Articles | Volume 13, issue 5
https://doi.org/10.5194/amt-13-2501-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/amt-13-2501-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
19 May 2020
Research article |
| 19 May 2020
| 19 May 2020
Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry
CERN, 1211 Geneva, Switzerland
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
Mario Simon
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
Martin Heinritzi
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
Felix Piel
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
now at: Ionicon Analytik GmbH, 6020 Innsbruck, Austria
Lena Weitz
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
now at: GSI Helmholtzzentrum für Schwerionenforschung GmbH,
64291 Darmstadt, Germany
Dongyu Wang
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Manuel Granzin
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
Tatjana Müller
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
Steffen Bräkling
TOFWERK AG, 3600 Thun, Switzerland
Jasper Kirkby
CERN, 1211 Geneva, Switzerland
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
Joachim Curtius
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
Andreas Kürten
Institute for Atmospheric and Environmental Sciences, 60438, Goethe University Frakfurt Am Main, Germany
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- Rapid growth of new atmospheric particles by nitric acid and ammonia condensation M. Wang et al. 10.1038/s41586-020-2270-4
- Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry J. Pfeifer et al. 10.5194/amt-13-2501-2020
24 citations as recorded by crossref.
- Experimental and Theoretical Study on the Enhancement of Alkanolamines on Sulfuric Acid Nucleation S. Fomete et al. 10.1021/acs.jpca.2c01672
- Enhanced growth rate of atmospheric particles from sulfuric acid D. Stolzenburg et al. 10.5194/acp-20-7359-2020
- Perspective on the Recent Measurements of Reduced Nitrogen Compounds in the Atmosphere S. Lee 10.3389/fenvs.2022.868534
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- Passive Wireless Detection for Ammonia Based on 2.4 GHz Square Carbon Nanotube-Loaded Chipless RFID-Inspired Tag G. Shi et al. 10.1109/TIM.2023.3300433
- Nonagricultural Emissions Dominate Urban Atmospheric Amines as Revealed by Mobile Measurements Y. Chang et al. 10.1029/2021GL097640
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
- Airborne flux measurements of ammonia over the southern Great Plains using chemical ionization mass spectrometry S. Schobesberger et al. 10.5194/amt-16-247-2023
- Low-Cost Alternative for Online Analysis of Volatile Organic Compounds B. Rico et al. 10.1021/acs.analchem.4c00916
- Detection of gaseous dimethylamine using vocus proton-transfer-reaction time-of-flight mass spectrometry Y. Wang et al. 10.1016/j.atmosenv.2020.117875
- Wireless Volatile Organic Compound Detection for Restricted Internet of Things Environments Based on Cataluminescence Sensors X. Shen et al. 10.3390/chemosensors10050179
- Measurement of the collision rate coefficients between atmospheric ions and multiply charged aerosol particles in the CERN CLOUD chamber J. Pfeifer et al. 10.5194/acp-23-6703-2023
- The driving factors of new particle formation and growth in the polluted boundary layer M. Xiao et al. 10.5194/acp-21-14275-2021
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- Insights into the Chemistry of Iodine New Particle Formation: The Role of Iodine Oxides and the Source of Iodic Acid J. Gómez Martín et al. 10.1021/jacs.1c12957
- Evaluation of a reduced-pressure chemical ion reactor utilizing adduct ionization for the detection of gaseous organic and inorganic species M. Riva et al. 10.5194/amt-17-5887-2024
- A new advance in the pollution profile, transformation process, and contribution to aerosol formation and aging of atmospheric amines X. Shen et al. 10.1039/D2EA00167E
- Protonated acetone ion chemical ionization time-of-flight mass spectrometry for real-time measurement of atmospheric ammonia F. Dong et al. 10.1016/j.jes.2021.07.023
- On the development of a new prototype PTR-ToF-MS instrument and its application to the detection of atmospheric amines A. Håland et al. 10.5194/amt-15-6297-2022
- Measurement of iodine species and sulfuric acid using bromide chemical ionization mass spectrometers M. Wang et al. 10.5194/amt-14-4187-2021
- New particle formation from isoprene under upper-tropospheric conditions J. Shen et al. 10.1038/s41586-024-08196-0
- Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere X. He et al. 10.1126/science.adh2526
- Ion–Molecule Rate Constants for Reactions of Sulfuric Acid with Acetate and Nitrate Ions S. Fomete et al. 10.1021/acs.jpca.2c02072
- Recent progress in chemical ionization mass spectrometry and its application in atmospheric environment W. Li et al. 10.1016/j.atmosenv.2024.120426
2 citations as recorded by crossref.
Latest update: 04 Jul 2025
Short summary
Ammonia is an important atmospheric trace gas that affects secondary aerosol formation and, together with sulfuric acid, the formation of new particles. A measurement technique is presented that uses high-resolution mass spectrometry and protonated water clusters for the ultrasensitive detection of ammonia at single-digit parts per trillion by volume levels. The instrument is further capable of measuring amines and a suite of iodine compounds at sub-parts per trillion by volume levels.
Ammonia is an important atmospheric trace gas that affects secondary aerosol formation and,...
Special issue