Articles | Volume 11, issue 1
https://doi.org/10.5194/amt-11-49-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-49-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 Jan 2018
Research article |
| 08 Jan 2018
| 08 Jan 2018
A reference data set for validating vapor pressure measurement techniques: homologous series of polyethylene glycols
Ulrich K. Krieger
CORRESPONDING AUTHOR
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Franziska Siegrist
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Claudia Marcolli
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Eva U. Emanuelsson
Department of Chemistry, Aarhus University, 8000 Aarhus, Denmark
Freya M. Gøbel
Department of Chemistry, Aarhus University, 8000 Aarhus, Denmark
Merete Bilde
Department of Chemistry, Aarhus University, 8000 Aarhus, Denmark
Aleksandra Marsh
School of Chemistry, University of Bristol, BS8 1TS Bristol, UK
Jonathan P. Reid
School of Chemistry, University of Bristol, BS8 1TS Bristol, UK
Andrew J. Huisman
Chemistry Department, Union College, Schenectady, NY 12308, USA
Ilona Riipinen
Department of Environmental Science and Analytical Chemistry, Stockholm University, 106 91 Stockholm, Sweden
Noora Hyttinen
Department of Chemistry, University of Helsinki, 00014 Helsinki, Finland
Nanna Myllys
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Theo Kurtén
Department of Chemistry, University of Helsinki, 00014 Helsinki, Finland
Thomas Bannan
Centre for Atmospheric Sciences, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
Carl J. Percival
Centre for Atmospheric Sciences, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
David Topping
Centre for Atmospheric Sciences, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
Viewed
Total article views: 4,814 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 06 Jul 2017)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 2,613 | 2,075 | 126 | 4,814 | 117 | 124 |
- HTML: 2,613
- PDF: 2,075
- XML: 126
- Total: 4,814
- BibTeX: 117
- EndNote: 124
Total article views: 3,940 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 08 Jan 2018)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 2,186 | 1,636 | 118 | 3,940 | 110 | 115 |
- HTML: 2,186
- PDF: 1,636
- XML: 118
- Total: 3,940
- BibTeX: 110
- EndNote: 115
Total article views: 874 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 06 Jul 2017)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 427 | 439 | 8 | 874 | 7 | 9 |
- HTML: 427
- PDF: 439
- XML: 8
- Total: 874
- BibTeX: 7
- EndNote: 9
Viewed (geographical distribution)
Total article views: 4,814 (including HTML, PDF, and XML)
Thereof 4,702 with geography defined
and 112 with unknown origin.
Total article views: 3,940 (including HTML, PDF, and XML)
Thereof 3,854 with geography defined
and 86 with unknown origin.
Total article views: 874 (including HTML, PDF, and XML)
Thereof 848 with geography defined
and 26 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
41 citations as recorded by crossref.
