Articles | Volume 12, issue 1
https://doi.org/10.5194/amt-12-299-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-299-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
17 Jan 2019
Research article |
| 17 Jan 2019
| 17 Jan 2019
HOx and NOx production in oxidation flow reactors via photolysis of isopropyl nitrite, isopropyl nitrite-d7, and 1,3-propyl dinitrite at λ = 254, 350, and 369 nm
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Jordan E. Krechmer
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Dept. of Chemistry and Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
Jason R. Casar
Dept. of Chemistry, Harvey Mudd College, Claremont, CA, USA
Anthony J. Carrasquillo
Dept. of Chemistry, Williams College, Williamstown, MA, USA
Jonathan D. Raff
School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
Jose L. Jimenez
Dept. of Chemistry and Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
Douglas R. Worsnop
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Dept. of Physics, University of Helsinki, Helsinki, Finland
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Cited
21 citations as recorded by crossref.
- Peking University Cold Aerosol Flow Tube (PKU-CAT): Development and Characterization for Studying Wintertime Secondary Organic Aerosol Formation J. Wang et al. https://doi.org/10.1021/acsenvironau.5c00298
- Decamethylcyclopentasiloxane (D5) Oxidation: Product Chemistry, Influence of RO2 Fate, and Secondary Aerosol Production S. Mohammadi et al. https://doi.org/10.1021/acsestair.6c00037
- Insights Into Formation and Aging of Secondary Organic Aerosol From Oxidation Flow Reactors: A Review Z. Zhang et al. https://doi.org/10.1007/s40726-024-00309-7
- Direct observation of the intermediate radical in the photodissociation of 1,3-cyclohexane dinitrite T. Qin et al. https://doi.org/10.1039/C9CP03895G
- Investigating the Potential of Essential Oils from Citrus reticulata Leaves in Mitigating Memory Decline and Oxidative Stress in the Scopolamine-Treated Zebrafish Model I. Brinza et al. https://doi.org/10.3390/plants13121648
- KinSim: A Research-Grade, User-Friendly, Visual Kinetics Simulator for Chemical-Kinetics and Environmental-Chemistry Teaching Z. Peng & J. Jimenez https://doi.org/10.1021/acs.jchemed.9b00033
- Nitrate radical generation via continuous generation of dinitrogen pentoxide in a laminar flow reactor coupled to an oxidation flow reactor A. Lambe et al. https://doi.org/10.5194/amt-13-2397-2020
- Photoinitiated Degradation Kinetics of the Organic UV Filter Oxybenzone in Solutions and Aerosols: Impacts of Salt, Photosensitizers, and the Medium A. Cooper et al. https://doi.org/10.1021/acsestair.4c00149
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez https://doi.org/10.1039/C9CS00766K
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al. https://doi.org/10.1021/acs.jpca.1c08427
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al. https://doi.org/10.5194/amt-17-4915-2024
- Structural effect on electron impact decomposition of 1,3- and 1,4-cyclohexane dinitrites T. Qin et al. https://doi.org/10.1063/1674-0068/cjcp2102024
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. https://doi.org/10.1021/acsearthspacechem.2c00304
- Technical Note: Effect of varying the λ = 185 and 254 nm photon flux ratio on radical generation in oxidation flow reactors J. Rowe et al. https://doi.org/10.5194/acp-20-13417-2020
- Oxidation Flow Reactor Results in a Chinese Megacity Emphasize the Important Contribution of S/IVOCs to Ambient SOA Formation W. Hu et al. https://doi.org/10.1021/acs.est.1c03155
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. https://doi.org/10.1039/D2EA00018K
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al. https://doi.org/10.5194/acp-24-7961-2024
- The Role of Dietary Antioxidants in the Pathogenesis of Neurodegenerative Diseases and Their Impact on Cerebral Oxidoreductive Balance A. Winiarska-Mieczan et al. https://doi.org/10.3390/nu12020435
- Comparison of oxidation products generated from the reaction of α-pinene with hydroxyl radicals, chlorine atoms, and bromine atoms measured using ammonium adduct chemical ionization mass spectrometry A. Lambe et al. https://doi.org/10.1039/D5EA00091B
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. https://doi.org/10.5194/acp-20-9563-2020
- Technical note: Gas-phase nitrate radical generation via irradiation of aerated ceric ammonium nitrate mixtures A. Lambe et al. https://doi.org/10.5194/acp-23-13869-2023
21 citations as recorded by crossref.
