Articles | Volume 10, issue 12
https://doi.org/10.5194/amt-10-4687-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-10-4687-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Effects of gas–wall partitioning in Teflon tubing and instrumentation on time-resolved measurements of gas-phase organic compounds
Demetrios Pagonis
Cooperative Institute for Research in Environmental Sciences (CIRES),
Boulder, Colorado 80309, USA
Department of Chemistry and Biochemistry, University of Colorado,
Boulder, Colorado 80309, USA
Jordan E. Krechmer
Cooperative Institute for Research in Environmental Sciences (CIRES),
Boulder, Colorado 80309, USA
Department of Chemistry and Biochemistry, University of Colorado,
Boulder, Colorado 80309, USA
Aerodyne Research, Inc., Billerica, Massachusetts 01821, USA
Joost de Gouw
Cooperative Institute for Research in Environmental Sciences (CIRES),
Boulder, Colorado 80309, USA
NOAA Earth System Research Laboratory, Boulder, Colorado 80305, USA
Jose L. Jimenez
CORRESPONDING AUTHOR
Cooperative Institute for Research in Environmental Sciences (CIRES),
Boulder, Colorado 80309, USA
Department of Chemistry and Biochemistry, University of Colorado,
Boulder, Colorado 80309, USA
Paul J. Ziemann
CORRESPONDING AUTHOR
Cooperative Institute for Research in Environmental Sciences (CIRES),
Boulder, Colorado 80309, USA
Department of Chemistry and Biochemistry, University of Colorado,
Boulder, Colorado 80309, USA
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Latest update: 01 Nov 2024
Short summary
Laboratory studies were conducted to investigate gas-wall partitioning of atmospheric organic compounds in Teflon tubing and inside an instrument used to monitor concentrations. Rapid partitioning caused time delays in instrument response that vary with tubing length and diameter, flow rate, and compound volatility. Tubing delay times of seconds to hours were described using a model that also included effects of instrument surfaces. The results can enable better design of air sampling systems.
Laboratory studies were conducted to investigate gas-wall partitioning of atmospheric organic...