We describe a method for measuring the emissivity of natural surfaces using data from the new Far-INfrarEd Spectrometer for Surface Emissivity (FINESSE) instrument. We demonstrate our method by making measurements of the emissivity of water. We then compare our results to the emissivity predicted using a model and find good agreement. The observations from FINESSE are novel because they allow us to determine surface emissivity at longer wavelengths than have been routinely measured before.