Articles | Volume 11, issue 1
https://doi.org/10.5194/amt-11-95-2018
https://doi.org/10.5194/amt-11-95-2018
Research article
 | 
10 Jan 2018
Research article |  | 10 Jan 2018

Measurement of interferences associated with the detection of the hydroperoxy radical in the atmosphere using laser-induced fluorescence

Michelle M. Lew, Sebastien Dusanter, and Philip S. Stevens

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Short summary
This paper describes measurements of the conversion efficiency of several organic peroxy radicals upon reaction with nitric oxide to the hydroperoxy radical, which can interfere with measurements of the latter. This interference could explain some of the discrepancies between measurements and model predictions of the hydroperoxy radical. Previous measurements of the hydroperoxy radical during the Mexico City Metropolitan Area campaign in 2006 are reanalyzed to account for the interference.