Articles | Volume 12, issue 6
https://doi.org/10.5194/amt-12-3137-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-3137-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
13 Jun 2019
Research article |
| 13 Jun 2019
| 13 Jun 2019
Effects of gas–wall interactions on measurements of semivolatile compounds and small polar molecules
Xiaoxi Liu
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Benjamin Deming
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Demetrios Pagonis
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Douglas A. Day
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Brett B. Palm
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Ranajit Talukdar
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
James M. Roberts
NOAA Chemical Sciences Division, Earth Systems Research Laboratory, Boulder, CO, USA
Patrick R. Veres
NOAA Chemical Sciences Division, Earth Systems Research Laboratory, Boulder, CO, USA
Jordan E. Krechmer
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Joel A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Joost A. de Gouw
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Paul J. Ziemann
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Jose L. Jimenez
CORRESPONDING AUTHOR
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
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Latest update: 30 Mar 2025
Short summary
Delays or losses of gases in sampling tubing and instrumental surfaces due to surface interactions can lead to inaccurate quantification. By sampling with several chemical ionization mass spectrometers and six tubing materials, we quantify delays of semivolatile organic compounds and small polar gases. Delay times generally increase with decreasing volatility or increasing polarity and also depend on materials. The method and results will inform inlet material selection and instrumental design.
Delays or losses of gases in sampling tubing and instrumental surfaces due to surface...
