Articles | Volume 13, issue 6
https://doi.org/10.5194/amt-13-3167-2020
https://doi.org/10.5194/amt-13-3167-2020
Research article
 | 
16 Jun 2020
Research article |  | 16 Jun 2020

Correcting the impact of the isotope composition on the mixing ratio dependency of water vapour isotope measurements with cavity ring-down spectrometers

Yongbiao Weng, Alexandra Touzeau, and Harald Sodemann

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Interactive discussion

Status: closed
Status: closed
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
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Peer-review completion

AR: Author's response | RR: Referee report | ED: Editor decision
AR by Yongbiao Weng on behalf of the Authors (14 Mar 2020)  Author's response   Manuscript 
ED: Referee Nomination & Report Request started (27 Mar 2020) by Christof Janssen
RR by Anonymous Referee #1 (31 Mar 2020)
RR by Anonymous Referee #3 (16 Apr 2020)
ED: Publish subject to minor revisions (review by editor) (20 Apr 2020) by Christof Janssen
AR by Yongbiao Weng on behalf of the Authors (30 Apr 2020)  Author's response   Manuscript 
ED: Publish subject to technical corrections (11 May 2020) by Christof Janssen
AR by Yongbiao Weng on behalf of the Authors (12 May 2020)  Author's response   Manuscript 
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Short summary
We find that the known mixing ratio dependence of laser spectrometers for water vapour isotope measurements varies with isotope composition. We have developed a scheme to correct for this isotope-composition-dependent bias. The correction is most substantial at low mixing ratios. Stability tests indicate that the first-order dependency is a constant instrument characteristic. Water vapour isotope measurements at low mixing ratios can now be corrected by following our proposed procedure.