Articles | Volume 11, issue 1
https://doi.org/10.5194/amt-11-33-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-33-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 Jan 2018
Research article |
| 08 Jan 2018
| 08 Jan 2018
Electrodynamic balance–mass spectrometry of single particles as a new platform for atmospheric chemistry research
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
Ulrich K. Krieger
CORRESPONDING AUTHOR
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zurich, Switzerland
Frank N. Keutsch
CORRESPONDING AUTHOR
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA
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Cited
22 citations as recorded by crossref.
- Rapid and Sensitive Chemical Analysis of Individual Picolitre Droplets by Mass Spectrometry J. Walker & B. Bzdek 10.1021/acs.analchem.4c05458
- Single-particle Raman spectroscopy for studying physical and chemical processes of atmospheric particles Z. Liang et al. 10.5194/acp-22-3017-2022
- Translation–deformation coupling effects on the Rayleigh instability of an electrodynamically levitated charged droplet N. Gawande et al. 10.1140/epje/s10189-022-00203-4
- Mass, charge, and radius of droplets in a linear quadrupole electrodynamic balance J. Davies 10.1080/02786826.2018.1559921
- Optical Interrogation of Single Levitated Droplets in a Linear Quadrupole Trap by Cavity Ring-Down Spectroscopy A. Valenzuela et al. 10.1021/acs.jpca.0c09213
- Micro‐droplet Trapping and Manipulation: Understanding Aerosol Better for a Healthier Environment Y. Chang et al. 10.1002/asia.202100516
- Measuring the Chemical Evolution of Levitated Particles: A Study on the Evaporation of Multicomponent Organic Aerosol R. Kohli & J. Davies 10.1021/acs.analchem.1c02890
- Combining Mass Spectrometry of Picoliter Samples with a Multicompartment Electrodynamic Trap for Probing the Chemistry of Droplet Arrays M. Willis et al. 10.1021/acs.analchem.0c02343
- Optical trapping and light scattering in atmospheric aerosol science A. Rafferty et al. 10.1039/D2CP05301B
- An Open Port Sampling Interface for the Chemical Characterization of Levitated Microparticles R. Kaur Kohli et al. 10.1021/acs.analchem.1c05550
- Atomic Spectrometry Update – a review of advances in environmental analysis J. Bacon et al. 10.1039/C8JA90044B
- Photophoretic spectroscopy in atmospheric chemistry – high-sensitivity measurements of light absorption by a single particle N. Bluvshtein et al. 10.5194/amt-13-3191-2020
- Spectroscopic Studies of Clusters of Atmospheric Relevance N. Frederiks et al. 10.1146/annurev-physchem-062322-041503
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al. 10.1039/D2CP03289A
- Electrodynamic single-particle trap integrated into double-cavity ring-down spectroscopy for light extinction A. Valenzuela et al. 10.1016/j.jaerosci.2023.106292
- Competition of Partitioning and Reaction Controls Brown Carbon Formation from Butenedial in Particles J. Hensley et al. 10.1021/acs.est.1c02891
- Single-particle experiments measuring humidity and inorganic salt effects on gas-particle partitioning of butenedial A. Birdsall et al. 10.5194/acp-19-14195-2019
- Revisiting the reaction of dicarbonyls in aerosol proxy solutions containing ammonia: the case of butenedial J. Hensley et al. 10.5194/acp-21-8809-2021
- Oxidation pathways of linoleic acid revisited with electrodynamic balance–mass spectrometry M. Müller et al. 10.1039/D2EA00127F
- Paper spray mass spectrometry for the analysis of picoliter droplets R. Kaur Kohli & J. Davies 10.1039/C9AN02534K
- Tutorial: Electrodynamic balance methods for single particle levitation and the physicochemical analysis of aerosol R. Kaur Kohli et al. 10.1016/j.jaerosci.2023.106255
- Exploring Chemistry in Microcompartments Using Guided Droplet Collisions in a Branched Quadrupole Trap Coupled to a Single Droplet, Paper Spray Mass Spectrometer M. Jacobs et al. 10.1021/acs.analchem.7b03704
21 citations as recorded by crossref.
