Articles | Volume 10, issue 7
https://doi.org/10.5194/amt-10-2669-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-10-2669-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
26 Jul 2017
Research article |
| 26 Jul 2017
Abundances of isotopologues and calibration of CO2 greenhouse gas measurements
Pieter P. Tans
CORRESPONDING AUTHOR
Global Monitoring Division, Earth System Research Laboratory, National
Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
Central Calibration Laboratory, World Meteorological Organization
Global Atmosphere Watch program (WMO/GAW), Boulder, Colorado 80305, USA
Andrew M. Crotwell
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, Boulder, Colorado 80309, USA
Central Calibration Laboratory, World Meteorological Organization
Global Atmosphere Watch program (WMO/GAW), Boulder, Colorado 80305, USA
Kirk W. Thoning
Global Monitoring Division, Earth System Research Laboratory, National
Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
Central Calibration Laboratory, World Meteorological Organization
Global Atmosphere Watch program (WMO/GAW), Boulder, Colorado 80305, USA
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- The fingerprint of the summer 2018 drought in Europe on ground-based atmospheric CO2measurements M. Ramonet et al. 10.1098/rstb.2019.0513
- A spatially explicit inventory scaling approach to estimate urban CO2 emissions K. Hajny et al. 10.1525/elementa.2021.00121
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25 citations as recorded by crossref.
- Integration and calibration of non-dispersive infrared (NDIR) CO<sub>2</sub> low-cost sensors and their operation in a sensor network covering Switzerland M. Müller et al. 10.5194/amt-13-3815-2020
- Cropland Carbon Uptake Delayed and Reduced by 2019 Midwest Floods Y. Yin et al. 10.1029/2019AV000140
- Gravimetrically prepared carbon dioxide standards in support of atmospheric research B. Hall et al. 10.5194/amt-12-517-2019
- SI traceability and scales for underpinning atmospheric monitoring of greenhouse gases P. Brewer et al. 10.1088/1681-7575/aad830
- Calibration of isotopologue-specific optical trace gas analysers: a practical guide D. Griffith 10.5194/amt-11-6189-2018
- An FTIR method for accurate CO2 mole fraction measurements with correction for differences in isotopic composition of gases E. Flores et al. 10.1088/1681-7575/ab2941
- Policy-Relevant Assessment of Urban CO2 Emissions T. Lauvaux et al. 10.1021/acs.est.0c00343
- Potential improvements aimed at high precision δ13C isotopic ratio determinations in CO2 mixtures using optical absorption spectrometry S. Koulikov et al. 10.1016/j.talanta.2018.02.076
- Isotopic trace analysis of water vapor with multipass cavity Raman scattering J. Singh & A. Muller 10.1039/D1AN01254A
- High-temperature absorption line shape parameters for CO2 in the 6800–7000 cm-1 region from dual frequency comb measurements up to 1000 K R. Cole et al. 10.1016/j.jqsrt.2021.107912
- Seasonal Variability in Local Carbon Dioxide Biomass Burning Sources Over Central and Eastern US Using Airborne In Situ Enhancement Ratios J. DiGangi et al. 10.1029/2020JD034525
- Measuring techniques for concentration and stable isotopologues of CO2 in a terrestrial ecosystem: A review G. Voglar et al. 10.1016/j.earscirev.2019.102978
- Testing and evaluation of a new airborne system for continuous N<sub>2</sub>O, CO<sub>2</sub>, CO, and H<sub>2</sub>O measurements: the Frequent Calibration High-performance Airborne Observation System (FCHAOS) A. Gvakharia et al. 10.5194/amt-11-6059-2018
- Spatial attribution of aircraft mass balance experiment CO2 estimations for policy-relevant boundaries: New York City J. Tomlin et al. 10.1525/elementa.2023.00046
- UK greenhouse gas measurements at two new tall towers for aiding emissions verification A. Stavert et al. 10.5194/amt-12-4495-2019
- Abrupt CO 2 release to the atmosphere under glacial and early interglacial climate conditions C. Nehrbass-Ahles et al. 10.1126/science.aay8178
- Advances in reference materials and measurement techniques for greenhouse gas atmospheric observations P. Brewer et al. 10.1088/1681-7575/ab1506
- Revision of the World Meteorological Organization Global Atmosphere Watch (WMO/GAW) CO<sub>2</sub> calibration scale B. Hall et al. 10.5194/amt-14-3015-2021
- Simultaneous measurement of <i>δ</i><sup>13</sup>C, <i>δ</i><sup>18</sup>O and <i>δ</i><sup>17</sup>O of atmospheric CO<sub>2</sub> – performance assessment of a dual-laser absorption spectrometer P. Steur et al. 10.5194/amt-14-4279-2021
- The fingerprint of the summer 2018 drought in Europe on ground-based atmospheric CO2measurements M. Ramonet et al. 10.1098/rstb.2019.0513
- A spatially explicit inventory scaling approach to estimate urban CO2 emissions K. Hajny et al. 10.1525/elementa.2021.00121
- Assessing the bias and uncertainties in the aircraft mass balance technique for the determination of carbon dioxide emission rates K. Hajny et al. 10.1525/elementa.2022.00135
- Millennial-scale atmospheric CO<sub>2</sub> variations during the Marine Isotope Stage 6 period (190–135 ka) J. Shin et al. 10.5194/cp-16-2203-2020
- REMINISCING ON THE USE AND ABUSE OF 14C AND 13C IN ATMOSPHERIC CO2 P. Tans 10.1017/RDC.2022.7
- New York City greenhouse gas emissions estimated with inverse modeling of aircraft measurements J. Pitt et al. 10.1525/elementa.2021.00082
Latest update: 24 Apr 2024
Short summary
We describe a new CO2 calibration system for the Central Calibration Laboratory of the World Meteorological Organization Global Atmosphere Watch program. The system uses two laser spectroscopic instruments to measure the three major CO2 isotopologues individually. We account for isotopic differences between standards in the calibration hierarchy when assigning CO2 mole fraction, eliminating bias due to variations in the isotopic composition.
We describe a new CO2 calibration system for the Central Calibration Laboratory of the World...
