Preprints
https://doi.org/10.5194/amt-2021-433
https://doi.org/10.5194/amt-2021-433

  05 Jan 2022

05 Jan 2022

Review status: this preprint is currently under review for the journal AMT.

Long-term behavior and stability of calibration models for NO and NO2 low cost sensors

Horim Kim1, Michael Müller1,a, Stephan Henne1, and Christoph Hüglin1 Horim Kim et al.
  • 1Laboratory for Air Pollution and Environmental Technology, Empa, 8600 Dübendorf, Switzerland
  • anow at: Amt für Geoinformation, Kanton Basel-Landschaft, 4410 Liestal, Switzerland

Abstract. Low-cost sensors are considered as exhibiting great potential to complement classical air quality measurements in existing monitoring networks. However, the use of low-cost sensors poses some challenges. In this study, the behavior and performance of electrochemical sensors for NO and NO2 were determined over a longer operating period in a real-world deployment. After careful calibration of the sensors, based on co-location with reference instruments at a rural traffic site during six months and by using robust linear regression and random forest regression, the coefficient of determination of both types of sensors were high (R2 > 0.9) and the root mean square error (RMSE) of NO and NO2 sensors were about 6.8 ppb and 3.5 ppb, respectively, for 10-minute mean concentrations. The RMSE of the NO2 sensors, however, more than doubled, when the sensors were deployed without re-calibration for a one-year period at other site types (including urban background locations), where the range and the variability of air pollutant concentrations differed from the calibration site. This indicates a significant effect of the re-location of the sensors on the quality of their data. During deployment, we found that the NO2 sensors are capable of distinguishing general pollution levels, but they proved unsuitable for accurate measurements, mainly due to significant biases. In order to investigate the long-term stability of the original calibration, the sensors were re-installed at the calibration site after deployment. Surprisingly, the coefficient of determination and the RMSE of the NO sensor remained almost unchanged after more than one year of operation. In contrast, the performance of the NO2 sensors clearly deteriorated as indicated by a higher RMSE (about 7.5 ppb, 10-minute mean concentrations) and a lower coefficient of determination (R2 = 0.59).

Horim Kim et al.

Status: open (until 10 Feb 2022)

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Horim Kim et al.

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Short summary
In this study, the performance of electrochemical sensors for NO and NO2 for measuring air quality was determined over a longer operating period. The performance of NO sensors remained reliable for more than 18 months. However, the NO2 sensors showed decreasing performance over time. During deployment, we found that the NO2 sensors can distinguish general pollution levels, but they proved unsuitable for accurate measurements due to significant biases.