Articles | Volume 11, issue 2
https://doi.org/10.5194/amt-11-881-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-881-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Feb 2018
Research article |
| 14 Feb 2018
| 14 Feb 2018
Field measurements of biogenic volatile organic compounds in the atmosphere using solid-phase microextraction Arrow
Luís Miguel Feijó Barreira
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Geoffroy Duporté
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Tuukka Rönkkö
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Jevgeni Parshintsev
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Kari Hartonen
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Lydia Hyrsky
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Enna Heikkinen
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Matti Jussila
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
Markku Kulmala
Department of Physics, University of Helsinki, P.O. Box 64,
00014 Helsinki, Finland
Marja-Liisa Riekkola
CORRESPONDING AUTHOR
Department of Chemistry, University of
Helsinki, P.O. Box 55, 00014 Helsinki, Finland
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- Direct Ambient Mass Spectrometry for Food, Beverage, and Agricultural Sample Analysis and Research L. Schmidtke et al. 10.1002/mas.70001
- Problems Caused by Moisture in Gas Chromatographic Analysis of Headspace SPME Samples of Short-Chain Amines K. Hartonen et al. 10.1007/s10337-018-3641-y
- Development of a flow‐cell coupled to dynamic SPME technique for automated measurement of fragrance emission from fabric J. Zou et al. 10.1002/ffj.3712
- Coping with the concurrent heatwaves and ozone extremes in China under a warming climate M. Li et al. 10.1016/j.scib.2024.05.034
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- Recent advances in breath analysis to track human health by new enrichment technologies C. Ghosh et al. 10.1002/jssc.201900769
- On-Line Sorbentless Cryogenic Needle Trap and GC–FID Method for the Extraction and Analysis of Trace Volatile Organic Compounds from Soil Samples D. Djozan et al. 10.1093/chromsci/bmaa056
- Fundamentals of and recent advances in sorbent-based headspace extractions A. Paiva et al. 10.1016/j.trac.2021.116252
- Exploring the volatile profile of whiskey samples using solid-phase microextraction Arrow and comprehensive two-dimensional gas chromatography-mass spectrometry A. Ferracane et al. 10.1016/j.chroma.2022.463241
- Trends and applications in plant volatile sampling and analysis D. Tholl et al. 10.1111/tpj.15176
- Comparison of multiple calibration approaches for the determination of volatile organic compounds in air samples by solid phase microextraction Arrow and in-tube extraction J. Ruiz-Jimenez et al. 10.1016/j.chroma.2019.460825
- Fan-based device for integrated air sampling and microextraction F. Casado-Carmona et al. 10.1016/j.talanta.2021.122290
- A Preliminary Study for Ultraviolet Optical Methyl Salicylate Monitoring in Agriculture I. Di Bari et al. 10.3390/s25103021
- Elevated [CO2] enhances soil respiration and AMF abundance in a semiarid peanut agroecosystem H. E. Laza et al. 10.1016/j.agee.2023.108592
- Solid phase microextraction Arrow for the determination of synthetic musk fragrances in fish samples Ó. Castro et al. 10.1016/j.chroma.2019.01.032
- Aerial drone as a carrier for miniaturized air sampling systems J. Ruiz-Jimenez et al. 10.1016/j.chroma.2019.04.009
- Analyzing volatiles in brown rice vinegar by headspace solid-phase microextraction (SPME)–Arrow: Optimizing the extraction conditions and comparisons with conventional SPME T. Nam et al. 10.1080/10942912.2019.1634099
- Predicting Indonesian coffee origins using untargeted SPME − GCMS - based volatile compounds fingerprinting and machine learning approaches F. Aurum et al. 10.1007/s00217-023-04281-2
- Analytical Technique Optimization on the Detection of β-cyclocitral in Microcystis Species R. Yamashita et al. 10.3390/molecules25040832