- Atmospheric clusters to nanoparticles: Recent progress and challenges in closing the gap in chemical composition J. Smith et al. 10.1016/j.jaerosci.2020.105733
- On evaporation kinetics of multicomponent aerosols: Characteristic times and implications for volatility measurements A. Khlystov 10.1080/02786826.2024.2385640
- Measured Solid State and Sub-Cooled Liquid Vapour Pressures of Benzaldehydes Using Knudsen Effusion Mass Spectrometry P. Shelley et al. 10.3390/atmos12030397
- Temperature-Controlled Dual-Beam Optical Trap for Single Particle Studies of Organic Aerosol A. Logozzo & T. Preston 10.1021/acs.jpca.1c09363
- Pore-Fiber Transport Dynamics of Aqueous Cosolvent Solutions in Paper S. Karimnejad et al. 10.1021/acs.langmuir.4c01965
- A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application T. Bannan et al. 10.5194/amt-12-1429-2019
- Field observations of C2 and C3 organosulfates and insights into their formation mechanisms at a suburban site in Hong Kong Y. Wang et al. 10.1016/j.scitotenv.2023.166851
- On the calibration of FIGAERO-ToF-CIMS: importance and impact of calibrant delivery for the particle-phase calibration A. Ylisirniö et al. 10.5194/amt-14-355-2021
- The effect of molecular weight and deposition temperature on the formation of poly(ethylene oxide) films using the femtosecond pulsed laser deposition D. Fischer 10.1002/pcr2.10153
- Measured solid state and subcooled liquid vapour pressures of nitroaromatics using Knudsen effusion mass spectrometry P. Shelley et al. 10.5194/acp-20-8293-2020
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Single-particle measurements and estimations of activity coefficients for semi-volatile organic compounds in organic aerosol of known chemical speciation T. Hilditch et al. 10.1039/D2EA00180B
- Vaporization enthalpies of self-associated aromatic compounds at 298.15 K: A review of existing data and the features of heat capacity correction. Part III. Polyphenols, polyanilines and aminophenols D. Bolmatenkov et al. 10.1016/j.jct.2024.107408
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Estimating the saturation vapor pressures of isoprene oxidation products C<sub>5</sub>H<sub>12</sub>O<sub>6</sub> and C<sub>5</sub>H<sub>10</sub>O<sub>6</sub> using COSMO-RS T. Kurtén et al. 10.5194/acp-18-17589-2018
- Steady-State Mass Balance Model for Predicting Particle–Gas Concentration Ratios of PBDEs F. Zhao et al. 10.1021/acs.est.0c04368
- Tutorial: Dynamic organic growth modeling with a volatility basis set D. Stolzenburg et al. 10.1016/j.jaerosci.2022.106063
- Optimization of process models for determining volatility distribution and viscosity of organic aerosols from isothermal particle evaporation data O. Tikkanen et al. 10.5194/acp-19-9333-2019
- Simultaneous Retrieval of the Size and Refractive Index of Suspended Droplets in a Linear Quadrupole Electrodynamic Balance C. Price et al. 10.1021/acs.jpca.9b10748
- Squeeze film absolute pressure sensors with sub-millipascal sensitivity M. Salimi et al. 10.1016/j.sna.2024.115450
- Probing the evaporation dynamics of semi-volatile organic compounds to reveal the thermodynamics of liquid–liquid phase separated aerosol J. Choczynski et al. 10.1039/D3SC05164A
- Sensorized tissue analogues enabled by a 3D-printed conductive organogel M. Crump et al. 10.1038/s41528-021-00104-0
- Densities of internally mixed organic-inorganic particles from mobility diameter measurements of aerodynamically classified aerosols E. Vokes et al. 10.1080/02786826.2022.2062293
- Unexpected concentration dependence of the mass accommodation coefficient of water on aqueous triethylene glycol droplets M. Gleichweit et al. 10.1039/D4CP00966E
- Measuring the Chemical Evolution of Levitated Particles: A Study on the Evaporation of Multicomponent Organic Aerosol R. Kohli & J. Davies 10.1021/acs.analchem.1c02890
- Impact of organic molecular structure on the estimation of atmospherically relevant physicochemical parameters G. Isaacman-VanWertz & B. Aumont 10.5194/acp-21-6541-2021
- Sensitivity Constraints of Extractive Electrospray for a Model System and Secondary Organic Aerosol D. Bell et al. 10.1021/acs.analchem.3c00441
- Surface equilibrium vapor pressure of organic nanoparticles measured from the dynamic-aerosol-size electrical mobility spectrometer E. Häkkinen et al. 10.5194/amt-17-4211-2024
- Single-particle experiments measuring humidity and inorganic salt effects on gas-particle partitioning of butenedial A. Birdsall et al. 10.5194/acp-19-14195-2019
- Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber Z. Li et al. 10.5194/acp-23-6863-2023
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
- A dual-droplet approach for measuring the hygroscopicity of aqueous aerosol J. Choczynski et al. 10.5194/amt-14-5001-2021
- Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS M. Le Breton et al. 10.5194/acp-18-10355-2018
- Gas-to-Particle Partitioning of Cyclohexene- and α-Pinene-Derived Highly Oxygenated Dimers Evaluated Using COSMOtherm N. Hyttinen et al. 10.1021/acs.jpca.0c11328
- Evolution of volatility and composition in sesquiterpene-mixed and <i>α</i>-pinene secondary organic aerosol particles during isothermal evaporation Z. Li et al. 10.5194/acp-21-18283-2021
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems A. Ylisirniö et al. 10.5194/acp-20-5629-2020
- Electrodynamic balance–mass spectrometry of single particles as a new platform for atmospheric chemistry research A. Birdsall et al. 10.5194/amt-11-33-2018
- Development of lithium attachment mass spectrometry – knudsen effusion and chemical ionisation mass spectrometry (KEMS, CIMS) A. Booth et al. 10.1039/C7AN01161J
- Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols B. Bzdek & J. Reid 10.1063/1.5002641
- Diffusivity measurements of volatile organics in levitated viscous aerosol particles S. Bastelberger et al. 10.5194/acp-17-8453-2017
37 citations as recorded by crossref.
