Articles | Volume 11, issue 1
https://doi.org/10.5194/amt-11-95-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-95-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
10 Jan 2018
Research article |
| 10 Jan 2018
| 10 Jan 2018
Measurement of interferences associated with the detection of the hydroperoxy radical in the atmosphere using laser-induced fluorescence
Michelle M. Lew
Department of Chemistry, Indiana University, Bloomington, IN, USA
Sebastien Dusanter
IMT Lille Douai, Univ. Lille, SAGE – Département Sciences de
l'Atmosphère et Génie de l'Environnement, 59000 Lille,
France
School of Public and Environmental Affairs, Indiana University,
Bloomington, IN, USA
Department of Chemistry, Indiana University, Bloomington, IN, USA
School of Public and Environmental Affairs, Indiana University,
Bloomington, IN, USA
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Cited
27 citations as recorded by crossref.
- Measurements of Hydroxyl Radical Concentrations during Indoor Cooking Events: Evidence of an Unmeasured Photolytic Source of Radicals E. Reidy et al. 10.1021/acs.est.2c05756
- Airborne measurement of peroxy radicals using chemical amplification coupled with cavity ring-down spectroscopy: the PeRCEAS instrument M. George et al. 10.5194/amt-13-2577-2020
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. 10.1021/acsestair.4c00118
- Winter photochemistry in Beijing: Observation and model simulation of OH and HO2 radicals at an urban site X. Ma et al. 10.1016/j.scitotenv.2019.05.329
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Measurements of Atmospheric HO2 Radicals Using Br-CIMS with Elimination of Potential Interferences from Ambient Peroxynitric Acid L. Wang et al. 10.1021/acs.analchem.4c01184
- Evaluation of OH and HO<sub>2</sub> concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-18-11409-2018
- Analytical Challenges and Opportunities For Indoor Air Chemistry Field Studies D. Farmer 10.1021/acs.analchem.9b00277
- Overview of HOMEChem: House Observations of Microbial and Environmental Chemistry D. Farmer et al. 10.1039/C9EM00228F
- Application of a coupled model of photosynthesis and stomatal conductance for estimating plant physiological response to pollution by fine particulate matter (PM2.5) W. Yu et al. 10.1007/s11356-018-2128-6
- Peroxy radical measurements by ethane – nitric oxide chemical amplification and laser-induced fluorescence during the IRRONIC field campaign in a forest in Indiana S. Kundu et al. 10.5194/acp-19-9563-2019
- Experimental budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals and implications for ozone formation in the Pearl River Delta in China 2014 Z. Tan et al. 10.5194/acp-19-7129-2019
- Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/acp-18-8001-2018
- OH and HO<sub>2</sub> radical chemistry in a midlatitude forest: measurements and model comparisons M. Lew et al. 10.5194/acp-20-9209-2020
- Wintertime photochemistry in Beijing: observations of RO<sub><i>x</i></sub> radical concentrations in the North China Plain during the BEST-ONE campaign Z. Tan et al. 10.5194/acp-18-12391-2018
- Measurement of tropospheric HO2 radical using fluorescence assay by gas expansion with low interferences Y. Wang et al. 10.1016/j.jes.2020.06.010
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Observation and simulation of HOx radicals in an urban area in Shanghai, China G. Zhang et al. 10.1016/j.scitotenv.2021.152275
- Improved laser-induced fluorescent instrument for online peroxy radical measurement: Consistency in high-sensitivity for detection G. Zhang et al. 10.1016/j.snb.2024.136774
- Oxidation processes in the eastern Mediterranean atmosphere: evidence from the modelling of HO<sub><i>x</i></sub> measurements over Cyprus C. Mallik et al. 10.5194/acp-18-10825-2018
- Characterization of a chemical amplifier for peroxy radical measurements in the atmosphere M. Duncianu et al. 10.1016/j.atmosenv.2019.117106
- Insights into HO<sub><i>x</i></sub> and RO<sub><i>x</i></sub> chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. 10.5194/acp-18-13457-2018
- Biomass burning emission disturbances of isoprene oxidation in a tropical forest F. Santos et al. 10.5194/acp-18-12715-2018
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-20-3333-2020
- Measurements of hydroperoxy radicals (HO<sub>2</sub>) at atmospheric concentrations using bromide chemical ionisation mass spectrometry S. Albrecht et al. 10.5194/amt-12-891-2019
- Measurements of a potential interference with laser-induced fluorescence measurements of ambient OH from the ozonolysis of biogenic alkenes P. Rickly & P. Stevens 10.5194/amt-11-1-2018
26 citations as recorded by crossref.