- Overview: Recent advances in the understanding of the northern Eurasian environments and of the urban air quality in China – a Pan-Eurasian Experiment (PEEX) programme perspective H. Lappalainen et al. 10.5194/acp-22-4413-2022
- Miniaturised air sampling techniques for analysis of volatile organic compounds in air H. Lan et al. 10.1016/j.trac.2020.115873
- Fully Automated Online Dynamic In-Tube Extraction for Continuous Sampling of Volatile Organic Compounds in Air H. Lan et al. 10.1021/acs.analchem.9b01668
- Quantitative analysis and spatial and temporal distribution of volatile organic compounds in atmospheric air by utilizing drone with miniaturized samplers H. Lan et al. 10.1016/j.chemosphere.2021.131024
- Application of solid-phase microextraction arrows for characterizing volatile organic compounds from 3D printing of acrylonitrile-styrene-acrylate filament J. Minář et al. 10.1016/j.chroma.2023.464180
- Determination and Characteristic Analysis of Atmospheric Non-Methane Hydrocarbons in a Regional Hub City of North China Plain J. Wang et al. 10.1088/1755-1315/223/1/012052
- Comprehensive Strategy for Sample Preparation for the Analysis of Food Contaminants and Residues by GC–MS/MS: A Review of Recent Research Trends M. Xu et al. 10.3390/foods10102473
- Comparison of headspace–SPME and SPME-Arrow–GC–MS methods for the determination of volatile compounds in Korean salt–fermented fish sauce N. Song et al. 10.1186/s13765-019-0424-6
- Needle-based extraction techniques with protected sorbent as powerful sample preparation tools to gas chromatographic analysis: Trends in application K. Kędziora-Koch & W. Wasiak 10.1016/j.chroma.2018.06.046
- Optimization and automation of rapid and selective analysis of fatty acid methyl esters from aqueous samples by headspace SPME arrow extraction followed by GC–MS/MS analysis L. Tintrop et al. 10.1007/s00216-022-04204-2
- Solid-Phase Microextraction Arrow for the Sampling of Volatile Organic Compounds in Milk Samples N. Manousi et al. 10.3390/separations7040075
31 citations as recorded by crossref.
- Low Molecular Weight Volatile Organic Compounds Indicate Grazing by the Marine Rotifer Brachionus plicatilis on the Microalgae Microchloropsis salina C. Fisher et al. 10.3390/metabo10090361
- Direct Ambient Mass Spectrometry for Food, Beverage, and Agricultural Sample Analysis and Research L. Schmidtke et al. 10.1002/mas.70001
- Problems Caused by Moisture in Gas Chromatographic Analysis of Headspace SPME Samples of Short-Chain Amines K. Hartonen et al. 10.1007/s10337-018-3641-y
- Development of a flow‐cell coupled to dynamic SPME technique for automated measurement of fragrance emission from fabric J. Zou et al. 10.1002/ffj.3712
- Coping with the concurrent heatwaves and ozone extremes in China under a warming climate M. Li et al. 10.1016/j.scib.2024.05.034
- Selective extraction of aliphatic amines by functionalized mesoporous silica-coated solid phase microextraction Arrow H. Lan et al. 10.1007/s00604-019-3523-5
- Recent advances in breath analysis to track human health by new enrichment technologies C. Ghosh et al. 10.1002/jssc.201900769
- On-Line Sorbentless Cryogenic Needle Trap and GC–FID Method for the Extraction and Analysis of Trace Volatile Organic Compounds from Soil Samples D. Djozan et al. 10.1093/chromsci/bmaa056
- Fundamentals of and recent advances in sorbent-based headspace extractions A. Paiva et al. 10.1016/j.trac.2021.116252
- Exploring the volatile profile of whiskey samples using solid-phase microextraction Arrow and comprehensive two-dimensional gas chromatography-mass spectrometry A. Ferracane et al. 10.1016/j.chroma.2022.463241
- Trends and applications in plant volatile sampling and analysis D. Tholl et al. 10.1111/tpj.15176
- Comparison of multiple calibration approaches for the determination of volatile organic compounds in air samples by solid phase microextraction Arrow and in-tube extraction J. Ruiz-Jimenez et al. 10.1016/j.chroma.2019.460825