- Peking University Cold Aerosol Flow Tube (PKU-CAT): Development and Characterization for Studying Wintertime Secondary Organic Aerosol Formation J. Wang et al. https://doi.org/10.1021/acsenvironau.5c00298
- Decamethylcyclopentasiloxane (D5) Oxidation: Product Chemistry, Influence of RO2 Fate, and Secondary Aerosol Production S. Mohammadi et al. https://doi.org/10.1021/acsestair.6c00037
- Insights Into Formation and Aging of Secondary Organic Aerosol From Oxidation Flow Reactors: A Review Z. Zhang et al. https://doi.org/10.1007/s40726-024-00309-7
- Direct observation of the intermediate radical in the photodissociation of 1,3-cyclohexane dinitrite T. Qin et al. https://doi.org/10.1039/C9CP03895G
- Investigating the Potential of Essential Oils from Citrus reticulata Leaves in Mitigating Memory Decline and Oxidative Stress in the Scopolamine-Treated Zebrafish Model I. Brinza et al. https://doi.org/10.3390/plants13121648
- KinSim: A Research-Grade, User-Friendly, Visual Kinetics Simulator for Chemical-Kinetics and Environmental-Chemistry Teaching Z. Peng & J. Jimenez https://doi.org/10.1021/acs.jchemed.9b00033
- Nitrate radical generation via continuous generation of dinitrogen pentoxide in a laminar flow reactor coupled to an oxidation flow reactor A. Lambe et al. https://doi.org/10.5194/amt-13-2397-2020
- Photoinitiated Degradation Kinetics of the Organic UV Filter Oxybenzone in Solutions and Aerosols: Impacts of Salt, Photosensitizers, and the Medium A. Cooper et al. https://doi.org/10.1021/acsestair.4c00149
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez https://doi.org/10.1039/C9CS00766K
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al. https://doi.org/10.1021/acs.jpca.1c08427
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al. https://doi.org/10.5194/amt-17-4915-2024
- Structural effect on electron impact decomposition of 1,3- and 1,4-cyclohexane dinitrites T. Qin et al. https://doi.org/10.1063/1674-0068/cjcp2102024
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. https://doi.org/10.1021/acsearthspacechem.2c00304
- Technical Note: Effect of varying the λ = 185 and 254 nm photon flux ratio on radical generation in oxidation flow reactors J. Rowe et al. https://doi.org/10.5194/acp-20-13417-2020
- Oxidation Flow Reactor Results in a Chinese Megacity Emphasize the Important Contribution of S/IVOCs to Ambient SOA Formation W. Hu et al. https://doi.org/10.1021/acs.est.1c03155
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. https://doi.org/10.1039/D2EA00018K
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al. https://doi.org/10.5194/acp-24-7961-2024
- The Role of Dietary Antioxidants in the Pathogenesis of Neurodegenerative Diseases and Their Impact on Cerebral Oxidoreductive Balance A. Winiarska-Mieczan et al. https://doi.org/10.3390/nu12020435
- Comparison of oxidation products generated from the reaction of α-pinene with hydroxyl radicals, chlorine atoms, and bromine atoms measured using ammonium adduct chemical ionization mass spectrometry A. Lambe et al. https://doi.org/10.1039/D5EA00091B
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. https://doi.org/10.5194/acp-20-9563-2020
- Technical note: Gas-phase nitrate radical generation via irradiation of aerated ceric ammonium nitrate mixtures A. Lambe et al. https://doi.org/10.5194/acp-23-13869-2023
Saved (final revised paper)
Latest update: 04 Aug 2026
Short summary
This paper is an evaluation of methods used to generate OH radicals under conditions with high concentrations of NO and NO2 to simulate oxidation chemistry in polluted urban atmospheres over equivalent atmospheric timescales of ~ 1 day.
This paper is an evaluation of methods used to generate OH radicals under conditions with high...
