Articles | Volume 15, issue 6
https://doi.org/10.5194/amt-15-1811-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-15-1811-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Mar 2022
Research article |
| 25 Mar 2022
| 25 Mar 2022
Fragmentation inside proton-transfer-reaction-based mass spectrometers limits the detection of ROOR and ROOH peroxides
School of Civil and Environmental Engineering, Harbin Institute of
Technology, Shenzhen, 518055, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Thomas Golin Almeida
Department of Chemistry, University of Helsinki, Helsinki, 00014,
Finland
Yuanyuan Luo
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Jian Zhao
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Brett B. Palm
Department of Atmospheric Science, University of Washington, Seattle, Washington, WA, 98195, USA
Christopher D. Daub
Department of Chemistry, University of Helsinki, Helsinki, 00014,
Finland
Wei Huang
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Claudia Mohr
Department of Environmental Science, Stockholm University, 11418,
Stockholm, Sweden
Jordan E. Krechmer
Aerodyne Research, Inc., Billerica, MA, 01821, USA
Theo Kurtén
CORRESPONDING AUTHOR
Department of Chemistry, University of Helsinki, Helsinki, 00014,
Finland
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
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- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Analytical methodologies for oxidized organic compounds in the atmosphere A. Tiusanen et al. 10.1039/D3EM00163F
- Dimeric product formation in the self-reaction of small peroxy radicals using synchrotron radiation vacuum ultraviolet photoionization mass spectrometry L. Liu et al. 10.1016/j.chemosphere.2024.142846
- Elucidating the photodissociation fingerprint and quantifying the determination of organic hydroperoxides in gas-phase autoxidation Z. Hu et al. 10.1073/pnas.2220131120
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20 citations as recorded by crossref.
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- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
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- Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al. 10.1021/acs.est.3c02895
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- Response of protonated, adduct, and fragmented ions in Vocus proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) F. Li et al. 10.5194/amt-17-2415-2024
- The gas phase ozonolysis and secondary OH production of cashmeran, a musk compound from fragrant volatile chemical products A. Akande & N. Borduas-Dedekind 10.1039/D4EM00452C
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Analytical methodologies for oxidized organic compounds in the atmosphere A. Tiusanen et al. 10.1039/D3EM00163F
- Dimeric product formation in the self-reaction of small peroxy radicals using synchrotron radiation vacuum ultraviolet photoionization mass spectrometry L. Liu et al. 10.1016/j.chemosphere.2024.142846
- Elucidating the photodissociation fingerprint and quantifying the determination of organic hydroperoxides in gas-phase autoxidation Z. Hu et al. 10.1073/pnas.2220131120
- Ammonium CI-Orbitrap: a tool for characterizing the reactivity of oxygenated organic molecules D. Li et al. 10.5194/amt-17-5413-2024
- Effect of an Electric Field on the Structure and Stability of Atmospheric Clusters C. Daub & T. Kurtén 10.1021/acs.jpca.3c07260
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Dimeric Product of Peroxy Radical Self-Reaction Probed with VUV Photoionization Mass Spectrometry and Theoretical Calculations: The Case of C2H5OOC2H5 H. Yue et al. 10.3390/ijms24043731
- Selective deuteration as a tool for resolving autoxidation mechanisms in α-pinene ozonolysis M. Meder et al. 10.5194/acp-23-4373-2023
- Pollution characteristics, source appointment and environmental effect of oxygenated volatile organic compounds in Guangdong-Hong Kong-Macao Greater Bay Area: Implication for air quality management G. Liu et al. 10.1016/j.scitotenv.2024.170836
- Strong Uptake of Gas-Phase Organic Peroxy Radicals (ROO•) by Solid Surfaces Driven by Redox Reactions O. Durif et al. 10.1021/jacsau.4c00060
1 citations as recorded by crossref.
Latest update: 23 Nov 2024
Short summary
This work evaluated the potential for PTR-based mass spectrometers to detect ROOR and ROOH peroxides both experimentally and through computations. Laboratory experiments using a Vocus PTR observed only noisy signals of potential dimers during α-pinene ozonolysis and a few small signals of dimeric compounds during cyclohexene ozonolysis. Quantum chemical calculations for model ROOR and ROOH systems showed that most of these peroxides should fragment partially following protonation.
This work evaluated the potential for PTR-based mass spectrometers to detect ROOR and ROOH...