- Atmospheric clusters to nanoparticles: Recent progress and challenges in closing the gap in chemical composition J. Smith et al. 10.1016/j.jaerosci.2020.105733
- On evaporation kinetics of multicomponent aerosols: Characteristic times and implications for volatility measurements A. Khlystov 10.1080/02786826.2024.2385640
- Measured Solid State and Sub-Cooled Liquid Vapour Pressures of Benzaldehydes Using Knudsen Effusion Mass Spectrometry P. Shelley et al. 10.3390/atmos12030397
- Temperature-Controlled Dual-Beam Optical Trap for Single Particle Studies of Organic Aerosol A. Logozzo & T. Preston 10.1021/acs.jpca.1c09363
- Pore-Fiber Transport Dynamics of Aqueous Cosolvent Solutions in Paper S. Karimnejad et al. 10.1021/acs.langmuir.4c01965
- A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application T. Bannan et al. 10.5194/amt-12-1429-2019
- Field observations of C2 and C3 organosulfates and insights into their formation mechanisms at a suburban site in Hong Kong Y. Wang et al. 10.1016/j.scitotenv.2023.166851
- On the calibration of FIGAERO-ToF-CIMS: importance and impact of calibrant delivery for the particle-phase calibration A. Ylisirniö et al. 10.5194/amt-14-355-2021
- The effect of molecular weight and deposition temperature on the formation of poly(ethylene oxide) films using the femtosecond pulsed laser deposition D. Fischer 10.1002/pcr2.10153
- Measured solid state and subcooled liquid vapour pressures of nitroaromatics using Knudsen effusion mass spectrometry P. Shelley et al. 10.5194/acp-20-8293-2020
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Single-particle measurements and estimations of activity coefficients for semi-volatile organic compounds in organic aerosol of known chemical speciation T. Hilditch et al. 10.1039/D2EA00180B
- Vaporization enthalpies of self-associated aromatic compounds at 298.15 K: A review of existing data and the features of heat capacity correction. Part III. Polyphenols, polyanilines and aminophenols D. Bolmatenkov et al. 10.1016/j.jct.2024.107408
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Estimating the saturation vapor pressures of isoprene oxidation products C<sub>5</sub>H<sub>12</sub>O<sub>6</sub> and C<sub>5</sub>H<sub>10</sub>O<sub>6</sub> using COSMO-RS T. Kurtén et al. 10.5194/acp-18-17589-2018
- Steady-State Mass Balance Model for Predicting Particle–Gas Concentration Ratios of PBDEs F. Zhao et al. 10.1021/acs.est.0c04368
- Tutorial: Dynamic organic growth modeling with a volatility basis set D. Stolzenburg et al. 10.1016/j.jaerosci.2022.106063
- Optimization of process models for determining volatility distribution and viscosity of organic aerosols from isothermal particle evaporation data O. Tikkanen et al. 10.5194/acp-19-9333-2019
- Simultaneous Retrieval of the Size and Refractive Index of Suspended Droplets in a Linear Quadrupole Electrodynamic Balance C. Price et al. 10.1021/acs.jpca.9b10748
- Squeeze film absolute pressure sensors with sub-millipascal sensitivity M. Salimi et al. 10.1016/j.sna.2024.115450
- Probing the evaporation dynamics of semi-volatile organic compounds to reveal the thermodynamics of liquid–liquid phase separated aerosol J. Choczynski et al. 10.1039/D3SC05164A
