Articles | Volume 12, issue 3
https://doi.org/10.5194/amt-12-1935-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-1935-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
26 Mar 2019
Research article |
| 26 Mar 2019
| 26 Mar 2019
Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement
Philipp G. Eger
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie,
55128 Mainz, Germany
Frank Helleis
Department of Natural Sciences, University of Chester, Chester CH2 4NU, UK
Gerhard Schuster
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie,
55128 Mainz, Germany
Gavin J. Phillips
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie,
55128 Mainz, Germany
Department of Natural Sciences, University of Chester, Chester CH2 4NU, UK
Jos Lelieveld
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie,
55128 Mainz, Germany
Atmospheric Chemistry Department, Max-Planck-Institut für Chemie,
55128 Mainz, Germany
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16 citations as recorded by crossref.
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- A vacuum ultraviolet ion source (VUV-IS) for iodide–chemical ionization mass spectrometry: a substitute for radioactive ion sources Y. Ji et al. 10.5194/amt-13-3683-2020
- Reactive nitrogen around the Arabian Peninsula and in the Mediterranean Sea during the 2017 AQABA ship campaign N. Friedrich et al. 10.5194/acp-21-7473-2021
- High Chlorine Concentrations in an Unconventional Oil and Gas Development Region and Impacts on Atmospheric Chemistry C. Masoud et al. 10.1021/acs.est.3c04005
- Improvements to a laser-induced fluorescence instrument for measuring SO<sub>2</sub> – impact on accuracy and precision P. Rickly et al. 10.5194/amt-14-2429-2021
- The Impacts of Peroxyacetyl Nitrate in the Atmosphere of Megacities and Large Urban Areas: A Historical Perspective J. Gaffney & N. Marley 10.1021/acsearthspacechem.1c00143
- Influence of vessel characteristics and atmospheric processes on the gas and particle phase of ship emission plumes: in situ measurements in the Mediterranean Sea and around the Arabian Peninsula S. Celik et al. 10.5194/acp-20-4713-2020
- Measurement report: Carbonyl sulfide production during dimethyl sulfide oxidation in the atmospheric simulation chamber SAPHIR M. von Hobe et al. 10.5194/acp-23-10609-2023
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) P. Dewald et al. 10.5194/amt-14-5501-2021
- Observationally constrained analysis of sulfur cycle in the marine atmosphere with NASA ATom measurements and AeroCom model simulations H. Bian et al. 10.5194/acp-24-1717-2024
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- Iodide CIMS and <i>m</i>∕<i>z</i> 62: the detection of HNO<sub>3</sub> as NO<sub>3</sub><sup>−</sup> in the presence of PAN, peroxyacetic acid and ozone R. Dörich et al. 10.5194/amt-14-5319-2021
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15 citations as recorded by crossref.
- Using tunable infrared laser direct absorption spectroscopy for ambient hydrogen chloride detection: HCl-TILDAS J. Halfacre et al. 10.5194/amt-16-1407-2023
- Shipborne measurements of ClNO<sub>2</sub> in the Mediterranean Sea and around the Arabian Peninsula during summer P. Eger et al. 10.5194/acp-19-12121-2019
- A vacuum ultraviolet ion source (VUV-IS) for iodide–chemical ionization mass spectrometry: a substitute for radioactive ion sources Y. Ji et al. 10.5194/amt-13-3683-2020
- Reactive nitrogen around the Arabian Peninsula and in the Mediterranean Sea during the 2017 AQABA ship campaign N. Friedrich et al. 10.5194/acp-21-7473-2021
- High Chlorine Concentrations in an Unconventional Oil and Gas Development Region and Impacts on Atmospheric Chemistry C. Masoud et al. 10.1021/acs.est.3c04005
- Improvements to a laser-induced fluorescence instrument for measuring SO<sub>2</sub> – impact on accuracy and precision P. Rickly et al. 10.5194/amt-14-2429-2021
- The Impacts of Peroxyacetyl Nitrate in the Atmosphere of Megacities and Large Urban Areas: A Historical Perspective J. Gaffney & N. Marley 10.1021/acsearthspacechem.1c00143
- Influence of vessel characteristics and atmospheric processes on the gas and particle phase of ship emission plumes: in situ measurements in the Mediterranean Sea and around the Arabian Peninsula S. Celik et al. 10.5194/acp-20-4713-2020
- Measurement report: Carbonyl sulfide production during dimethyl sulfide oxidation in the atmospheric simulation chamber SAPHIR M. von Hobe et al. 10.5194/acp-23-10609-2023
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) P. Dewald et al. 10.5194/amt-14-5501-2021
- Observationally constrained analysis of sulfur cycle in the marine atmosphere with NASA ATom measurements and AeroCom model simulations H. Bian et al. 10.5194/acp-24-1717-2024
- A dopant-assisted iodide-adduct chemical ionization time-of-flight mass spectrometer based on VUV lamp photoionization for atmospheric low-molecular-weight organic acids analysis Y. Zhang et al. 10.1016/j.jes.2024.01.008
- Iodide CIMS and <i>m</i>∕<i>z</i> 62: the detection of HNO<sub>3</sub> as NO<sub>3</sub><sup>−</sup> in the presence of PAN, peroxyacetic acid and ozone R. Dörich et al. 10.5194/amt-14-5319-2021
Latest update: 23 Apr 2024
Short summary
We present a chemical ionization quadrupole mass spectrometer (CI-QMS) with a novel discharge ion source. In addition to the expected detection of PAN, peracetic acid and ClNO2, the instrument is also sensitive to SO2, HCl and acetic acid through ion chemistry unique for our ion source. We present ionization schemes along with illustrative datasets from field campaigns underlining the potential of the CI-QMS as an alternative to polonium, especially for application in the marine boundary layer.
We present a chemical ionization quadrupole mass spectrometer (CI-QMS) with a novel discharge...
