Articles | Volume 14, issue 9
https://doi.org/10.5194/amt-14-5913-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-5913-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
02 Sep 2021
Research article |
| 02 Sep 2021
| 02 Sep 2021
Effects of aerosol size and coating thickness on the molecular detection using extractive electrospray ionization
Chuan Ping Lee
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Mihnea Surdu
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
David M. Bell
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Houssni Lamkaddam
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Mingyi Wang
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA
15213, USA
Farnoush Ataei
Department of Experimental Aerosol and Cloud Microphysics, Leibniz Institute for Tropospheric Research, 04318 Leipzig, Germany
Victoria Hofbauer
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA
15213, USA
Brandon Lopez
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Department of Chemical Engineering, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Neil M. Donahue
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA
15213, USA
Department of Chemical Engineering, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Department of Engineering and Public Policy, Carnegie Mellon
University, Pittsburgh, PA 15213, USA
Josef Dommen
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Andre S. H. Prevot
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Jay G. Slowik
CORRESPONDING AUTHOR
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Urs Baltensperger
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
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Cited
13 citations as recorded by crossref.
- Real-Time Identification of Aerosol-Phase Carboxylic Acid Production Using Extractive Electrospray Ionization Mass Spectrometry M. Surdu et al. 10.1021/acs.est.4c01605
- Emission and Formation of Aircraft Engine Oil Ultrafine Particles Z. Decker et al. 10.1021/acsestair.4c00184
- High-frequency gaseous and particulate chemical characterization using extractive electrospray ionization mass spectrometry (Dual-Phase-EESI-TOF) C. Lee et al. 10.5194/amt-15-3747-2022
- Particle-phase processing of α-pinene NO3 secondary organic aerosol in the dark D. Bell et al. 10.5194/acp-22-13167-2022
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Sensitivity Constraints of Extractive Electrospray for a Model System and Secondary Organic Aerosol D. Bell et al. 10.1021/acs.analchem.3c00441
- Photodegradation of naphthalene-derived particle oxidation products F. Sari Doré et al. 10.1039/D4EA00125G
- The characterization of ambient levoglucosan in Beijing during summertime: Dynamic variation and source contributions under strong cooking influences J. Wang et al. 10.1016/j.jes.2024.08.029
- The Evolution of Secondary/Extractive Electrospray Ionization: From Ionization Mechanism to Instrumental Advances G. Liao et al. 10.1002/mas.21931
- Effects of Relative Humidity and Phase on the Molecular Detection of Nascent Sea Spray Aerosol Using Extractive Electrospray Ionization S. Kruse et al. 10.1021/acs.analchem.4c02871
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
- Effects of aerosol size and coating thickness on the molecular detection using extractive electrospray ionization C. Lee et al. 10.5194/amt-14-5913-2021
12 citations as recorded by crossref.
- Real-Time Identification of Aerosol-Phase Carboxylic Acid Production Using Extractive Electrospray Ionization Mass Spectrometry M. Surdu et al. 10.1021/acs.est.4c01605
- Emission and Formation of Aircraft Engine Oil Ultrafine Particles Z. Decker et al. 10.1021/acsestair.4c00184
- High-frequency gaseous and particulate chemical characterization using extractive electrospray ionization mass spectrometry (Dual-Phase-EESI-TOF) C. Lee et al. 10.5194/amt-15-3747-2022
- Particle-phase processing of α-pinene NO3 secondary organic aerosol in the dark D. Bell et al. 10.5194/acp-22-13167-2022
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Sensitivity Constraints of Extractive Electrospray for a Model System and Secondary Organic Aerosol D. Bell et al. 10.1021/acs.analchem.3c00441
- Photodegradation of naphthalene-derived particle oxidation products F. Sari Doré et al. 10.1039/D4EA00125G
- The characterization of ambient levoglucosan in Beijing during summertime: Dynamic variation and source contributions under strong cooking influences J. Wang et al. 10.1016/j.jes.2024.08.029
- The Evolution of Secondary/Extractive Electrospray Ionization: From Ionization Mechanism to Instrumental Advances G. Liao et al. 10.1002/mas.21931
- Effects of Relative Humidity and Phase on the Molecular Detection of Nascent Sea Spray Aerosol Using Extractive Electrospray Ionization S. Kruse et al. 10.1021/acs.analchem.4c02871
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
Latest update: 24 May 2025
Short summary
Extractive electrospray ionization mass spectrometry (EESI-MS) has been deployed for high throughput online detection of particles with minimal fragmentation. Our study elucidates the extraction mechanism between the particles and electrospray (ES) droplets of different properties. The results show that the extraction rate is likely affected by the coagulation rate between the particles and ES droplets. Once coagulated, the particles undergo complete extraction within the ES droplet.
Extractive electrospray ionization mass spectrometry (EESI-MS) has been deployed for high...