- Rapid and Sensitive Chemical Analysis of Individual Picolitre Droplets by Mass Spectrometry J. Walker & B. Bzdek 10.1021/acs.analchem.4c05458
- Single-particle Raman spectroscopy for studying physical and chemical processes of atmospheric particles Z. Liang et al. 10.5194/acp-22-3017-2022
- Translation–deformation coupling effects on the Rayleigh instability of an electrodynamically levitated charged droplet N. Gawande et al. 10.1140/epje/s10189-022-00203-4
- Mass, charge, and radius of droplets in a linear quadrupole electrodynamic balance J. Davies 10.1080/02786826.2018.1559921
- Optical Interrogation of Single Levitated Droplets in a Linear Quadrupole Trap by Cavity Ring-Down Spectroscopy A. Valenzuela et al. 10.1021/acs.jpca.0c09213
- Micro‐droplet Trapping and Manipulation: Understanding Aerosol Better for a Healthier Environment Y. Chang et al. 10.1002/asia.202100516
- Measuring the Chemical Evolution of Levitated Particles: A Study on the Evaporation of Multicomponent Organic Aerosol R. Kohli & J. Davies 10.1021/acs.analchem.1c02890
- Combining Mass Spectrometry of Picoliter Samples with a Multicompartment Electrodynamic Trap for Probing the Chemistry of Droplet Arrays M. Willis et al. 10.1021/acs.analchem.0c02343
- Optical trapping and light scattering in atmospheric aerosol science A. Rafferty et al. 10.1039/D2CP05301B
- An Open Port Sampling Interface for the Chemical Characterization of Levitated Microparticles R. Kaur Kohli et al. 10.1021/acs.analchem.1c05550
- Atomic Spectrometry Update – a review of advances in environmental analysis J. Bacon et al. 10.1039/C8JA90044B
- Photophoretic spectroscopy in atmospheric chemistry – high-sensitivity measurements of light absorption by a single particle N. Bluvshtein et al. 10.5194/amt-13-3191-2020
- Spectroscopic Studies of Clusters of Atmospheric Relevance N. Frederiks et al. 10.1146/annurev-physchem-062322-041503
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al. 10.1039/D2CP03289A
- Electrodynamic single-particle trap integrated into double-cavity ring-down spectroscopy for light extinction A. Valenzuela et al. 10.1016/j.jaerosci.2023.106292
- Competition of Partitioning and Reaction Controls Brown Carbon Formation from Butenedial in Particles J. Hensley et al. 10.1021/acs.est.1c02891
- Single-particle experiments measuring humidity and inorganic salt effects on gas-particle partitioning of butenedial A. Birdsall et al. 10.5194/acp-19-14195-2019
- Revisiting the reaction of dicarbonyls in aerosol proxy solutions containing ammonia: the case of butenedial J. Hensley et al. 10.5194/acp-21-8809-2021
- Oxidation pathways of linoleic acid revisited with electrodynamic balance–mass spectrometry M. Müller et al. 10.1039/D2EA00127F
- Paper spray mass spectrometry for the analysis of picoliter droplets R. Kaur Kohli & J. Davies 10.1039/C9AN02534K
- Tutorial: Electrodynamic balance methods for single particle levitation and the physicochemical analysis of aerosol R. Kaur Kohli et al. 10.1016/j.jaerosci.2023.106255
Latest update: 08 Jul 2025
Short summary
We have developed a laboratory system that provides mass spectra of individual particles, roughly 20 microns in diameter, after they have been levitated in an electric field. Measured evaporation of polyethylene glycol particles was found to agree with a kinetic model. The system can be used to study fundamental chemical and physical processes involving particles that are difficult to isolate and study with other techniques, and hence improve our understanding of atmospheric particles.
We have developed a laboratory system that provides mass spectra of individual particles,...
