</bold> color PB in
February, <bold>(b)</bold> color PG in February, <bold>(c)</bold> color PR in
February, <bold>(d)</bold> color PB in August, <bold>(e)</bold> color PG in August
and <bold>(f)</bold> color PR in August.</p></caption>
          <?xmltex \igopts{width=441.017717pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f11.jpg"/>

        </fig>

      <p>After correcting the reflectances for instrumental degradation and
dependencies on viewing angles, latitudes and seasons, we apply the following
color approach to determine cloud-free reflectance composite maps.</p>
      <p>First, a grid with a resolution of 0.2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> in latitude and longitude is
defined (globally resulting in 900 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 1800 <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1 620 000 grid
cells). For each grid cell we collect all GOME-2A measurements between
April 2008 and June 2013 (63 months) with central longitude and latitude
within the borders of each grid cell. Since we want to derive monthly
cloud-free composites, these measurements are further divided according to
the month in which they were taken (the same months in consecutive years are
combined). Based on the 5-year data set, the resulting number of measurements
per grid cell and per month is around 120 to 180, depending on geolocation.
Grid cells closer to the poles have a shorter revisit timescale and will
therefore likely contain more measurements within a given time frame than a
grid cell at the equator. For each color (PB, PG and PR) the normalized color
(Pb, Pg and Pr) is obtained.

                <disp-formula id="Ch1.E4" specific-use="align" content-type="subnumberedsingle"><mml:math display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E4.1"><mml:mtd/><mml:mtd><mml:mrow><mml:mtext>Pb</mml:mtext><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mtext>PB</mml:mtext><mml:mrow><mml:mtext>PB</mml:mtext><mml:mo>+</mml:mo><mml:mtext>PG</mml:mtext><mml:mo>+</mml:mo><mml:mtext>PR</mml:mtext></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E4.2"><mml:mtd/><mml:mtd><mml:mrow><mml:mtext>Pg</mml:mtext><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mtext>PG</mml:mtext><mml:mrow><mml:mtext>PB</mml:mtext><mml:mo>+</mml:mo><mml:mtext>PG</mml:mtext><mml:mo>+</mml:mo><mml:mtext>PR</mml:mtext></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E4.3"><mml:mtd/><mml:mtd><mml:mrow><mml:mtext>Pr</mml:mtext><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mtext>PR</mml:mtext><mml:mrow><mml:mtext>PB</mml:mtext><mml:mo>+</mml:mo><mml:mtext>PG</mml:mtext><mml:mo>+</mml:mo><mml:mtext>PR</mml:mtext></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

            The normalized colors based on S-polarization (Sb, Sg and Sr) are obtained in
a similar way. In contrast to the non-normalized RGB colors (which are
reflectances), the normalized colors rgb
add up to unity, i.e., r <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> g <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> b <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1. In a Pr-Pg or Sr-Sg color
diagram, let <inline-formula><mml:math display="inline"><mml:mi>w</mml:mi></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> (1/3, 1/3) be the white point and <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>M</mml:mi><mml:mtext>P</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mo>(</mml:mo><mml:mtext>Pr</mml:mtext></mml:mrow></mml:math></inline-formula>, Pg) and <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>M</mml:mi><mml:mtext>S</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mo>(</mml:mo><mml:mtext>Sr</mml:mtext></mml:mrow></mml:math></inline-formula>, Sg) be the measurements
based on P-polarization and S-polarization, respectively. Then the distances
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mtext>P</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> from the measurement to the white point for the
two polarization cases are given.

                <disp-formula id="Ch1.E5" specific-use="align" content-type="subnumberedsingle"><mml:math display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E5.1"><mml:mtd/><mml:mtd><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mtext>P</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:msqrt><mml:mrow><mml:msup><mml:mfenced open="(" close=")"><mml:mtext>Pr</mml:mtext><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">3</mml:mn></mml:mfrac></mml:mstyle></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mfenced open="(" close=")"><mml:mtext>Pg</mml:mtext><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">3</mml:mn></mml:mfrac></mml:mstyle></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:msqrt><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E5.2"><mml:mtd/><mml:mtd><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mtext>S</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:msqrt><mml:mrow><mml:msup><mml:mfenced close=")" open="("><mml:mtext>Sr</mml:mtext><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">3</mml:mn></mml:mfrac></mml:mstyle></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mfenced open="(" close=")"><mml:mtext>Sg</mml:mtext><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">3</mml:mn></mml:mfrac></mml:mstyle></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:msqrt></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

            The distances from the white point are calculated for all measurements within
a grid cell and the RGB colors of the measurement with the largest distance
from the white point are defined to represent the cloud-free situation of
that grid cell. By merging the cloud-free conditions of all grid cells, we
can finally obtain global cloud-free TOA reflectance composite maps for each
month and RGB color. All cloud-free composite maps are stored in look-up
tables. Some examples for the spring and summer months for OCRA colors PB, PG
and PR are shown in Fig. <xref ref-type="fig" rid="Ch1.F11"/>. Close to the
poles it may occur that cells do not contain enough data. Such cells are
assigned with NaN values and appear grey in the plots. It may be noted here that
the cloud-free reflectance for PR in February appears to be below 0.5 for
some geolocations over Antarctica, see
Fig. <xref ref-type="fig" rid="Ch1.F11"/>c). A study by
<xref ref-type="bibr" rid="bib1.bibx4" id="text.15"/> concludes that the snow/ice reflectance
significantly depends on various characteristics (e.g., grain size,
impurities, water content, surface roughness, snow age) and that large grain
sizes, high water content and soot/dust impurities can in fact effectively
decrease the reflectance in the visible spectral range associated with the
OCRA PR color, i.e., around 600–800 nm, to values well below 0.5. We assume
the low reflectances at some Antarctic geolocations to be associated to such
effects outlined above.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F12" specific-use="star"><caption><p>Yearly evolution of cloud-free reflectances in a normalized
rg-color-diagram for different surface types: <bold>(a)</bold> Vancouver Island,
<bold>(b)</bold> Alps, <bold>(c)</bold> Amazon rainforest, <bold>(d)</bold> Hudson Bay,
<bold>(e)</bold> Sahara and <bold>(f)</bold> South Atlantic Ocean. The square symbol
marks the white point of the normalized color diagram. The cloud-free scenes
in subsequent months are connected with solid black lines.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f12.png"/>

