Articles | Volume 16, issue 19
https://doi.org/10.5194/amt-16-4461-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-16-4461-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
09 Oct 2023
Research article |
| 09 Oct 2023
| 09 Oct 2023
Characterisation of gaseous iodine species detection using the multi-scheme chemical ionisation inlet 2 with bromide and nitrate chemical ionisation methods
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Finnish Meteorological Institute, 00560 Helsinki, Finland
Jiali Shen
CORRESPONDING AUTHOR
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Siddharth Iyer
Aerosol Physics Laboratory, Faculty of Engineering and Natural Sciences, Tampere University, 33014 Tampere, Finland
Paxton Juuti
Karsa Ltd., 00560 Helsinki, Finland
Jiangyi Zhang
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Mrisha Koirala
Department of Chemistry, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Mikko M. Kytökari
Department of Chemistry, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Douglas R. Worsnop
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Aerodyne Research, Inc., Billerica, 01821 MA, USA
Matti Rissanen
Aerosol Physics Laboratory, Faculty of Engineering and Natural Sciences, Tampere University, 33014 Tampere, Finland
Department of Chemistry, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Markku Kulmala
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Helsinki Institute of Physics, University of Helsinki, 00014 Helsinki, Finland
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, 210023 Nanjing, China
Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, 100029 Beijing, China
Norbert M. Maier
Department of Chemistry, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Jyri Mikkilä
Karsa Ltd., 00560 Helsinki, Finland
Mikko Sipilä
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Juha Kangasluoma
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Karsa Ltd., 00560 Helsinki, Finland
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Cited
15 citations as recorded by crossref.
- Characterisation of gaseous iodine species detection using the multi-scheme chemical ionisation inlet 2 with bromide and nitrate chemical ionisation methods X. He et al. 10.5194/amt-16-4461-2023
- Decomposition of Clusters of Oxygenated Compounds with NO3– by Applying Voltage Scanning to Chemical Ionization Mass Spectrometry in Steady-State Experiments H. Wang et al. 10.1021/acs.estlett.4c00276
- Temperature, humidity, and ionisation effect of iodine oxoacid nucleation B. Rörup et al. 10.1039/D4EA00013G
- Multiphysical description of atmospheric pressure interface chemical ionisation in MION2 and Eisele type inlets H. Finkenzeller et al. 10.5194/amt-17-5989-2024
- The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition M. Boyer et al. 10.5194/acp-24-12595-2024
- Data‐Driven Compound Identification in Atmospheric Mass Spectrometry H. Sandström et al. 10.1002/advs.202306235
- Iodine oxoacids and their roles in sub-3 nm particle growth in polluted urban environments Y. Zhang et al. 10.5194/acp-24-1873-2024
- 1-Hexene Ozonolysis across Atmospheric and Combustion Temperatures via Synchrotron-Based Photoelectron Spectroscopy and Chemical Ionization Mass Spectrometry C. Smith Lewin et al. 10.1021/acs.jpca.4c02687
- From Hydrocarbons to Highly Functionalized Molecules in a Single Measurement: Comprehensive Analysis of Complex Gas Mixtures by Multi-Pressure Chemical Ionization Mass Spectrometry A. Shcherbinin et al. 10.1021/acs.analchem.4c03859
- Gas‐Phase Formation of Sulfurous Acid (H2SO3) in the Atmosphere T. Berndt et al. 10.1002/anie.202405572
- Gasphasenbildung von Schwefliger Säure (H2SO3) in der Atmosphäre T. Berndt et al. 10.1002/ange.202405572
- Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al. 10.1021/acs.analchem.4c00650
- Enhanced detection of aromatic oxidation products using NO3− chemical ionization mass spectrometry with limited nitric acid O. Garmash et al. 10.1039/D4EA00087K
- New particle formation from isoprene under upper-tropospheric conditions J. Shen et al. 10.1038/s41586-024-08196-0
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. 10.5194/acp-24-2885-2024
15 citations as recorded by crossref.
- Characterisation of gaseous iodine species detection using the multi-scheme chemical ionisation inlet 2 with bromide and nitrate chemical ionisation methods X. He et al. 10.5194/amt-16-4461-2023
- Decomposition of Clusters of Oxygenated Compounds with NO3– by Applying Voltage Scanning to Chemical Ionization Mass Spectrometry in Steady-State Experiments H. Wang et al. 10.1021/acs.estlett.4c00276
- Temperature, humidity, and ionisation effect of iodine oxoacid nucleation B. Rörup et al. 10.1039/D4EA00013G
- Multiphysical description of atmospheric pressure interface chemical ionisation in MION2 and Eisele type inlets H. Finkenzeller et al. 10.5194/amt-17-5989-2024
- The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition M. Boyer et al. 10.5194/acp-24-12595-2024
- Data‐Driven Compound Identification in Atmospheric Mass Spectrometry H. Sandström et al. 10.1002/advs.202306235
- Iodine oxoacids and their roles in sub-3 nm particle growth in polluted urban environments Y. Zhang et al. 10.5194/acp-24-1873-2024
- 1-Hexene Ozonolysis across Atmospheric and Combustion Temperatures via Synchrotron-Based Photoelectron Spectroscopy and Chemical Ionization Mass Spectrometry C. Smith Lewin et al. 10.1021/acs.jpca.4c02687
- From Hydrocarbons to Highly Functionalized Molecules in a Single Measurement: Comprehensive Analysis of Complex Gas Mixtures by Multi-Pressure Chemical Ionization Mass Spectrometry A. Shcherbinin et al. 10.1021/acs.analchem.4c03859
- Gas‐Phase Formation of Sulfurous Acid (H2SO3) in the Atmosphere T. Berndt et al. 10.1002/anie.202405572
- Gasphasenbildung von Schwefliger Säure (H2SO3) in der Atmosphäre T. Berndt et al. 10.1002/ange.202405572
- Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al. 10.1021/acs.analchem.4c00650
- Enhanced detection of aromatic oxidation products using NO3− chemical ionization mass spectrometry with limited nitric acid O. Garmash et al. 10.1039/D4EA00087K
- New particle formation from isoprene under upper-tropospheric conditions J. Shen et al. 10.1038/s41586-024-08196-0
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. 10.5194/acp-24-2885-2024
Latest update: 13 Dec 2024
Short summary
In this study, the upgraded multi-scheme chemical ionisation inlet 2 is presented. Sulfuric acid, hypoiodous acid, iodine, sulfur dioxide, and hydroperoxyl radicals are calibrated, and the improved ion optics allow us to detect sulfuric acid and iodine-containing molecules at as low as a few parts per quadrillion by volume. Additionally, we confirm the reliable detection of iodic acid using both the nitrate and bromide chemical ionisation methods under atmospherically relevant conditions.
In this study, the upgraded multi-scheme chemical ionisation inlet 2 is presented. Sulfuric...
