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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 11, issue 4
Atmos. Meas. Tech., 11, 1851–1881, 2018
https://doi.org/10.5194/amt-11-1851-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Meas. Tech., 11, 1851–1881, 2018
https://doi.org/10.5194/amt-11-1851-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 04 Apr 2018

Research article | 04 Apr 2018

An ion-neutral model to investigate chemical ionization mass spectrometry analysis of atmospheric molecules – application to a mixed reagent ion system for hydroperoxides and organic acids

Brian G. Heikes et al.

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Interactive discussion

Status: closed
Status: closed
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
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Peer review completion

AR: Author's response | RR: Referee report | ED: Editor decision
AR by Brian Heikes on behalf of the Authors (19 Jan 2018)  Author's response    Manuscript
ED: Publish as is (05 Feb 2018) by Fred Stroh
Publications Copernicus
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Short summary
A CIMS utilizing a multi-species negative ion chemistry was designed to measure peroxides and organic acids throughout the troposphere from an aircraft. Prior CIMS used a single reagent ion, and the multi-ion approach has the potential to be a significant step forward, although one with analytical risk. Here, a chemical kinetics numerical model is presented which simulates its past water vapor and pressure dependence, providing a test bed to characterize its use in future environments.
A CIMS utilizing a multi-species negative ion chemistry was designed to measure peroxides and...
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