        </fig>

      <p>Since a proper construction of the cloud-free composites requires a large
amount of data and especially the largest possible temporal coverage, we use
GOME-2A for creating the cloud-free maps. The current GOME-2B data record is
still well below three years and simply too short to achieve enough
measurements per grid cell to derive stable cloud-free values at the given
grid cell resolution of 0.2 by 0.2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. Once the mission lifetime of
GOME-2B is above four to five years, we will create cloud-free composites
based on the GOME-2B data themselves to derive the GOME-2B OCRA cloud
fractions. Until then, the GOME-2A maps will be used for GOME-2B too.
Figure <xref ref-type="fig" rid="Ch1.F12"/> shows rg-diagrams of the
yearly temporal evolution of the cloud-free conditions for six different
surface types. It can be nicely seen that the normalized color of the
cloud-free background does not change significantly for the
Amazon rainforest, South Atlantic
Ocean and Sahara cases throughout the course of the year. In contrast, the
Vancouver, Alps and Hudson Bay cases show significant monthly changes of the
cloud-free background during the melting season (April–May–June) and the
beginning of winter with fresh snow (October–November–December). Also,
fresh snow seems to have lower Pr values (November, December) compared to old
snow (March).</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Cloud-fraction determination</title>
      <p>The determination of the radiometric cloud fraction with OCRA follows a
two-step process. The first part consists of the separation of a scene into a
contribution from the clouds and a cloud-free background and has been
described in Sect. <xref ref-type="sec" rid="Ch1.S3.SS1"/>. The second part involves a
comparison of the measured reflectance of a scene with its corresponding
cloud-free situation. This second step is now outlined in the rest of this
subsection.</p>
<sec id="Ch1.S3.SS2.SSS1">
  <?xmltex \opttitle{Matching the measurements to the\hack{\break} cloud-free grid}?><title>Matching the measurements to the<?xmltex \hack{\break}?> cloud-free grid</title>
      <p>In order to find the corresponding cloud-free reflectance for a measured
scene, we search for the grid cell of the composite map which contains the
central latitude and longitude of the measured pixel. The final cloud-free
value is determined via linear interpolation between the two monthly
cloud-free composite maps enclosing the observation. We assume a monthly
cloud-free map to correspond to the middle of the month. If a measurement is
dated in the first half of a month, we find the cloud-free value via linear
interpolation between the cloud-free maps of the previous and current month
and if the measurement is dated in the second part of a month, we obtain the
cloud-free value via linear interpolation between the cloud-free maps of the
current and next month.</p><?xmltex \hack{\newpage}?>
</sec>
<sec id="Ch1.S3.SS2.SSS2">
  <title>OCRA</title>
      <p>OCRA determines the cloud fraction using the differences between the colors
of a measured scene and its corresponding cloud-free values. Let <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>,
with <inline-formula><mml:math display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> R, G, B, be the wavelength ranges of the OCRA colors as
defined in Table <xref ref-type="table" rid="Ch1.T2"/>. Furthermore, let
<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> be the measured reflectances and
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> the cloud-free background values of the grid cell
corresponding to the geolocation of the measured reflectances. The
radiometric cloud fraction <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mtext>c</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is then obtained by the following
equation.
              <disp-formula id="Ch1.E6" content-type="numbered"><mml:math display="block"><mml:mrow><?xmltex \hack{\hbox\bgroup\fontsize{8.8}{8.8}\selectfont$\displaystyle}?><mml:mtable class="array" columnalign="left"><mml:mtr><mml:mtd><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mtext>c</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mo movablelimits="false">min⁡</mml:mo><mml:mo mathsize="2.5em" mathvariant="italic">{</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:mspace linebreak="nobreak" width="1em"/><mml:msqrt><mml:mrow><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mtext>R</mml:mtext><mml:mo>,</mml:mo><mml:mtext>G</mml:mtext><mml:mo>,</mml:mo><mml:mtext>B</mml:mtext></mml:mrow></mml:munder><mml:mi mathvariant="italic">α</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>⋅</mml:mo><mml:mo movablelimits="false">max⁡</mml:mo><mml:mo mathvariant="italic" mathsize="1.5em">{</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mo>,</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mo mathsize="1.5em" mathvariant="italic">}</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:msqrt><mml:mo mathsize="2.5em" mathvariant="italic">}</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable><?xmltex \hack{$\egroup}?></mml:mrow></mml:math></disp-formula>
            where the scaling factors <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">α</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> are determined by a histogram
analysis of the difference <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> at a
cumulative histogram value of 0.99.
              <disp-formula id="Ch1.E7" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mi mathvariant="italic">α</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msubsup><mml:mo>)</mml:mo><mml:mn>0.99</mml:mn><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:math></disp-formula>
            The offset values <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">β</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> are determined by a histogram
analysis of the difference <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> at the
mode of the normal histogram.
              <disp-formula id="Ch1.E8" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mi mathvariant="italic">β</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msub><mml:mo>)</mml:mo><mml:mtext>mode</mml:mtext></mml:msub></mml:mrow></mml:math></disp-formula>
            These parameters <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula> practically act as upper and lower
thresholds defining a fully clouded and a cloud-free scene, respectively.
They can also compensate for exceptionally bright situations (e.g., extreme
sun glint) and for exceptionally dark situations (e.g., shadowing effects,
darkening due to aerosols). The <inline-formula><mml:math display="inline"><mml:mrow><mml:mo>max⁡</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mo>,</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mrow><mml:mo>min⁡</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>,</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> functions in the
equation above ensure a mapping of the cloud fractions to the interval
<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>[</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mo>,</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>]</mml:mo></mml:mrow></mml:math></inline-formula>.</p>
      <p>The cloud-fraction determination is done separately for the P-based colors
(PB, PG, PR) and S-based colors (SB, SG, SR) and the final cloud fraction is
taken as the mean of the P- and S-based cloud fractions.</p>
      <p>For GOME-2A the scaling factors <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> and offset values <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula> are
determined from 29 test days spread over a 6-year period. Each test day uses
the same criteria: the scaling factor <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> via the 0.99 cumulative
histogram value of the difference <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>
and the offset value <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula> via the mode of the normalized histogram value of
<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. See
Fig. <xref ref-type="fig" rid="Ch1.F13"/> for an example. Over the 6-year time
base, there is no significant trend or variation seen in the parameters of
the 29 test days; hence we can use one fixed set of alphas and betas for the
whole mission (see Table <xref ref-type="table" rid="Ch1.T3"/>). For GOME-2B we use 6 test
days spread over a time period of 18 months to determine the scaling factors
and offset values.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F13"><caption><p>Determination of <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula> via histogram analysis of the
differences between the measured reflectance and the cloud-free reflectance.
This example shows GOME-2A data from 1 February 2007 for color B:
<bold>(a)</bold> <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula> is determined via the mode of the normalized histogram,
<bold>(b)</bold> <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> is determined via the reflectance difference at the
0.99 value of the cumulative histogram.</p></caption>
            <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f13.jpg"/>

