Articles | Volume 11, issue 1
https://doi.org/10.5194/amt-11-49-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-49-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 Jan 2018
Research article |
| 08 Jan 2018
| 08 Jan 2018
A reference data set for validating vapor pressure measurement techniques: homologous series of polyethylene glycols
Ulrich K. Krieger
CORRESPONDING AUTHOR
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Franziska Siegrist
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Claudia Marcolli
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Eva U. Emanuelsson
Department of Chemistry, Aarhus University, 8000 Aarhus, Denmark
Freya M. Gøbel
Department of Chemistry, Aarhus University, 8000 Aarhus, Denmark
Merete Bilde
Department of Chemistry, Aarhus University, 8000 Aarhus, Denmark
Aleksandra Marsh
School of Chemistry, University of Bristol, BS8 1TS Bristol, UK
Jonathan P. Reid
School of Chemistry, University of Bristol, BS8 1TS Bristol, UK
Andrew J. Huisman
Chemistry Department, Union College, Schenectady, NY 12308, USA
Ilona Riipinen
Department of Environmental Science and Analytical Chemistry, Stockholm University, 106 91 Stockholm, Sweden
Noora Hyttinen
Department of Chemistry, University of Helsinki, 00014 Helsinki, Finland
Nanna Myllys
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Theo Kurtén
Department of Chemistry, University of Helsinki, 00014 Helsinki, Finland
Thomas Bannan
Centre for Atmospheric Sciences, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
Carl J. Percival
Centre for Atmospheric Sciences, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
David Topping
Centre for Atmospheric Sciences, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
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Discussed (final revised paper)
Discussed (preprint)
Latest update: 21 Feb 2025
Short summary
Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the literature often differ by several orders of magnitude between measurement techniques. These discrepancies exceed the stated uncertainty of each technique, which is generally reported to be smaller than a factor of 2. We determined saturation vapor pressures for the homologous series of polyethylene glycols ranging in vapor pressure at 298 K from 1E−7 Pa to 5E−2 Pa as a reference set.
Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the...
