Articles | Volume 16, issue 1
https://doi.org/10.5194/amt-16-15-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-16-15-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Real-time measurement of phase partitioning of organic compounds using a proton-transfer-reaction time-of-flight mass spectrometer coupled to a CHARON inlet
Yarong Peng
Department of Environmental Science and Engineering, Fudan
University, Shanghai, 200438, China
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai, 200233, China
Hongli Wang
CORRESPONDING AUTHOR
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai, 200233, China
Yaqin Gao
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai, 200233, China
Shengao Jing
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai, 200233, China
Shuhui Zhu
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai, 200233, China
Dandan Huang
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai, 200233, China
Peizhi Hao
School of Natural Sciences, University of California, Merced, 95343, USA
Shengrong Lou
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai, 200233, China
Tiantao Cheng
CORRESPONDING AUTHOR
Department of Atmospheric and Oceanic Sciences, Fudan University,
Shanghai, 200438, China
Big Data Institute for Carbon Emission and Environmental Pollution,
Fudan University, Shanghai, 200438, China
Cheng Huang
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai, 200233, China
Xuan Zhang
CORRESPONDING AUTHOR
School of Natural Sciences, University of California, Merced, 95343, USA
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Cited
8 citations as recorded by crossref.
- Isoprene peroxy chemistry operates competitively in areas of East China K. DeMarsh et al. 10.1016/j.apgeochem.2023.105778
- Atmospheric organic aerosols: online molecular characterization and environmental impacts Y. Sun et al. 10.1038/s41612-025-01199-2
- Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant J. Song et al. 10.5194/acp-24-13199-2024
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- In situ measurements of gas–particle partitioning of organic compounds in Fairbanks A. Ijaz et al. 10.1039/D4FD00175C
- Advancing green analytical solutions: A review of proton transfer reaction mass spectrometry in atmospheric aerosol research Y. Li 10.1016/j.greeac.2024.100175
- Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany J. Song et al. 10.5194/acp-24-6699-2024
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
8 citations as recorded by crossref.
- Isoprene peroxy chemistry operates competitively in areas of East China K. DeMarsh et al. 10.1016/j.apgeochem.2023.105778
- Atmospheric organic aerosols: online molecular characterization and environmental impacts Y. Sun et al. 10.1038/s41612-025-01199-2
- Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant J. Song et al. 10.5194/acp-24-13199-2024
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- In situ measurements of gas–particle partitioning of organic compounds in Fairbanks A. Ijaz et al. 10.1039/D4FD00175C
- Advancing green analytical solutions: A review of proton transfer reaction mass spectrometry in atmospheric aerosol research Y. Li 10.1016/j.greeac.2024.100175
- Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany J. Song et al. 10.5194/acp-24-6699-2024
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
Latest update: 03 Sep 2025
Short summary
This work examined the phase partitioning behaviors of organic compounds at hourly resolution in ambient conditions with the use of the CHemical Analysis of aeRosols ONline (CHARON) inlet coupled to a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS). Properly accounting for the neutral losses of small moieties during the molecular feature extraction from PTR mass spectra could significantly reduce uncertainties associated with the gas–particle partitioning measurements.
This work examined the phase partitioning behaviors of organic compounds at hourly resolution in...