Articles | Volume 14, issue 9
Atmos. Meas. Tech., 14, 5913–5923, 2021
https://doi.org/10.5194/amt-14-5913-2021

Special issue: Simulation chambers as tools in atmospheric research (AMT/ACP/GMD...

Atmos. Meas. Tech., 14, 5913–5923, 2021
https://doi.org/10.5194/amt-14-5913-2021

Research article 02 Sep 2021

Research article | 02 Sep 2021

Effects of aerosol size and coating thickness on the molecular detection using extractive electrospray ionization

Chuan Ping Lee et al.

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Latest update: 28 Jan 2022
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Short summary
Extractive electrospray ionization mass spectrometry (EESI-MS) has been deployed for high throughput online detection of particles with minimal fragmentation. Our study elucidates the extraction mechanism between the particles and electrospray (ES) droplets of different properties. The results show that the extraction rate is likely affected by the coagulation rate between the particles and ES droplets. Once coagulated, the particles undergo complete extraction within the ES droplet.