Articles | Volume 10, issue 4
https://doi.org/10.5194/amt-10-1465-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-10-1465-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
19 Apr 2017
Research article |
| 19 Apr 2017
Development of a portable cavity-enhanced absorption spectrometer for the measurement of ambient NO3 and N2O5: experimental setup, lab characterizations, and field applications in a polluted urban environment
Haichao Wang
State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, China
Jun Chen
College of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai, China
State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, China
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Cited
57 citations as recorded by crossref.
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- Field Determination of Nitrate Formation Pathway in Winter Beijing X. Chen et al. 10.1021/acs.est.0c00972
- Secondary Production of Gaseous Nitrated Phenols in Polluted Urban Environments X. Cheng et al. 10.1021/acs.est.0c07988
- Phonon-Enhanced Mid-Infrared CO2 Gas Sensing Using Boron Nitride Nanoresonators N. Bareza et al. 10.1021/acsphotonics.1c01254
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- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- A Demonstration of Broadband Cavity-Enhanced Absorption Spectroscopy at Deep-Ultraviolet Wavelengths: Application to Sensitive Real-Time Detection of the Aromatic Pollutants Benzene, Toluene, and Xylene M. Wang et al. 10.1021/acs.analchem.1c04940
- High-accuracy and high-sensitivity spectroscopic measurement of dinitrogen pentoxide (N2O5) in an atmospheric simulation chamber using a quantum cascade laser H. Yi et al. 10.1039/C7AN01167A
- Effects of nighttime heterogeneous reactions on the formation of secondary aerosols and ozone in the Pearl River Delta Y. Niu et al. 10.1360/TB-2021-0638
- Development of an incoherent broadband cavity-enhanced absorption spectrometer for measurements of ambient glyoxal and NO2 in a polluted urban environment S. Liang et al. 10.5194/amt-12-2499-2019
- Open path incoherent broadband cavity-enhanced measurements of NO3 radical and aerosol extinction in the North China Plain K. Suhail et al. 10.1016/j.saa.2018.09.023
- An IBBCEAS system for atmospheric measurements of glyoxal and methylglyoxal in the presence of high NO2 concentrations J. Liu et al. 10.5194/amt-12-4439-2019
- Measurements of atmospheric HONO and NO<sub>2</sub> utilizing an open-path broadband cavity enhanced absorption spectroscopy based on an iterative algorithm F. Meng et al. 10.7498/aps.71.20220150
- 腔增强吸收光谱技术研究与应用进展（特邀） 超. CHAO Xing et al. 10.3788/gzxb20235203.0352102
- Development of a broadband cavity-enhanced absorption spectrometer for simultaneous measurements of ambient NO3, NO2, and H2O W. Nam et al. 10.5194/amt-15-4473-2022
- High N2O5 Concentrations Observed in Urban Beijing: Implications of a Large Nitrate Formation Pathway H. Wang et al. 10.1021/acs.estlett.7b00341
- Revisiting the Ultraviolet Absorption Cross Section of Gaseous Nitrous Acid (HONO): New Insights for Atmospheric HONO Budget X. Li et al. 10.1021/acs.est.3c08339
- Observation of nitrogen oxide-influenced chlorine chemistry and source analysis of Cl2 in the Yangtze River Delta, China F. Li et al. 10.1016/j.atmosenv.2023.119829
- Mid-infrared Gas Sensing Using Graphene Plasmons Tuned by Reversible Chemical Doping N. Bareza et al. 10.1021/acsphotonics.9b01714
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- Important Role of NO3 Radical to Nitrate Formation Aloft in Urban Beijing: Insights from Triple Oxygen Isotopes Measured at the Tower M. Fan et al. 10.1021/acs.est.1c02843
- Observation based study on atmospheric oxidation capacity in Shanghai during late-autumn: Contribution from nitryl chloride S. Lou et al. 10.1016/j.atmosenv.2021.118902
- Atmospheric Δ17O(NO3−) reveals nocturnal chemistry dominates nitrate production in Beijing haze P. He et al. 10.5194/acp-18-14465-2018
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- Direct measurement of N2O5 heterogeneous uptake coefficients on ambient aerosols via an aerosol flow tube system: design, characterization and performance X. Chen et al. 10.5194/amt-15-7019-2022