          </fig>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T3"><caption><p>OCRA scaling factors and offset values for GOME-2A and GOME-2B.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry rowsep="1" namest="col3" nameend="col4" align="center">P-polarization </oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry rowsep="1" namest="col6" nameend="col7" align="center">S-polarization </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">Color</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6"><inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col7"><inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">B</oasis:entry>  
         <oasis:entry colname="col3">4.7</oasis:entry>  
         <oasis:entry colname="col4">0.033</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">4.8</oasis:entry>  
         <oasis:entry colname="col7">0.033</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">GOME-2A</oasis:entry>  
         <oasis:entry colname="col2">G</oasis:entry>  
         <oasis:entry colname="col3">2.6</oasis:entry>  
         <oasis:entry colname="col4">0.035</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">2.6</oasis:entry>  
         <oasis:entry colname="col7">0.035</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">R</oasis:entry>  
         <oasis:entry colname="col3">2.1</oasis:entry>  
         <oasis:entry colname="col4">0.020</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">2.1</oasis:entry>  
         <oasis:entry colname="col7">0.020</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">B</oasis:entry>  
         <oasis:entry colname="col3">3.15</oasis:entry>  
         <oasis:entry colname="col4">0.048</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">3.35</oasis:entry>  
         <oasis:entry colname="col7">0.047</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">GOME-2B</oasis:entry>  
         <oasis:entry colname="col2">G</oasis:entry>  
         <oasis:entry colname="col3">2.10</oasis:entry>  
         <oasis:entry colname="col4">0.039</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">2.25</oasis:entry>  
         <oasis:entry colname="col7">0.032</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">R</oasis:entry>  
         <oasis:entry colname="col3">2.00</oasis:entry>  
         <oasis:entry colname="col4">0.014</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">1.85</oasis:entry>  
         <oasis:entry colname="col7">0.019</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p>An example of a normalized rg-color diagram for a grid cell near Munich for
the month of April is shown in Fig. <xref ref-type="fig" rid="Ch1.F14"/> and contains 128
measurements which happened to be in this grid cell in the month of April during
the years 2007–2013. It is obvious that the strong variation of the
cloud-free condition from one month to the other (big star symbols in the
plot) call for an interpolation towards daily cloud-free values (small star
symbols in the plot).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F14"><caption><p>Normalized rg-color-diagram for an example 0.2 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.2 grid
cell (Munich, Latitude [48.0, 48.2], Longitude [11.6, 11.8]). This diagram
contains all measurements from April for the years 2007–2013. The black
square marks the white point at (1/3, 1/3). The big stars represent the
monthly cloud-free conditions for March (left filled star), April (filled
star) and May (right filled star) taken from the LUT. The small stars
represent daily cloud-free conditions for the month of April, found by linear
interpolation between the three LUT values for March, April and May. Each
measurement is color-coded with its resulting OCRA cloud fraction and
connected to its corresponding interpolated daily cloud-free condition via a
thin grey line.</p></caption>
            <?xmltex \igopts{width=184.942913pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f14.jpg"/>

          </fig>

</sec>
</sec>
<sec id="Ch1.S3.SS3">
  <title>Sun glint removal</title>

      <?xmltex \floatpos{t}?><fig id="Ch1.F15" specific-use="star"><caption><p>Sun glint factors for GOME-2A for 1 December 2012. If the sun glint
factor is below 25 (i.e., nonwhite in the plot), a measurement over water may
possibly be affected by sun glint.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f15.jpg"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F16" specific-use="star"><caption><p>Example of the performance of the OCRA sun-glint removal scheme for
GOME-2A data. A zoomed-in image of three orbits from 1 December 2012 in the
region is shown, covering roughly 120 to 180<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> west and 0 to
30<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S. Areas without coverage are shown in grey. Panels <bold>(a, b, c)</bold> show the
properties PSG, Stokes12 and PRPB, respectively. PSG is the ratio of PMD4 to
PMD3, Stokes12 represents the Stokes fraction of PMD12 and PRPB the ratio of
the OCRA colors PR and PB. Panels <bold>(d, e, f)</bold> depict OCRA cloud
fraction before sun glint removal, OCRA cloud fraction after sun glint
removal and cloud-fraction difference after sun glint removal, respectively.
See text for further details.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f16.jpg"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F17" specific-use="star"><caption><p>Global map with OCRA cloud fractions for 1 January 2013. The data
from both sensors, GOME-2A and GOME-2B, have been merged in this plot in
order to provide a daily, global cloud-fraction coverage without gaps between
the swaths.</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f17.jpg"/>