- Measurements of Hydroxyl Radical Concentrations during Indoor Cooking Events: Evidence of an Unmeasured Photolytic Source of Radicals E. Reidy et al. 10.1021/acs.est.2c05756
- Airborne measurement of peroxy radicals using chemical amplification coupled with cavity ring-down spectroscopy: the PeRCEAS instrument M. George et al. 10.5194/amt-13-2577-2020
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. 10.1021/acsestair.4c00118
- Winter photochemistry in Beijing: Observation and model simulation of OH and HO2 radicals at an urban site X. Ma et al. 10.1016/j.scitotenv.2019.05.329
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Measurements of Atmospheric HO2 Radicals Using Br-CIMS with Elimination of Potential Interferences from Ambient Peroxynitric Acid L. Wang et al. 10.1021/acs.analchem.4c01184
- Evaluation of OH and HO<sub>2</sub> concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-18-11409-2018
- Analytical Challenges and Opportunities For Indoor Air Chemistry Field Studies D. Farmer 10.1021/acs.analchem.9b00277
- Overview of HOMEChem: House Observations of Microbial and Environmental Chemistry D. Farmer et al. 10.1039/C9EM00228F
- Application of a coupled model of photosynthesis and stomatal conductance for estimating plant physiological response to pollution by fine particulate matter (PM2.5) W. Yu et al. 10.1007/s11356-018-2128-6
- Peroxy radical measurements by ethane – nitric oxide chemical amplification and laser-induced fluorescence during the IRRONIC field campaign in a forest in Indiana S. Kundu et al. 10.5194/acp-19-9563-2019
- Experimental budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals and implications for ozone formation in the Pearl River Delta in China 2014 Z. Tan et al. 10.5194/acp-19-7129-2019
- Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/acp-18-8001-2018
- OH and HO<sub>2</sub> radical chemistry in a midlatitude forest: measurements and model comparisons M. Lew et al. 10.5194/acp-20-9209-2020
- Wintertime photochemistry in Beijing: observations of RO<sub><i>x</i></sub> radical concentrations in the North China Plain during the BEST-ONE campaign Z. Tan et al. 10.5194/acp-18-12391-2018
- Measurement of tropospheric HO2 radical using fluorescence assay by gas expansion with low interferences Y. Wang et al. 10.1016/j.jes.2020.06.010
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Observation and simulation of HOx radicals in an urban area in Shanghai, China G. Zhang et al. 10.1016/j.scitotenv.2021.152275
- Improved laser-induced fluorescent instrument for online peroxy radical measurement: Consistency in high-sensitivity for detection G. Zhang et al. 10.1016/j.snb.2024.136774
- Oxidation processes in the eastern Mediterranean atmosphere: evidence from the modelling of HO<sub><i>x</i></sub> measurements over Cyprus C. Mallik et al. 10.5194/acp-18-10825-2018
- Characterization of a chemical amplifier for peroxy radical measurements in the atmosphere M. Duncianu et al. 10.1016/j.atmosenv.2019.117106
- Insights into HO<sub><i>x</i></sub> and RO<sub><i>x</i></sub> chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. 10.5194/acp-18-13457-2018
- Biomass burning emission disturbances of isoprene oxidation in a tropical forest F. Santos et al. 10.5194/acp-18-12715-2018
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-20-3333-2020
- Measurements of hydroperoxy radicals (HO<sub>2</sub>) at atmospheric concentrations using bromide chemical ionisation mass spectrometry S. Albrecht et al. 10.5194/amt-12-891-2019
Latest update: 17 Nov 2024
Short summary
This paper describes measurements of the conversion efficiency of several organic peroxy radicals upon reaction with nitric oxide to the hydroperoxy radical, which can interfere with measurements of the latter. This interference could explain some of the discrepancies between measurements and model predictions of the hydroperoxy radical. Previous measurements of the hydroperoxy radical during the Mexico City Metropolitan Area campaign in 2006 are reanalyzed to account for the interference.
This paper describes measurements of the conversion efficiency of several organic peroxy...