- Intercomparison of in situ CRDS and CEAS for measurements of atmospheric N2O5 in Beijing, China Z. Li et al. 10.1016/j.scitotenv.2017.08.302
- Exploring atmospheric free-radical chemistry in China: the self-cleansing capacity and the formation of secondary air pollution K. Lu et al. 10.1093/nsr/nwy073
- A pptv Level Incoherent Broadband Cavity-Enhanced Absorption Spectrometer for the Measurement of Atmospheric NO3 L. Ling et al. 10.3390/atmos14030543
- Review of Chinese atmospheric science research over the past 70 years: Atmospheric physics and atmospheric environment T. Wang et al. 10.1007/s11430-019-9536-1
- Synchronous detection of multiple optical characteristics of atmospheric aerosol by coupled photoacoustic cavity H. Jin et al. 10.1088/1674-1056/ac43ad
- A mini broadband cavity enhanced absorption spectrometer for nitrogen dioxide measurement on the unmanned aerial vehicle platform Z. Zheng et al. 10.1016/j.atmosenv.2024.120361
- Development and Application of Cavity-based Absorption Spectroscopy in Atmospheric Chemistry: Recent Progress W. Zhao et al. 10.1007/s00376-024-4209-4
- A review of experimental techniques for aerosol hygroscopicity studies M. Tang et al. 10.5194/acp-19-12631-2019
- Wintertime N2O5 uptake coefficients over the North China Plain H. Wang et al. 10.1016/j.scib.2020.02.006
- NO3 and N2O5 chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 H. Wang et al. 10.1016/j.atmosenv.2019.117180
- Observation and modeling of organic nitrates on a suburban site in southwest China C. Li et al. 10.1016/j.scitotenv.2022.160287
- Formation Mechanisms and Source Apportionments of Nitrate Aerosols in a Megacity of Eastern China Based On Multiple Isotope Observations M. Fan et al. 10.1029/2022JD038129
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al. 10.5194/acp-24-977-2024
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- Near-Infrared Off-Axis Integrated Cavity Output Spectroscopic Gas Sensor for Real-Time, In Situ Atmospheric Methane Monitoring K. Zheng et al. 10.1109/JSEN.2020.3042697
- Broadband cavity enhanced absorption spectroscopy for measuring atmospheric NO<sub>3</sub> radical J. Duan et al. 10.7498/aps.70.20201066
- N2O5 uptake onto saline mineral dust: a potential missing source of tropospheric ClNO2 in inland China H. Wang et al. 10.5194/acp-22-1845-2022
- Multiple Gas Detection by Cavity-Enhanced Raman Spectroscopy with Sub-ppm Sensitivity Q. Yang et al. 10.1021/acs.analchem.2c05432
- Review of Incoherent Broadband Cavity-Enhanced Absorption Spectroscopy (IBBCEAS) for Gas Sensing K. Zheng et al. 10.3390/s18113646
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- Near-infrared broadband cavity-enhanced sensor system for methane detection using a wavelet-denoising assisted Fourier-transform spectrometer K. Zheng et al. 10.1039/C8AN01290C
- Intercomparison of NO3 under Humid Conditions with Open-Path and Extractive IBBCEAS in an Atmospheric Reaction Chamber M. Wang et al. 10.3390/rs15030739
57 citations as recorded by crossref.
- A Study of Chemical Processes of Nitrate in Atmospheric Aerosol and Snow Based on Stable Isotopes M. Chen et al. 10.3390/atmos15010059
- Chlorine oxidation of VOCs at a semi-rural site in Beijing: significant chlorine liberation from ClNO2 and subsequent gas- and particle-phase Cl–VOC production M. Le Breton et al. 10.5194/acp-18-13013-2018
- Field Determination of Nitrate Formation Pathway in Winter Beijing X. Chen et al. 10.1021/acs.est.0c00972
- Secondary Production of Gaseous Nitrated Phenols in Polluted Urban Environments X. Cheng et al. 10.1021/acs.est.0c07988
- Phonon-Enhanced Mid-Infrared CO2 Gas Sensing Using Boron Nitride Nanoresonators N. Bareza et al. 10.1021/acsphotonics.1c01254
- Development of a portable cavity ring down spectroscopy instrument for simultaneous, in situ measurement of NO3 and N2O5 Z. Li et al. 10.1364/OE.26.00A433
- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- A Demonstration of Broadband Cavity-Enhanced Absorption Spectroscopy at Deep-Ultraviolet Wavelengths: Application to Sensitive Real-Time Detection of the Aromatic Pollutants Benzene, Toluene, and Xylene M. Wang et al. 10.1021/acs.analchem.1c04940
