Articles | Volume 10, issue 4
https://doi.org/10.5194/amt-10-1373-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-10-1373-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
11 Apr 2017
Research article |
| 11 Apr 2017
New insights into atmospherically relevant reaction systems using direct analysis in real-time mass spectrometry (DART-MS)
Department of Chemistry, University of California, Irvine, CA 92697, USA
currently at: Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Michelle C. Fairhurst
Department of Chemistry, University of California, Irvine, CA 92697, USA
Lisa M. Wingen
Department of Chemistry, University of California, Irvine, CA 92697, USA
Véronique Perraud
Department of Chemistry, University of California, Irvine, CA 92697, USA
Michael J. Ezell
Department of Chemistry, University of California, Irvine, CA 92697, USA
Barbara J. Finlayson-Pitts
CORRESPONDING AUTHOR
Department of Chemistry, University of California, Irvine, CA 92697, USA
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Cited
21 citations as recorded by crossref.
- Molecular Characterization of Atmospheric Organic Aerosol by Mass Spectrometry M. Johnston & D. Kerecman 10.1146/annurev-anchem-061516-045135
- Probing surfaces of atmospherically relevant organic particles by easy ambient sonic-spray ionization mass spectrometry (EASI-MS) L. Wingen & B. Finlayson-Pitts 10.1039/C8SC03851A
- A cautionary note on the effects of laboratory air contaminants on ambient ionization mass spectrometry measurements S. Kumbhani et al. 10.1002/rcm.7951
- Online molecular characterisation of organic aerosols in an atmospheric chamber using extractive electrospray ionisation mass spectrometry P. Gallimore et al. 10.5194/acp-17-14485-2017
- Using Nanoparticle X-ray Spectroscopy to Probe the Formation of Reactive Chemical Gradients in Diffusion-Limited Aerosols M. Jacobs et al. 10.1021/acs.jpca.9b04507
- Analysis of Atmospheric Particles: From the Bulk to the Interface T. Lei et al. 10.1021/acs.analchem.4c06795
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Compositional evolution of particle-phase reaction products and water in the heterogeneous OH oxidation of model aqueous organic aerosols M. Chim et al. 10.5194/acp-17-14415-2017
- Role of Gas-Phase Halogen Bonding in Ambient Chemical Ionization Mass Spectrometry Utilizing Iodine J. Ganske et al. 10.1021/acsearthspacechem.9b00030
- High‐throughput bioanalysis of sitagliptin in plasma using direct analysis in real time mass spectrometry and its application in the pharmacokinetic study thereof Y. Liu et al. 10.1002/jssc.202100461
- The chemical reactions in electrosprays of water do not always correspond to those at the pristine air–water interface A. Gallo et al. 10.1039/C8SC05538F
- Distinct Temperature Trends in the Uptake of Gaseous n-Butylamine on Two Solid Diacids Y. Li et al. 10.1021/acsestair.3c00032
- Investigating the Kinetics of Heterogeneous Lipid Ozonolysis by an Online Photoionization High-Resolution Mass Spectrometry Technique P. Liu et al. 10.1021/acs.analchem.4c04404
- Investigation of solvent microparticle formation in spray ionization–quadrupole ion trap–mass spectrometry A. Özdemir et al. 10.1002/jms.4785
- Knudsen cell studies of the uptake of gaseous ammonia and amines onto C3–C7 solid dicarboxylic acids M. Fairhurst et al. 10.1039/C7CP05252A
- Separation of Pimelic Acid Using Tri-n-octylamine in Various Organic Solvents by Reactive Extraction: Equilibrium and Modeling H. Zeidan et al. 10.1021/acs.jced.1c00633
- CHEMICAL REACTION MONITORING BY AMBIENT MASS SPECTROMETRY J. Sun et al. 10.1002/mas.21668
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Heterogeneous photochemistry of dicarboxylic acids on mineral dust M. Ponczek et al. 10.1016/j.atmosenv.2019.05.032
- Ultrahigh-throughput absolute quantitative analysis of linezolid in human plasma by direct analysis in real time mass spectrometry without chromatographic separation and its application to a pharmacokinetic study L. Yin et al. 10.1007/s00216-019-01891-2
- Kinetics, mechanisms and ionic liquids in the uptake of n-butylamine onto low molecular weight dicarboxylic acids M. Fairhurst et al. 10.1039/C6CP08663B
20 citations as recorded by crossref.