        </fig>

      <p>Under certain geometrical conditions, sunlight reflected by the ocean surface
may directly reach the satellite sensor enhancing the measured signal in
comparison to a nonaffected scene over water. This effect is called sun
glint. More details on this effect may be found in
<xref ref-type="bibr" rid="bib1.bibx10 bib1.bibx11" id="text.16"/> and applications to
spaceborne sensors are outlined in <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx29" id="text.17"/><?xmltex \hack{\egroup}?>,
<xref ref-type="bibr" rid="bib1.bibx9" id="text.18"/> and <xref ref-type="bibr" rid="bib1.bibx22" id="text.19"/>. Since clouds in the visual
appear bright, the sun glint will affect the OCRA cloud-fraction retrieval by
mimicking an enhanced cloud fraction. The flagging of measurements over
water, which may possibly be affected by sun glint, is purely based on
geometrical conditions. Due to the geometry of the MetOp-A/B orbits, sun
glint for GOME-2 can only appear in the eastern part of the swath. Based on the
solar zenith angle <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="normal">Θ</mml:mi><mml:mo>⊙</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula>, satellite zenith angle
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="normal">Θ</mml:mi><mml:mtext>sat</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, solar azimuth angle <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>⊙</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> and satellite
azimuth angle <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">φ</mml:mi><mml:mtext>sat</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, a sun glint factor <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ν</mml:mi></mml:math></inline-formula> is calculated:
            <disp-formula id="Ch1.E9" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mi mathvariant="italic">ν</mml:mi><mml:mo>=</mml:mo><mml:msqrt><mml:mrow><mml:mo>(</mml:mo><mml:mfenced close="|" open="|"><mml:msub><mml:mi mathvariant="normal">Θ</mml:mi><mml:mo>⊙</mml:mo></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="normal">Θ</mml:mi><mml:mtext>sat</mml:mtext></mml:msub></mml:mfenced><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">φ</mml:mi><mml:mtext>sat</mml:mtext></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>⊙</mml:mo></mml:msub><mml:mo>-</mml:mo><mml:mn>180</mml:mn><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:msqrt><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          OCRA raises a flag of possible sun glint if <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ν</mml:mi></mml:math></inline-formula> is below a certain
threshold <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ν</mml:mi><mml:mtext>thres</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, which was determined empirically and set to 25,
and if the measurement is over water. For each orbit, this results in roughly
ellipsoidal-shaped regions in the eastern part of the swath which have an
extension of roughly 30<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> in latitudinal and 10<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> in
longitudinal direction. The possibility for sun glint increases the closer
the measurement is to the center of the ellipse. This is illustrated in
Fig. <xref ref-type="fig" rid="Ch1.F15"/>. The latitudinal location of the ellipse
depends on the season and reaches its highest latitudes in June/July,
extending roughly from <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>60 to <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>20<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. The lowest latitudes are
reached in December/January, extending roughly from 0 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>40<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>.</p>
      <p>Based on <xref ref-type="bibr" rid="bib1.bibx17" id="text.20"/> and in addition to flagging possible sun
glint situations, we also improved the algorithm to find a correction for the
affected scenes. To do so, we need to distinguish whether a retrieved cloud
fraction is in fact due a cloud or if it is mimicked by sun glint (which can
only appear in the absence of clouds under clear-sky conditions). For
measurements, which may possibly be affected by sun glint and also are over
water, the following steps are undertaken. First we consider a cloud-fraction
threshold of 0.1. Sun glint is only corrected above this threshold, meaning
that we assume sun glint to cause cloud-fraction signals above 0.1. Next, we
introduce three quantities which are capable of distinguishing clouds from sun
glint if they are used in concert. One is a reflectance ratio in the blue
spectral part. We use the ratio of PMD4 to PMD3 (see
Table <xref ref-type="table" rid="Ch1.T1"/>). The second is the Stokes fraction (see
Sect. 3.7 in <xref ref-type="bibr" rid="bib1.bibx19" id="altparen.21"/>, for further information) in the red
(PMD12) and the third is the ratio of the OCRA colors PR/PB (see
Table <xref ref-type="table" rid="Ch1.T2"/>). Let us call these three indicators PSG,
Stokes12 and PRPB. PSG separates cloudy and sun glint scenes
from clear scenes if the scene reflectance is above a certain threshold. The
other two indicators distinguish clouds from sun glint. If the absolute value
of Stokes12 is below an empirically determined threshold, the signal will be
due to clouds and cannot be due to sun glint. This is based on the assumption
that clouds tend to be depolarizing, due to multiple scattering, and the
Stokes fraction will therefore be close to zero for cloudy scenes. A detailed
investigation of GOME-2 polarization spectra and the influence of clouds on
the Stokes fraction is presented in <xref ref-type="bibr" rid="bib1.bibx24" id="text.22"/>. Finally, if the
value of the third indicator PRPB is below an empirically determined
threshold, the signal will be likely due to a cloud. Thus combining these
three criteria, we are able to distinguish between cloud and sun glint, and
hence correct for it (the cloud fraction is set to zero in this case). The
three quantities used in our sun glint removal procedure are shown together
with the cloud fractions before and after sun glint removal for a test scene
in Fig. <xref ref-type="fig" rid="Ch1.F16"/>. Note that the bright ellipsoidal sun
glint signals are successfully removed in panel e without affecting the true
cloud signals. The empirical thresholds are given below.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F18" specific-use="star"><caption><p>Monthly <bold>(a)</bold> zonal and <bold>(b)</bold> meridional OCRA cloud
fractions from GOME-2A and GOME-2B based on all data from the month of January
2013, i.e., where both instruments operated in the full 1920 km nominal swath
mode.</p></caption>
          <?xmltex \igopts{width=412.564961pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f18.jpg"/>

        </fig>

      <p><list list-type="bullet">
            <list-item>
              <p>PSG <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.050, abs(Stokes12) <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.125, PRPB <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.15 for GOME-2A data before 11 March 2008 (i.e., valid for PMD Def. 1.0),</p>
            </list-item>
            <list-item>
              <p>PSG <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.080, abs(Stokes12) <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.125, PRPB <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.15 for GOME-2A data after 11 March 2008 (i.e., valid for PMD Def. 3.1),</p>
            </list-item>
            <list-item>
              <p>PSG <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.995, abs(Stokes12) <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.100, PRPB <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.00 for GOME-2B data.</p>
            </list-item>
          </list>Subplot f basically shows which measurements inside the ellipse defined by
the geometrical conditions are affected by sun glint and the color scale
gives a measure for the strength of the sun glint, i.e., virtual cloud
fraction caused by sun glint. Note that the enhanced reflectance due to
sun glint may mimic a large virtual cloud fraction in small localized regions
(e.g., the bright feature seen at 15<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S and 155<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W) whereas
the smoother part spread over the whole sun glint area causes virtual cloud
fractions pronounced in the range around 0.1 to 0.3. A flag is set for each
measurement where a sun glint correction was applied (all pixels with a cloud-fraction difference larger than 0.1 in panel f of
Fig. <xref ref-type="fig" rid="Ch1.F16"/>). For all quantities involved, we use the
corrected reflectances as outlined in
Sect. <xref ref-type="sec" rid="Ch1.S2.SS2"/>.</p>
      <p>A similar approach to investigating sun glint in GOME-2 data has already been
presented by <xref ref-type="bibr" rid="bib1.bibx17" id="text.23"/> and <xref ref-type="bibr" rid="bib1.bibx1" id="text.24"/>.</p>
      <p>An example for a full day of OCRA cloud fractions after sun glint filtering,
based on GOME-2A and GOME-2B data merged together, is shown in
Fig. <xref ref-type="fig" rid="Ch1.F17"/>.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <title>Results</title>
      <p>The following subsections present the results of several comparison studies.
The OCRA cloud fractions are intercompared for both sensors, GOME-2A and
GOME-2B, as well as for both polarization cases. Furthermore, comparisons of
the OCRA cloud fractions to those of AVHRR and FRESCO have been carried out.</p>
<sec id="Ch1.S4.SS1">
  <title>Comparison of OCRA cloud fractions from GOME-2A and GOME-2B</title>