- High-accuracy and high-sensitivity spectroscopic measurement of dinitrogen pentoxide (N2O5) in an atmospheric simulation chamber using a quantum cascade laser H. Yi et al. 10.1039/C7AN01167A
- Effects of nighttime heterogeneous reactions on the formation of secondary aerosols and ozone in the Pearl River Delta Y. Niu et al. 10.1360/TB-2021-0638
- Development of an incoherent broadband cavity-enhanced absorption spectrometer for measurements of ambient glyoxal and NO2 in a polluted urban environment S. Liang et al. 10.5194/amt-12-2499-2019
- Open path incoherent broadband cavity-enhanced measurements of NO3 radical and aerosol extinction in the North China Plain K. Suhail et al. 10.1016/j.saa.2018.09.023
- An IBBCEAS system for atmospheric measurements of glyoxal and methylglyoxal in the presence of high NO2 concentrations J. Liu et al. 10.5194/amt-12-4439-2019
- Measurements of atmospheric HONO and NO<sub>2</sub> utilizing an open-path broadband cavity enhanced absorption spectroscopy based on an iterative algorithm F. Meng et al. 10.7498/aps.71.20220150
- 腔增强吸收光谱技术研究与应用进展（特邀） 超. CHAO Xing et al. 10.3788/gzxb20235203.0352102
- Development of a broadband cavity-enhanced absorption spectrometer for simultaneous measurements of ambient NO3, NO2, and H2O W. Nam et al. 10.5194/amt-15-4473-2022
- High N2O5 Concentrations Observed in Urban Beijing: Implications of a Large Nitrate Formation Pathway H. Wang et al. 10.1021/acs.estlett.7b00341
- Revisiting the Ultraviolet Absorption Cross Section of Gaseous Nitrous Acid (HONO): New Insights for Atmospheric HONO Budget X. Li et al. 10.1021/acs.est.3c08339
- Observation of nitrogen oxide-influenced chlorine chemistry and source analysis of Cl2 in the Yangtze River Delta, China F. Li et al. 10.1016/j.atmosenv.2023.119829
- Mid-infrared Gas Sensing Using Graphene Plasmons Tuned by Reversible Chemical Doping N. Bareza et al. 10.1021/acsphotonics.9b01714
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- Comprehensive detection of nitrated aromatic compounds in fine particulate matter using gas chromatography and tandem mass spectrometry coupled with an electron capture negative ionization source X. Shi et al. 10.1016/j.jhazmat.2020.124794
- Sensitive Detection of Ambient Formaldehyde by Incoherent Broadband Cavity Enhanced Absorption Spectroscopy J. Liu et al. 10.1021/acs.analchem.9b04821
- An explicit study of local ozone budget and NOx-VOCs sensitivity in Shenzhen China D. Yu et al. 10.1016/j.atmosenv.2020.117304
- Important Role of NO3 Radical to Nitrate Formation Aloft in Urban Beijing: Insights from Triple Oxygen Isotopes Measured at the Tower M. Fan et al. 10.1021/acs.est.1c02843
- Observation based study on atmospheric oxidation capacity in Shanghai during late-autumn: Contribution from nitryl chloride S. Lou et al. 10.1016/j.atmosenv.2021.118902
- Atmospheric Δ17O(NO3−) reveals nocturnal chemistry dominates nitrate production in Beijing haze P. He et al. 10.5194/acp-18-14465-2018
- Rapid and high-precision cavity-enhanced spectroscopic measurement of HONO and NO2: Application to emissions from heavy-duty diesel vehicles in chassis dynamometer tests and in mobile monitoring M. Wang et al. 10.1016/j.talanta.2024.127386
- Incoherent broad-band cavity enhanced absorption spectroscopy for sensitive and rapid molecular iodine detection in the presence of aerosols and water vapour C. Bahrini et al. 10.1016/j.optlastec.2018.06.050
- Elucidate the formation mechanism of particulate nitrate based on direct radical observations in the Yangtze River Delta summer 2019 T. Zhai et al. 10.5194/acp-23-2379-2023
- Wintertime photochemistry in Beijing: observations of ROx radical concentrations in the North China Plain during the BEST-ONE campaign Z. Tan et al. 10.5194/acp-18-12391-2018
- Narrow-band multi-component gas analysis based on photothermal spectroscopy and partial least squares regression method Y. Zhou et al. 10.1016/j.snb.2022.133029
