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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Two model systems are studied: dicarboxylic acid particles with gaseous amines and α-cedrene ozonolysis particles. Measurements by direct analysis in real-time mass spectrometry and high-resolution time-of-flight aerosol mass spectrometry show that the reaction of the amines with the acid particles is restricted to the surface layer, with an odd–even alternating pattern. Furthermore, in the α-cedrene study, DART-MS is able to differentiate isomers based on their volatility.
Articles | Volume 10, issue 4
Atmos. Meas. Tech., 10, 1373–1386, 2017
https://doi.org/10.5194/amt-10-1373-2017
Atmos. Meas. Tech., 10, 1373–1386, 2017
https://doi.org/10.5194/amt-10-1373-2017

Research article 11 Apr 2017

Research article | 11 Apr 2017

New insights into atmospherically relevant reaction systems using direct analysis in real-time mass spectrometry (DART-MS)

Yue Zhao et al.

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Latest update: 25 Jan 2021
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Short summary
Two model systems are studied: dicarboxylic acid particles with gaseous amines and α-cedrene ozonolysis particles. Measurements by direct analysis in real-time mass spectrometry and high-resolution time-of-flight aerosol mass spectrometry show that the reaction of the amines with the acid particles is restricted to the surface layer, with an odd–even alternating pattern. Furthermore, in the α-cedrene study, DART-MS is able to differentiate isomers based on their volatility.
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