      <?xmltex \floatpos{t}?><fig id="Ch1.F19" specific-use="star"><caption><p>OCRA cloud fractions based on GOME-2A data vs. those based on
GOME-2B data for all measurements within January 2013. Panel <bold>(a)</bold> is
for the original GOME-2B reflectances and <bold>(b)</bold> is based on the
homogenized GOME-2B reflectances, which have been adjusted to the GOME-2A
reflectances.</p></caption>
          <?xmltex \igopts{width=312.980315pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f19.jpg"/>

        </fig>

      <p>For one full month of data, January 2013, the OCRA cloud fractions based on
GOME-2A data are compared to those based on GOME-2B data. This time frame was
chosen because both instruments operated in full swath mode at that time;
hence, the most similar geographic coverage possible is established.
Figure <xref ref-type="fig" rid="Ch1.F18"/> shows the monthly mean cloud
fractions for GOME-2A and GOME-2B, subdivided into 10-degree wide zonal bins
(subplot a) and 30-degree wide meridional bins (subplot b). Three data
sets are used to generate this figure: OCRA cloud fractions based on GOME-2A
reflectances (blue data points), OCRA cloud fractions based on GOME-2B
reflectances (green data points) and OCRA cloud fractions based on shifted
GOME-2B reflectance data (red data points). The shifted GOME-2B reflectance
data have been generated in order to homogenize with GOME-2A reflectances.
The shift was determined in the following way: for 30 full days of data
spread over a 60-day time range, the offset between the mean global
reflectance in the latitude range from 60<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S to 60<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N has
been determined separately for GOME-2A and GOME-2B for all three OCRA colors.
The GOME-2B reflectances, used to retrieve the green data points, have then
been shifted by the mean offset in order to generate the homogenized GOME-2B
reflectances used to retrieve the red data points.
Figure <xref ref-type="fig" rid="Ch1.F19"/> shows the correlation of the cloud-fraction data mentioned above for the cases based on original GOME-2B
reflectances (<inline-formula><mml:math display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis in panel a) and homogenized GOME-2B reflectances
(<inline-formula><mml:math display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis in panel b). It should also be noted here that a direct PMD pixel
to PMD pixel comparison between GOME-2A and GOME-2B is not possible since the
ground tracks are not the same and the temporal coverage is not the same. The
former makes it necessary to regrid the data on a common grid before
comparison and the latter is a nonavoidable error source since clouds may
have moved during that time. Both effects together may pose a significant
error source.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <title>Comparison of OCRA cloud fractions for P- and S-polarization</title>

      <?xmltex \floatpos{t}?><fig id="Ch1.F20"><caption><p>Comparison of P-pol-based OCRA cloud fractions to S-pol-based OCRA
cloud fractions for GOME-2A for 1 February 2007. The correlation plot in
<bold>(a)</bold> shows a very high agreement with a correlation coefficient of
0.9998. The solid black line is the 1 : 1 line and the dashed white line is
a fit with the parameters indicated in the plot. The absolute cloud-fraction
differences are plotted on a world map in <bold>(b)</bold>.</p></caption>
          <?xmltex \igopts{width=199.169291pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f20.png"/>

        </fig>

      <p>Most plots in the previous sections are only shown for reflectances based on
the P-pol PMD data. Only in the final cloud-fraction map,
Fig. <xref ref-type="fig" rid="Ch1.F17"/>, the mean of the P-pol-based and S-pol-based
data are used. Larger discrepancies between the two polarization states do
appear for instrumental degradation and scan-angle dependencies. Since these
effects are corrected during the reflectance normalization, the discrepancies
do not translate to the cloud-fraction determination. Hence, the cloud
fractions based on using only P-pol PMD data do not significantly differ from
those based on S-pol PMD data (this is evident in
Fig. <xref ref-type="fig" rid="Ch1.F20"/>, which states a correlation coefficient
<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>R</mml:mi><mml:mo>=</mml:mo><mml:mn>0.9998</mml:mn></mml:mrow></mml:math></inline-formula> and a standard error of 0.00002 for the linear fit). The same
holds true for the cloud-free maps, because these are also generated based on
those reflectances which are corrected for instrumental degradation and scan-angle dependencies.</p><?xmltex \hack{\newpage}?>
</sec>
<sec id="Ch1.S4.SS3">
  <title>Comparison with AVHRR data</title>

      <?xmltex \floatpos{t}?><fig id="Ch1.F21" specific-use="star"><caption><p>Comparison of GOME-2A OCRA cloud fractions <bold>(a)</bold> with
colocated AVHRR cloud fractions <bold>(c)</bold> for 1 December 2012. The
absolute differences are plotted in <bold>(b)</bold> while subplot <bold>(d)</bold>
shows the correlation. The solid black line is the 1 : 1 identity and the
dashed line represents a linear fit with the parameters specified in the
plot.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f21.jpg"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F22" specific-use="star"><caption><p>Histograms of OCRA and AVHRR cloud fractions for MetOp-A on
1 December 2012 are shown in <bold>(a)</bold>, while a histogram of the cloud-fraction differences is plotted in <bold>(b)</bold>.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f22.jpg"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F23" specific-use="star"><caption><p>Comparison of OCRA <bold>(a)</bold> and AVHRR <bold>(b)</bold> cloud
fractions for MetOp-B on 1 May 2014. The colocated AVHRR data for the GOME-2
PMD footprints were taken from the PMAp product (see text for further
details).</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f23.jpg"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F24" specific-use="star"><caption><p>Panels <bold>(a, b)</bold> show a comparison of OCRA (blue) and AVHRR
(green) cloud-fraction histograms for MetOp-B on 1 May 2014. Panels
<bold>(c, d)</bold> show histograms of the cloud-fraction difference OCRA minus
AVHRR. All PMAp measurements are included in <bold>(a, c)</bold> but only PMAp
measurements with a COD larger than 5 and CF smaller than 0.95 are considered in
<bold>(b, d)</bold>.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f24.jpg"/>

