Atmospheric Measurement Techniques
Atmospheric Measurement Techniques
AMT
Articles | Volume 12, issue 2
Articles | Volume 12, issue 2
https://doi.org/10.5194/amt-12-1141-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-1141-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 12, issue 2
Research article
 | 
22 Feb 2019
Research article |  | 22 Feb 2019

Large-volume air sample system for measuring 34S∕32S isotope ratio of carbonyl sulfide

Kazuki Kamezaki, Shohei Hattori, Enno Bahlmann, and Naohiro Yoshida

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Short summary
Knowledge related to sulfur isotopic composition of carbonyl sulfide (OCS or COS), the most abundant atmospheric sulfur species, remains scarce. We present a new sampling system for collecting approx. 10 nmol of OCS from ambient air coupled with a purification system. The system presented herein is useful for application of sulfur isotopic compositions for investigation of OCS sources and sinks in the troposphere to elucidate its cycle and its contribution to background stratospheric sulfate.
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