Articles | Volume 17, issue 11
https://doi.org/10.5194/amt-17-3467-2024
© Author(s) 2024. This work is distributed under the Creative Commons Attribution 4.0 License.
Using a portable FTIR spectrometer to evaluate the consistency of Total Carbon Column Observing Network (TCCON) measurements on a global scale: the Collaborative Carbon Column Observing Network (COCCON) travel standard
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- Final revised paper (published on 05 Jun 2024)
- Preprint (discussion started on 02 Feb 2024)
Interactive discussion
Status: closed
Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor
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RC1: 'Comment on egusphere-2023-3089', Anonymous Referee #1, 01 Mar 2024
- AC2: 'Reply on RC1', Benedikt Herkommer, 27 Mar 2024
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RC2: 'Comment on egusphere-2023-3089', Anonymous Referee #2, 05 Mar 2024
- AC1: 'Reply on RC2', Benedikt Herkommer, 27 Mar 2024
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AR – Author's response | RR – Referee report | ED – Editor decision | EF – Editorial file upload
AR by Benedikt Herkommer on behalf of the Authors (27 Mar 2024)
Author's response
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ED: Publish as is (06 Apr 2024) by Thomas F. Hanisco
AR by Benedikt Herkommer on behalf of the Authors (08 Apr 2024)
The manuscript presents an approach to comparing CO2, CH4, and CO measurements from Total Carbon Column Observing Network (TCCON) instruments by using a travel standard EM27/SUN instrument. TCCON measurements are the reference standard for satellite measurements of total column CO2 and CH4. Consequently, having accurate measurements from TCCON is valuable to global GHG observations. Because TCCON instruments are not amenable to transport, it is not possible to move them for co-located instrument intercomparisons that would result in identification and elimination of intra-network variability in observations. This work demonstrates that more compact EM27/SUN instruments can be used as a travel standard to visit TCCON sites and perform co-located measurements, thereby tying the visited TCCON instrument back to a common reference TCCON site. The intercomparison approach presented has clear benefits and resulted in identification of issues to be addressed in instruments visited during this demonstration period. The manuscript does a good job of covering how they implement the transfer standard approach and should be published once improvements are made to the manuscript. Considerable copy editing is needed, both in terms of typos and text-figure mismatches in colors used. Comments/suggestions are below.
General Comments:
The Travel Standard is clearly a step forward in assessing the performance of TCCON instruments, and presumably a similar approach will be used for COCCON instruments. The result of the Travel Standard intercomparison is a series of correction scaling factors that ultimately relate the visited instruments back to the KIT TCCON instrument. Some questions that flow from this:
How often should Travel Standard visits be conducted?
Ultimately we need to tie all the measurements back to the WMO scale. If the KIT TCCON instrument is going to be the reference, should aircraft overflights or AirCore launches be conducted more regularly at the site to keep that instrument tightly related to the WMO scale? If, for logistical reasons, the KIT TCCON site isn’t ideal for overflights/launches, could another site be used for this purpose and the Travel Standard relate that TCCON instrument to the KIT instrument?
Specific Comments:
Consider defining Xgas early in your paper.
Line 23: Give some context to your “pressure analysis” statement here. What pressure is this? Why does it matter?
Line 49, 50: Is there a reference you could provide for the WMO trace gas scale, or the process/importance of tying measurements (in general) to that scale?
Lines 128-133: There isn’t much more info here than in the intro. Perhaps you could trim the corresponding section in the intro for brevity.
Lines 153-155: Please consider providing units for all equation terms.
Lines 165-168: Having the same name for a value and its inverse is unfortunate. Perhaps using a subscript to designate which convention is being used (GGG or PROFFAST) would provide clarity, assuming that the packages won’t settle on a common convention.
Lines 172-178: This text is largely redundant with text earlier in this section and in the intro. Consider removing for brevity.
Lines 212-216: I am not entirely clear on what you are trying to say here. Are you saying that the recorded shocks are at the very start and the very end of the recorded period, and therefore may be from rough handling of the logger when the logger wasn’t attached to the spectrometer?
Lines 218-219: This sentence isn’t necessary—consider removing for brevity.
Lines 288, 295, Fig 2 caption, and Table 1 caption: You’ve got a mismatch between colors mentioned and colors actually used in the figure. Also, since you use different symbol shapes (a good idea), it is worth mentioning them in the text in addition to the color here and in other figures.
Line 309: “It is assumed that the reference in Karlsruhe does not drift in time.” How is the validity of this assumption verified?
Lines 342-349: This correction approach effectively assumes the dependence on SZA is 100% in the Travel Standard instrument. How does the uncertainty in this assumption propagate into the calculation of absolute uncertainty of the CO measurements?
Line 353-354: Not important to this manuscript, but I was surprised that the Karlsruhe TCCON station doesn’t have its own high accuracy pressure measurement considering the importance of this measurement to TCCON data processing. What is the benefit of relying on the DWD data?
Line 434: The ‘yellow “x”-shaped markers’ are actually black triangles in the figure.
Figure 8 caption: For clarity, it is worth mentioning in the caption that the TK-LR, GGG data were only plotted for XCO.
Lines 448, 449, 464, Figure 10 and caption: The colors in the figure do not match the colors in the text.
Line 512: The WG-HR data are red in the figure, not green.
Section 7.1: I did not follow the explanation regarding the Wollongong HR/LR noise level relationship. Why does this explanation only apply to Wallongong and not the other TCCON sites?
Figure 16: Delete the last sentence in the caption—this is a given. What do the whiskers in the plots represent? Consider adding text in the caption to describe them.