        </fig>

      <p>We compared 12 days of OCRA data from GOME-2A/B with data from the AVHRR
(advanced very high resolution radiometer) instrument, which is mounted on
the same platform as the GOME-2 instruments, i.e., on MetOp-A and MetOp-B.
AVHRR is an across-track scanner sensing the radiation backscattered from
Earth in six channels from the visible/near-infrared range towards the
thermal infrared. The spatial resolution is 1 km at nadir. Based on the
dedicated cloud-test results provided with the AVHRR level-1B files, the
geometrical cloud fraction for one GOME-2 PMD pixel is derived as the
fraction of the sum of all cloudy pixels to the total number of AVHRR pixels
collocated within one GOME-2 PMD pixel. This AVHHR cloud fraction is then
added as an extra field to the GOME-2 level-1B file. In early 2014, R. Lang
(EUMETSAT) provided 12 test days of collocated AVHRR geometrical cloud
fractions to GOME-2 PMD pixels. These comprise the first day of each month
between December 2012 and November 2013. Here we compare the GOME-2A OCRA
radiometric cloud fractions for 1 December 2012 with the collocated AVHRR
geometrical cloud fractions. Figure <xref ref-type="fig" rid="Ch1.F21"/> shows the
OCRA (panel a) and AVHRR (panel c) cloud fractions for MetOp-A on a world
map. The absolute differences are plotted in panel b) and a correlation map
is found in panel d). The overall large-scale cloud structures are very
similar in both products. Although the linear correlation is relatively high
(linear correlation coefficient of <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>R</mml:mi><mml:mo>=</mml:mo><mml:mn>0.88</mml:mn></mml:mrow></mml:math></inline-formula>, see bottom right panel),
differences appear as a systematic offset towards larger AVHRR cloud
fractions of roughly 0.16. This may be explained by the fact that UVN
radiances from GOME-2 are less sensitive to clouds with low optical
thickness (e.g., cirrus clouds) compared to NIR or thermal infrared radiances
from AVHRR. In Fig. <xref ref-type="fig" rid="Ch1.F22"/>, histograms of the cloud
fractions based on OCRA and AVHRR are plotted in panel a. Panel b shows a
histogram of the cloud-fraction differences between OCRA and AVHRR for the
same day (1 December 2012). The histogram of the cloud-fraction differences
has a mean and a standard deviation of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.15 and 0.20, respectively, and
looks very similar to the histogram shown in the right panel of Fig. 4 in
<xref ref-type="bibr" rid="bib1.bibx16" id="text.25"/>. The latter compares OCRA cloud
fractions derived from the GOME (Global Ozone Monitoring Experiment)
instrument on ERS-2 (European Remote Sensing 2 Satellite) and the SEVIRI
(Spinning Enhanced Visible and Infrared Imager) instrument on MSG (METEOSAT
Second Generation) and finds a mean difference of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.21 with a standard
deviation of 0.26. Since GOME is not sensitive to optically thin clouds, but
SEVIRI is, the situation is very similar to the comparison of the
GOME-2/AVHRR pair. One possibility for circumventing these different cloud
sensitivities and achieving a better agreement is to filter the clouds with low
optical thickness (below a certain threshold) from the AVHRR or SEVIRI data.
For the latter case this has been done in the left panel of Fig. 4 by
<xref ref-type="bibr" rid="bib1.bibx16" id="text.26"/> and results in a much better agreement
of the GOME and SEVIRI data. Concerning GOME-2 and AVHRR, a similar cloud
optical thickness filtering of the AVHRR data is outlined in the following
subsection.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F25" specific-use="star"><caption><p>Zonal mean cloud fractions for 1 May 2014 for MetOp-A and MetOp-B
based on OCRA and AVHRR cloud fractions. The solid lines represent the
unfiltered data while the dashed lines represent the data after filtering out
cloud fractions with a COD smaller than 5 and a CF larger than 0.95.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f25.jpg"/>

        </fig>

      <?xmltex \floatpos{p}?><fig id="Ch1.F26" specific-use="star"><caption><p>Intercomparison of OCRA radiometric, FRESCO effective and AVHRR
geometric cloud fractions gridded to a common spatial grid of 1-degree in
latitude and longitude. The data are from 1 May 2014. Panels
<bold>(a, b, c)</bold> show the OCRA, FRESCO and AVHRR cloud fractions,
respectively. In all cases the data from both MetOp-A and MetOp-B have been
merged. For grid cells containing multiple measurements, the resulting cloud
fraction is an average. Panel <bold>(d)</bold> illustrates zonal mean cloud
fractions separately for MetOp-A and MetOp-B. Note that for <bold>(d)</bold> only
those grid cells from <bold>(a, b, c)</bold>, which contain valid values
for all three cases (OCRA and FRESCO and AVHRR), are used. The latitude bands have a
width of 10 degrees.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f26.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F27"><caption><p>Simulated OCRA RGB colors in a normalized rg-color diagram. The
theoretical white point at (1/3, 1/3) is shown as a black square and the red
dots represent fully cloudy scenes for various cloud types and observation
geometries. See text for further details on the simulations.</p></caption>
          <?xmltex \igopts{width=184.942913pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f27.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F28" specific-use="star"><caption><p>OCRA radiometric cloud fractions for GOME-2A for 1 December 2012
based on reflectances <bold>(a)</bold> without corrections for viewing angle
dependencies and <bold>(b)</bold> with corrections for viewing angle dependencies
as outlined in Sect. <xref ref-type="sec" rid="Ch1.S2.SS2.SSS2"/>.
Subplot <bold>(c)</bold> shows the absolute difference of the cloud fractions in
<bold>(a, b)</bold>. In the example shown here, the effect of the correction is
particularly prominent in the western part of the swaths.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://amt.copernicus.org/articles/9/2357/2016/amt-9-2357-2016-f28.png"/>

