Atmospheric Measurement Techniques
Atmospheric Measurement Techniques
AMT
Articles | Volume 16, issue 4
Articles | Volume 16, issue 4
https://doi.org/10.5194/amt-16-1061-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-16-1061-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 16, issue 4
Research article
 | 
02 Mar 2023
Research article |  | 02 Mar 2023

Development of an International System of Units (SI)-traceable transmission curve reference material to improve the quantitation and comparability of proton-transfer-reaction mass-spectrometry measurements

David R. Worton, Sergi Moreno, Kieran O'Daly, and Rupert Holzinger

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Allen, N. D. C., Worton, D. R., Brewer, P. J., Pascale, C., and Niederhauser, B.: The importance of cylinder passivation for preparation and long-term stability of multicomponent monoterpene primary reference materials, Atmos. Meas. Tech., 11, 6429–6438, https://doi.org/10.5194/amt-11-6429-2018, 2018. 
Ammann, C., Spirig, C., Neftel, A., Steinbacher, M., Komenda, M., and Schaub, A.: Application of PTR-MS for measurements of biogenic VOC in a deciduous forest, Int. J. Mass Spectrom., 239, 87–101, https://doi.org/10.1016/j.ijms.2004.08.012, 2004. 
Beauchamp, J., Herbig, J., Dunkl, J., Singer, W., and Hansel, A.: On the performance of proton-transfer-reaction mass spectrometry for breath-relevant gas matrices, Meas. Sci. Technol., 24, 125003, https://doi.org/10.1088/0957-0233/24/12/125003, 2013. 
Biasioli, F., Gasperi, F., Yeretzian, C., and Märk, T. D.: PTR-MS monitoring of VOCs and BVOCs in food science and technology, TrAC-Trend. Anal. Chem., 30, 968–977, https://doi.org/10.1016/j.trac.2011.03.009, 2011. 
Blake, R. S., Monks, P. S., and Ellis, A. M.: Proton-Transfer Reaction Mass Spectrometry, Chem. Rev., 109, 861–896, https://doi.org/10.1021/cr800364q, 2009. 
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Proton-transfer-reaction mass spectrometry is widely used in the environmental, health, and food and beverage sectors. As a result, there is a need for accurate and comparable measurements. In this work we have developed a 20-component gravimetrically prepared traceable primary reference material (gas standard in a high-pressure cylinder) to enable quantitative and comparable measurements. The accuracy of all components was better than 3 %–10 % with stabilities of better than 1–2 years.
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