- Fan-based device for integrated air sampling and microextraction F. Casado-Carmona et al. 10.1016/j.talanta.2021.122290
- A Preliminary Study for Ultraviolet Optical Methyl Salicylate Monitoring in Agriculture I. Di Bari et al. 10.3390/s25103021
- Elevated [CO2] enhances soil respiration and AMF abundance in a semiarid peanut agroecosystem H. E. Laza et al. 10.1016/j.agee.2023.108592
- Solid phase microextraction Arrow for the determination of synthetic musk fragrances in fish samples Ó. Castro et al. 10.1016/j.chroma.2019.01.032
- Aerial drone as a carrier for miniaturized air sampling systems J. Ruiz-Jimenez et al. 10.1016/j.chroma.2019.04.009
- Analyzing volatiles in brown rice vinegar by headspace solid-phase microextraction (SPME)–Arrow: Optimizing the extraction conditions and comparisons with conventional SPME T. Nam et al. 10.1080/10942912.2019.1634099
- Predicting Indonesian coffee origins using untargeted SPME − GCMS - based volatile compounds fingerprinting and machine learning approaches F. Aurum et al. 10.1007/s00217-023-04281-2
- Analytical Technique Optimization on the Detection of β-cyclocitral in Microcystis Species R. Yamashita et al. 10.3390/molecules25040832
- Overview: Recent advances in the understanding of the northern Eurasian environments and of the urban air quality in China – a Pan-Eurasian Experiment (PEEX) programme perspective H. Lappalainen et al. 10.5194/acp-22-4413-2022
- Miniaturised air sampling techniques for analysis of volatile organic compounds in air H. Lan et al. 10.1016/j.trac.2020.115873
- Fully Automated Online Dynamic In-Tube Extraction for Continuous Sampling of Volatile Organic Compounds in Air H. Lan et al. 10.1021/acs.analchem.9b01668
- Quantitative analysis and spatial and temporal distribution of volatile organic compounds in atmospheric air by utilizing drone with miniaturized samplers H. Lan et al. 10.1016/j.chemosphere.2021.131024
- Application of solid-phase microextraction arrows for characterizing volatile organic compounds from 3D printing of acrylonitrile-styrene-acrylate filament J. Minář et al. 10.1016/j.chroma.2023.464180
- Determination and Characteristic Analysis of Atmospheric Non-Methane Hydrocarbons in a Regional Hub City of North China Plain J. Wang et al. 10.1088/1755-1315/223/1/012052
- Comprehensive Strategy for Sample Preparation for the Analysis of Food Contaminants and Residues by GC–MS/MS: A Review of Recent Research Trends M. Xu et al. 10.3390/foods10102473
- Comparison of headspace–SPME and SPME-Arrow–GC–MS methods for the determination of volatile compounds in Korean salt–fermented fish sauce N. Song et al. 10.1186/s13765-019-0424-6
- Needle-based extraction techniques with protected sorbent as powerful sample preparation tools to gas chromatographic analysis: Trends in application K. Kędziora-Koch & W. Wasiak 10.1016/j.chroma.2018.06.046
- Optimization and automation of rapid and selective analysis of fatty acid methyl esters from aqueous samples by headspace SPME arrow extraction followed by GC–MS/MS analysis L. Tintrop et al. 10.1007/s00216-022-04204-2
- Solid-Phase Microextraction Arrow for the Sampling of Volatile Organic Compounds in Milk Samples N. Manousi et al. 10.3390/separations7040075
Latest update: 19 Jul 2025
Short summary
Our results demonstrated the benefits and challenges of using new SPME Arrow over SPME fiber for the sampling of BVOCs emitted by terrestrial vegetation in the atmosphere. The new SPME Arrow system showed significant improvement on sampling capacity, with collected amounts being approximately 2 times higher for monoterpenes and 7–8 times higher for aldehydes than with SPME fiber. Higher extraction efficiencies were obtained with dynamic collection prior to equilibrium regime.
Our results demonstrated the benefits and challenges of using new SPME Arrow over SPME fiber for...