        </fig>

<sec id="Ch1.S4.SS3.SSS1">
  <title>Cloud optical thickness filter</title>
      <p>Since May 2014, EUMETSAT provides the AVHRR cloud fraction colocated to the
GOME-2 PMD footprints as an operational (but not yet validated) product. This
EUMETSAT polar multi-sensor aerosol product (PMAp) provides the cloud optical
depth (COD) in addition to the cloud fraction <xref ref-type="bibr" rid="bib1.bibx7" id="paren.27"/>.</p>
      <p>A comparison of the OCRA cloud fractions with the AVHRR cloud fractions taken
from this PMAp product is shown in Fig. <xref ref-type="fig" rid="Ch1.F23"/> for data
from 1 May 2014. Both data sets are matched to a common lat/lon grid of
0.4<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> resolution. As before, the general large-scale cloud structures
agree very well. To account for GOME-2 insensitivity to low optical thickness
clouds, we filtered out all AVHRR cloud-fraction measurements which have a
COD smaller than 5. Additionally, all cloud fractions larger than 0.95 are
rejected in order to avoid ambiguities due to different treatments of the
cloud fraction over snow/ice scenes where the AVHRR cloud fraction is set to
1. The effect of this treatment is visible in
Fig. <xref ref-type="fig" rid="Ch1.F24"/>. Note that in panel a there are many
CF <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1 cases for AVHRR which are considerably less for OCRA. The major
contribution to these large deviations comes from polar regions (this is also
obvious in Fig. <xref ref-type="fig" rid="Ch1.F23"/>). In the histograms of the cloud
fractions (panels a and b) and histograms of the cloud-fraction differences
(panels c and d) visualized in Fig. <xref ref-type="fig" rid="Ch1.F24"/> it is
noted that the COD and CF filtering is able to remove the strong asymmetry
seen in panel c), but the rather large systematic offset (<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.24 in this
case) still remains in panel d). Finally,
Fig. <xref ref-type="fig" rid="Ch1.F25"/> nicely illustrates that this
systematic offset between the radiometric (GOME-2) and the geometric (AVHRR)
zonal mean cloud fractions has the same sign over the whole latitude range.
For all latitude bands considered, the AVHRR cloud fraction is larger than
the OCRA cloud fraction.</p>
</sec>
</sec>
<sec id="Ch1.S4.SS4">
  <title>Comparison with L1 FRESCO data</title>
      <p>Since the GOME-2 level 1 data also contain the effective cloud fraction based
on the FRESCO algorithm, Fig. <xref ref-type="fig" rid="Ch1.F26"/> shows an
intercomparison of OCRA, FRESCO and AVHRR cloud fractions, both for MetOp-A
and MetOp-B, on 1 May 2014. The OCRA and AVHRR data are given for the
10 km <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 40 km PMD footprint resolution, whereas the FRESCO data
are given in the nominal 80 km <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 40 km ground pixel resolution.
For the maps shown in panels a, b and c of
Fig. <xref ref-type="fig" rid="Ch1.F26"/>, all data have therefore been regridded
to a common spatial grid of one degree resolution in latitude and longitude.
Subplot d of Fig. <xref ref-type="fig" rid="Ch1.F26"/> illustrates the zonal mean
cloud fractions for the same data, but separately for MetOp-A and MetOp-B.</p>
</sec>
</sec>
<sec id="Ch1.S5">
  <title>Discussion</title>
      <p>A known issue for cloud-fraction retrieval algorithms in the UVN wavelength
range is the performance over very bright surfaces like snow or ice. In such
cases, external databases of daily snow/ice cover are often incorporated, the
affected scenes are flagged, given an arbitrary cloud-fraction value (e.g.,
1) and an effective scene albedo is retrieved instead. In OCRA, the cloud
fraction is calculated regardless of the surface condition. For the snow/ice
scenes mentioned above, this requires the cloud-free background maps to be as
close as possible to the current surface situation in order to represent the
cloud fraction over snow/ice as realistically as possible. As mentioned
before, the cloud-free reflectances for the OCRA RGB colors for a particular
grid cell are interpolated towards a daily value in between two monthly
cloud-free maps. If we imagine that the cloud-free reflectance of a
particular grid cell represents a snow/ice situation (i.e., higher background)
and in the same cell the snow/ice is melted in the next month (i.e., lower
background), OCRA's linear interpolation scheme may introduce some
uncertainties since snow/ice melting and particularly new snow/ice coverage
may happen on shorter timescales than 30 days. If melting or new snow occurs
within the timescale of days, it would of course be better to have e.g., weekly
cloud-free maps, but for this, there are simply not enough data available.
Hence, monthly maps with linear interpolation was found to be a reasonable
trade-off that can be done given the current combination of time base, grid
cell size and PMD pixel size. The effect of melting seasons and fresh snow
coverage on the cloud-free background was shown in
Fig. <xref ref-type="fig" rid="Ch1.F12"/>. In this figure, it can also
be seen that even for snow/ice surfaces the cloud-free background does not
coincide with the white point of the rg-diagram, which is why OCRA can also
retrieve the cloud fraction for these cases instead of setting an arbitrary
value. However, OCRA may slightly underestimate the cloud fraction in these
cases due to the fact that the scaling factor <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> is optimized for all
possible surface conditions and not for snow/ice conditions alone. From the
operational point of view it is desirable to have as few input
parameters to OCRA as possible (e.g., only one set of scaling factors for all surface
conditions), but in this case separate scaling factors for the different
surface types (e.g., permanent ice, sea ice, snow, desert, water, land) are
considered to be included in a future update to the OCRA algorithm.</p>
      <p>An alternative to choosing the maximum distance in the rg-diagram as in the
cloud-free situation would be to do a histogram analysis of
<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>CF</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> for each individual grid cell.
This would work fine for gaussian distributions (grid cells without strong
surface condition variations) but would also cause problems if the
distribution is bimodal or multimodal (grid cells with seasonal changes of
the surface conditions).</p>
      <p>Further attempts have been undertaken in order to distinguish snow/ice from
clouds. It was noticed that the difference between the P-pol-based OCRA cloud
fraction and the S-pol-based OCRA cloud fraction depends slightly on the
underlying surface. As can be seen in panel b of
Fig. <xref ref-type="fig" rid="Ch1.F20"/>, the cloud-fraction difference of the P-pol-based
cloud fraction minus the S-pol-based cloud fraction seems to be
particularly negative (blue in the plot) over snow/ice covered surfaces, e.g.,
Antarctica, Hudson Bay, Greenland, Siberia. Being an interesting aspect, this
approach to identifying snow/ice via the cloud fractions based on different
polarization states may be pursued further in future work.</p>
      <p>Figure <xref ref-type="fig" rid="Ch1.F27"/> presents simulated OCRA RGB colors
plotted in a normalized rg-color diagram for a set of fully cloudy scenes. In
the simulations, which have been performed with libRadtran
<xref ref-type="bibr" rid="bib1.bibx18" id="paren.28"/> for a grass surface, various cloud optical
thicknesses (10, 15, 30, 50) have been considered for a solar zenith angle of
30<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>, viewing zenith angles of 0, 25.8 and 36.9<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> and relative
azimuth angles of 0, 30, 60 and 90<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>.
Figure <xref ref-type="fig" rid="Ch1.F27"/> clearly shows that the fully cloudy
scenes slightly scatter around the theoretical white point value. This
behavior is also seen in the normalized rg-color diagram based on the
measured data in Fig. <xref ref-type="fig" rid="Ch1.F14"/>, where the cloudy scenes also
slightly deviate from the theoretical (1/3, 1/3) location.</p>
      <p>Finally, the effect of correcting the reflectances for scan angle
dependencies is illustrated in
Fig. <xref ref-type="fig" rid="Ch1.F28"/> and the improvement
in subplot b compared to subplot a clearly demonstrates the necessity of
performing the corrections outlined in
Sect. <xref ref-type="sec" rid="Ch1.S2.SS2.SSS2"/>.</p>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <title>Conclusions</title>
      <p>We have presented version 3.0 of the OCRA cloud-fraction algorithm applied to
data measured with the GOME-2 instrument onboard the MetOp satellites.
Improvements with regard to the previous OCRA version include a degradation
correction of the PMD reflectances as well as corrections for scan angle and
latitudinal dependencies. In addition, the cloud-free composite maps are now
based on more than six years of GOME-2A data. An improved sun glint flagging
and removal has been implemented, which now also considers the Stokes
fraction and an additional color ratio in order to distinguish between sun
glint and real clouds.</p>
      <p>The PMD-based OCRA cloud fractions have been compared to collocated AVHRR
cloud fractions and show a good general agreement. However, a systematic
offset is attributed to different sensitivities to low optical thickness
clouds due to the different spectral ranges covered by the GOME-2 and AVHRR
instruments.</p>
      <p>In addition to the simple OCRA color space approach, which does not need
expensive radiative transfer modeling, another advantage of OCRA lies in its
very fast computational performance. This is especially relevant for
providing products in near real time. All external input, like the cloud-free
reflectance composite maps, are precalculated look-up tables (LUTs) and do
not need to be calculated online. The radiometric cloud fractions for a full
GOME-2 orbit with around 120 000 single PMD measurements are calculated in
only <inline-formula><mml:math display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 20 s (operational). The OCRA algorithm was used for the
generation of operational products from GOME and SCIAMACHY and is not limited
to PMD data, but can also be used with normal radiance data (e.g., OMI,
TROPOMI). At the beginning of a new mission, cloud-free reflectance
composites from a predecessor mission can be used as an initial input. As
soon as a sufficient amount of data is collected to minimize residual cloud
contamination, the cloud-free reflectance composite maps will be based on the
same instrument.</p>
</sec>

