Articles | Volume 13, issue 7
Research article
03 Jul 2020
Research article |  | 03 Jul 2020

Highly oxygenated organic molecule cluster decomposition in atmospheric pressure interface time-of-flight mass spectrometers

Tommaso Zanca, Jakub Kubečka, Evgeni Zapadinsky, Monica Passananti, Theo Kurtén, and Hanna Vehkamäki


Interactive discussion

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AR: Author's response | RR: Referee report | ED: Editor decision
AR by Tommaso Zanca on behalf of the Authors (03 May 2020)  Author's response    Manuscript
ED: Publish as is (23 May 2020) by Hartmut Herrmann
Short summary
In this paper we quantify (using a statistical model) the probability of decomposition of a representative class of HOM clusters in an APi-TOF mass spectrometer. This is important because it quantifies the systematic error of measurements in a APi-TOF MS due to cluster decomposition. The results (specific for our selected clusters) show that decomposition is negligible, provided their bonding energy is large enough to allow formation in the atmosphere in the first place.