- Molecular Characterization of Atmospheric Organic Aerosol by Mass Spectrometry M. Johnston & D. Kerecman 10.1146/annurev-anchem-061516-045135
- Probing surfaces of atmospherically relevant organic particles by easy ambient sonic-spray ionization mass spectrometry (EASI-MS) L. Wingen & B. Finlayson-Pitts 10.1039/C8SC03851A
- A cautionary note on the effects of laboratory air contaminants on ambient ionization mass spectrometry measurements S. Kumbhani et al. 10.1002/rcm.7951
- Online molecular characterisation of organic aerosols in an atmospheric chamber using extractive electrospray ionisation mass spectrometry P. Gallimore et al. 10.5194/acp-17-14485-2017
- Using Nanoparticle X-ray Spectroscopy to Probe the Formation of Reactive Chemical Gradients in Diffusion-Limited Aerosols M. Jacobs et al. 10.1021/acs.jpca.9b04507
- Analysis of Atmospheric Particles: From the Bulk to the Interface T. Lei et al. 10.1021/acs.analchem.4c06795
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Compositional evolution of particle-phase reaction products and water in the heterogeneous OH oxidation of model aqueous organic aerosols M. Chim et al. 10.5194/acp-17-14415-2017
- Role of Gas-Phase Halogen Bonding in Ambient Chemical Ionization Mass Spectrometry Utilizing Iodine J. Ganske et al. 10.1021/acsearthspacechem.9b00030
- High‐throughput bioanalysis of sitagliptin in plasma using direct analysis in real time mass spectrometry and its application in the pharmacokinetic study thereof Y. Liu et al. 10.1002/jssc.202100461
- The chemical reactions in electrosprays of water do not always correspond to those at the pristine air–water interface A. Gallo et al. 10.1039/C8SC05538F
- Distinct Temperature Trends in the Uptake of Gaseous n-Butylamine on Two Solid Diacids Y. Li et al. 10.1021/acsestair.3c00032
- Investigating the Kinetics of Heterogeneous Lipid Ozonolysis by an Online Photoionization High-Resolution Mass Spectrometry Technique P. Liu et al. 10.1021/acs.analchem.4c04404
- Investigation of solvent microparticle formation in spray ionization–quadrupole ion trap–mass spectrometry A. Özdemir et al. 10.1002/jms.4785
- Knudsen cell studies of the uptake of gaseous ammonia and amines onto C3–C7 solid dicarboxylic acids M. Fairhurst et al. 10.1039/C7CP05252A
- Separation of Pimelic Acid Using Tri-n-octylamine in Various Organic Solvents by Reactive Extraction: Equilibrium and Modeling H. Zeidan et al. 10.1021/acs.jced.1c00633
- CHEMICAL REACTION MONITORING BY AMBIENT MASS SPECTROMETRY J. Sun et al. 10.1002/mas.21668
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Heterogeneous photochemistry of dicarboxylic acids on mineral dust M. Ponczek et al. 10.1016/j.atmosenv.2019.05.032
- Ultrahigh-throughput absolute quantitative analysis of linezolid in human plasma by direct analysis in real time mass spectrometry without chromatographic separation and its application to a pharmacokinetic study L. Yin et al. 10.1007/s00216-019-01891-2
Latest update: 13 Sep 2025
Short summary
Two model systems are studied: dicarboxylic acid particles with gaseous amines and α-cedrene ozonolysis particles. Measurements by direct analysis in real-time mass spectrometry and high-resolution time-of-flight aerosol mass spectrometry
show that the reaction of the amines with the acid particles is restricted to the surface layer, with an odd–even alternating pattern. Furthermore, in the α-cedrene study, DART-MS is able to differentiate isomers based on their volatility.
Two model systems are studied: dicarboxylic acid particles with gaseous amines and α-cedrene...