      
      </body>
    <back><ack><title>Acknowledgements</title><p>The authors would like to thank Rüdiger Lang (EUMETSAT) for providing the
AVHRR test data colocated to the GOME-2 PMD footprints. The PMAp data used
in this work have been acquired using the EUMETSAT Earth Observation Portal
<uri>https://eoportal.eumetsat.int/</uri>. Part of this work was related to the
TROPOMI/S5P project and was supported by the Bavarian Ministry of Economic
Affairs and Media, Energy and Technology grant 07 03/893 73/5/2013. Finally,
the authors thank the anonymous reviewers for their fruitful inputs and
suggestions which helped to improve this manuscript.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?> The article processing charges for this open-access
<?xmltex \hack{\newline}?> publication were covered by a Research <?xmltex \hack{\newline}?> Centre
of the Helmholtz Association.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?> Edited by:
A. Kokhanovsky</p></ack><ref-list>
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    </app></app-group></back>
    <!--<article-title-html>OCRA radiometric cloud fractions for GOME-2 on MetOp-A/B</article-title-html>
<abstract-html><p class="p">This paper describes an
approach for cloud parameter retrieval (radiometric cloud-fraction
estimation) using the polarization measurements of the Global Ozone
Monitoring Experiment-2 (GOME-2) onboard the MetOp-A/B satellites. The core
component of the Optical Cloud Recognition Algorithm (OCRA) is the
calculation of monthly cloud-free reflectances for a global grid (resolution
of 0.2° in longitude and 0.2° in latitude) to derive
radiometric cloud fractions. These cloud fractions will serve as a priori
information for the retrieval of cloud-top height (CTH), cloud-top pressure
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approach is already being implemented operationally for the GOME/ERS-2 and
SCIAMACHY/ENVISAT sensors and here we present version 3.0 of the OCRA
algorithm applied to the GOME-2 sensors.</p><p class="p">Based on more than five years of GOME-2A data (April 2008 to June 2013),
reflectances are calculated for  ≈  35 000 orbits. For each
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latitude-dependent correction is applied. In addition, an empirical
correction scheme is introduced in order to remove the effect of oceanic sun
glint. A comparison of the GOME-2A/B OCRA cloud fractions with colocated
AVHRR (Advanced Very High Resolution Radiometer) geometrical
cloud fractions shows a general good agreement with a mean difference of
−0.15 ± 0.20.</p><p class="p">From an operational point of view, an advantage of the OCRA algorithm is its
very fast computational time and its straightforward transferability to
similar sensors like OMI (Ozone Monitoring Instrument), TROPOMI (TROPOspheric
Monitoring Instrument) on Sentinel 5 Precursor, as well as Sentinel 4 and
Sentinel 5.</p><p class="p">In conclusion, it is shown that a robust, accurate and fast radiometric cloud-fraction estimation for GOME-2 can be achieved with OCRA using
polarization measurement devices (PMDs).</p></abstract-html>
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