- Sensorized tissue analogues enabled by a 3D-printed conductive organogel M. Crump et al. 10.1038/s41528-021-00104-0
- Densities of internally mixed organic-inorganic particles from mobility diameter measurements of aerodynamically classified aerosols E. Vokes et al. 10.1080/02786826.2022.2062293
- Unexpected concentration dependence of the mass accommodation coefficient of water on aqueous triethylene glycol droplets M. Gleichweit et al. 10.1039/D4CP00966E
- Measuring the Chemical Evolution of Levitated Particles: A Study on the Evaporation of Multicomponent Organic Aerosol R. Kohli & J. Davies 10.1021/acs.analchem.1c02890
- Impact of organic molecular structure on the estimation of atmospherically relevant physicochemical parameters G. Isaacman-VanWertz & B. Aumont 10.5194/acp-21-6541-2021
- Sensitivity Constraints of Extractive Electrospray for a Model System and Secondary Organic Aerosol D. Bell et al. 10.1021/acs.analchem.3c00441
- Surface equilibrium vapor pressure of organic nanoparticles measured from the dynamic-aerosol-size electrical mobility spectrometer E. Häkkinen et al. 10.5194/amt-17-4211-2024
- Single-particle experiments measuring humidity and inorganic salt effects on gas-particle partitioning of butenedial A. Birdsall et al. 10.5194/acp-19-14195-2019
- Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber Z. Li et al. 10.5194/acp-23-6863-2023
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
- A dual-droplet approach for measuring the hygroscopicity of aqueous aerosol J. Choczynski et al. 10.5194/amt-14-5001-2021
- Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS M. Le Breton et al. 10.5194/acp-18-10355-2018
- Gas-to-Particle Partitioning of Cyclohexene- and α-Pinene-Derived Highly Oxygenated Dimers Evaluated Using COSMOtherm N. Hyttinen et al. 10.1021/acs.jpca.0c11328
- Evolution of volatility and composition in sesquiterpene-mixed and <i>α</i>-pinene secondary organic aerosol particles during isothermal evaporation Z. Li et al. 10.5194/acp-21-18283-2021
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems A. Ylisirniö et al. 10.5194/acp-20-5629-2020
4 citations as recorded by crossref.
- Electrodynamic balance–mass spectrometry of single particles as a new platform for atmospheric chemistry research A. Birdsall et al. 10.5194/amt-11-33-2018
- Development of lithium attachment mass spectrometry – knudsen effusion and chemical ionisation mass spectrometry (KEMS, CIMS) A. Booth et al. 10.1039/C7AN01161J
- Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols B. Bzdek & J. Reid 10.1063/1.5002641
- Diffusivity measurements of volatile organics in levitated viscous aerosol particles S. Bastelberger et al. 10.5194/acp-17-8453-2017
Discussed (final revised paper)
Discussed (preprint)
Latest update: 20 Nov 2024
Short summary
Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the literature often differ by several orders of magnitude between measurement techniques. These discrepancies exceed the stated uncertainty of each technique, which is generally reported to be smaller than a factor of 2. We determined saturation vapor pressures for the homologous series of polyethylene glycols ranging in vapor pressure at 298 K from 1E−7 Pa to 5E−2 Pa as a reference set.
Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the...