- Direct measurement of N2O5 heterogeneous uptake coefficients on ambient aerosols via an aerosol flow tube system: design, characterization and performance X. Chen et al. 10.5194/amt-15-7019-2022
- Intercomparison of in situ CRDS and CEAS for measurements of atmospheric N2O5 in Beijing, China Z. Li et al. 10.1016/j.scitotenv.2017.08.302
- Exploring atmospheric free-radical chemistry in China: the self-cleansing capacity and the formation of secondary air pollution K. Lu et al. 10.1093/nsr/nwy073
- A pptv Level Incoherent Broadband Cavity-Enhanced Absorption Spectrometer for the Measurement of Atmospheric NO3 L. Ling et al. 10.3390/atmos14030543
- Review of Chinese atmospheric science research over the past 70 years: Atmospheric physics and atmospheric environment T. Wang et al. 10.1007/s11430-019-9536-1
- Synchronous detection of multiple optical characteristics of atmospheric aerosol by coupled photoacoustic cavity H. Jin et al. 10.1088/1674-1056/ac43ad
- A mini broadband cavity enhanced absorption spectrometer for nitrogen dioxide measurement on the unmanned aerial vehicle platform Z. Zheng et al. 10.1016/j.atmosenv.2024.120361
- Development and Application of Cavity-based Absorption Spectroscopy in Atmospheric Chemistry: Recent Progress W. Zhao et al. 10.1007/s00376-024-4209-4
- A review of experimental techniques for aerosol hygroscopicity studies M. Tang et al. 10.5194/acp-19-12631-2019
- Wintertime N2O5 uptake coefficients over the North China Plain H. Wang et al. 10.1016/j.scib.2020.02.006
- NO3 and N2O5 chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 H. Wang et al. 10.1016/j.atmosenv.2019.117180
- Observation and modeling of organic nitrates on a suburban site in southwest China C. Li et al. 10.1016/j.scitotenv.2022.160287
- Formation Mechanisms and Source Apportionments of Nitrate Aerosols in a Megacity of Eastern China Based On Multiple Isotope Observations M. Fan et al. 10.1029/2022JD038129
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al. 10.5194/acp-24-977-2024
- A Comprehensive Review on Study Methods of Aerosol Optical Properties in Different Dimensions Y. Liu et al. 10.1109/ACCESS.2023.3266333
- Monitoring Ambient Nitrate Radical by Open-Path Cavity-Enhanced Absorption Spectroscopy H. Wang & K. Lu 10.1021/acs.analchem.9b01971
- Near-Infrared Off-Axis Integrated Cavity Output Spectroscopic Gas Sensor for Real-Time, In Situ Atmospheric Methane Monitoring K. Zheng et al. 10.1109/JSEN.2020.3042697
- Broadband cavity enhanced absorption spectroscopy for measuring atmospheric NO<sub>3</sub> radical J. Duan et al. 10.7498/aps.70.20201066
- N2O5 uptake onto saline mineral dust: a potential missing source of tropospheric ClNO2 in inland China H. Wang et al. 10.5194/acp-22-1845-2022
- Multiple Gas Detection by Cavity-Enhanced Raman Spectroscopy with Sub-ppm Sensitivity Q. Yang et al. 10.1021/acs.analchem.2c05432
- Review of Incoherent Broadband Cavity-Enhanced Absorption Spectroscopy (IBBCEAS) for Gas Sensing K. Zheng et al. 10.3390/s18113646
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO2, RO2NO2, and RONO2 in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- Efficient N2O5 uptake and NO3 oxidation in the outflow of urban Beijing H. Wang et al. 10.5194/acp-18-9705-2018
- Near-infrared broadband cavity-enhanced sensor system for methane detection using a wavelet-denoising assisted Fourier-transform spectrometer K. Zheng et al. 10.1039/C8AN01290C
- Intercomparison of NO3 under Humid Conditions with Open-Path and Extractive IBBCEAS in an Atmospheric Reaction Chamber M. Wang et al. 10.3390/rs15030739
Latest update: 21 Feb 2025
Short summary
A new incoherent broadband cavity-enhanced absorption spectrometer for ambient NO3 and N2O5 detection is developed. This new instrument is featured with a mechanically aligned non-adjustable optical mounting system. Fast setup and stable running of this N2O5 spectrometer were successfully achieved during recent field campaigns in China due to this new feature. In addition, a dynamic reference spectrum is used for the CEAS type of instrument by NO titration for the first time.
A new incoherent broadband cavity-enhanced absorption spectrometer for ambient NO3 and N2O5...
