Articles | Volume 11, issue 6
https://doi.org/10.5194/amt-11-3251-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-3251-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Jun 2018
Research article |
| 07 Jun 2018
| 07 Jun 2018
The sensitivity of benzene cluster cation chemical ionization mass spectrometry to select biogenic terpenes
Avi Lavi
Department of Chemistry, University of Wisconsin, Madison, WI 53706,
USA
now at: Department of Chemistry, University of California-Riverside,
Riverside, CA 92521, USA
Michael P. Vermeuel
Department of Chemistry, University of Wisconsin, Madison, WI 53706,
USA
Gordon A. Novak
Department of Chemistry, University of Wisconsin, Madison, WI 53706,
USA
Timothy H. Bertram
CORRESPONDING AUTHOR
Department of Chemistry, University of Wisconsin, Madison, WI 53706,
USA
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Cited
16 citations as recorded by crossref.
- Evaluation of a reduced-pressure chemical ion reactor utilizing adduct ionization for the detection of gaseous organic and inorganic species M. Riva et al. 10.5194/amt-17-5887-2024
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Secondary aerosol formation from mixtures of marine volatile organic compounds in a potential aerosol mass oxidative flow reactor A. Moore et al. 10.1039/D3EA00169E
- Photoinduced Associative Ionization Time-of-Flight Mass Spectrometry for the Sensitive Determination of Monoterpenes Z. Zhang et al. 10.1080/00032719.2022.2049284
- Highly diverse emission of volatile organic compounds by Sitka spruce and determination of their emission pathways H. Furnell et al. 10.1039/D4EA00138A
- Kinetic Understanding of the Ultrahigh Ionization Efficiencies (up to 28%) of Excited-State CH2Cl2-Induced Associative Ionization: A Case Study with Nitro Compounds J. Huang et al. 10.1021/acs.analchem.8b04813
- Low-Cost Alternative for Online Analysis of Volatile Organic Compounds B. Rico et al. 10.1021/acs.analchem.4c00916
- A versatile vacuum ultraviolet ion source for reduced pressure bipolar chemical ionization mass spectrometry M. Breitenlechner et al. 10.5194/amt-15-1159-2022
- Olfaction in the Anthropocene: NO 3 negatively affects floral scent and nocturnal pollination J. Chan et al. 10.1126/science.adi0858
- The Sea Spray Chemistry and Particle Evolution study (SeaSCAPE): overview and experimental methods J. Sauer et al. 10.1039/D1EM00260K
- Styrene radical cations for chemical ionization mass spectrometry analyses of monoterpene hydrocarbons A. Spesyvyi et al. 10.1002/rcm.8556
- First eddy covariance flux measurements of semi-volatile organic compounds with the PTR3-TOF-MS L. Fischer et al. 10.5194/amt-14-8019-2021
- Airborne flux measurements of ammonia over the southern Great Plains using chemical ionization mass spectrometry S. Schobesberger et al. 10.5194/amt-16-247-2023
- Marine gas-phase sulfur emissions during an induced phytoplankton bloom D. Kilgour et al. 10.5194/acp-22-1601-2022
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Recent progress in chemical ionization mass spectrometry and its application in atmospheric environment W. Li et al. 10.1016/j.atmosenv.2024.120426
16 citations as recorded by crossref.
- Evaluation of a reduced-pressure chemical ion reactor utilizing adduct ionization for the detection of gaseous organic and inorganic species M. Riva et al. 10.5194/amt-17-5887-2024
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Secondary aerosol formation from mixtures of marine volatile organic compounds in a potential aerosol mass oxidative flow reactor A. Moore et al. 10.1039/D3EA00169E
- Photoinduced Associative Ionization Time-of-Flight Mass Spectrometry for the Sensitive Determination of Monoterpenes Z. Zhang et al. 10.1080/00032719.2022.2049284
- Highly diverse emission of volatile organic compounds by Sitka spruce and determination of their emission pathways H. Furnell et al. 10.1039/D4EA00138A
- Kinetic Understanding of the Ultrahigh Ionization Efficiencies (up to 28%) of Excited-State CH2Cl2-Induced Associative Ionization: A Case Study with Nitro Compounds J. Huang et al. 10.1021/acs.analchem.8b04813
- Low-Cost Alternative for Online Analysis of Volatile Organic Compounds B. Rico et al. 10.1021/acs.analchem.4c00916
- A versatile vacuum ultraviolet ion source for reduced pressure bipolar chemical ionization mass spectrometry M. Breitenlechner et al. 10.5194/amt-15-1159-2022
- Olfaction in the Anthropocene: NO 3 negatively affects floral scent and nocturnal pollination J. Chan et al. 10.1126/science.adi0858
- The Sea Spray Chemistry and Particle Evolution study (SeaSCAPE): overview and experimental methods J. Sauer et al. 10.1039/D1EM00260K
- Styrene radical cations for chemical ionization mass spectrometry analyses of monoterpene hydrocarbons A. Spesyvyi et al. 10.1002/rcm.8556
- First eddy covariance flux measurements of semi-volatile organic compounds with the PTR3-TOF-MS L. Fischer et al. 10.5194/amt-14-8019-2021
- Airborne flux measurements of ammonia over the southern Great Plains using chemical ionization mass spectrometry S. Schobesberger et al. 10.5194/amt-16-247-2023
- Marine gas-phase sulfur emissions during an induced phytoplankton bloom D. Kilgour et al. 10.5194/acp-22-1601-2022
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Recent progress in chemical ionization mass spectrometry and its application in atmospheric environment W. Li et al. 10.1016/j.atmosenv.2024.120426
Latest update: 09 May 2025
Short summary
Chemical ionization mass spectrometry has emerged as a versatile tool for the study of reactive gases. Robust calibration is required to assess the sensitivity of these instruments and their dependence on external factors such as specific humidity. Here, we report the sensitivity of benzene cluster cation chemical ionization for an array of terpene compounds. This work permits a more universal understanding of the sensitivity of this technique to a host of isobaric compounds.
Chemical ionization mass spectrometry has emerged as a versatile tool for the study of reactive...
