Articles | Volume 17, issue 19
https://doi.org/10.5194/amt-17-5887-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-17-5887-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Oct 2024
Research article |
| 07 Oct 2024
| 07 Oct 2024
Evaluation of a reduced-pressure chemical ion reactor utilizing adduct ionization for the detection of gaseous organic and inorganic species
Matthieu Riva
CORRESPONDING AUTHOR
TOFWERK, 3645 Thun, Switzerland
Université Claude Bernard Lyon 1, CNRS, IRCELYON 69626, Villeurbanne, France
Veronika Pospisilova
TOFWERK, 3645 Thun, Switzerland
Carla Frege
TOFWERK, 3645 Thun, Switzerland
Sebastien Perrier
Université Claude Bernard Lyon 1, CNRS, IRCELYON 69626, Villeurbanne, France
Priyanka Bansal
TOFWERK, 3645 Thun, Switzerland
Spiro Jorga
TOFWERK, 3645 Thun, Switzerland
Patrick Sturm
TOFWERK, 3645 Thun, Switzerland
Joel A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Urs Rohner
TOFWERK, 3645 Thun, Switzerland
Felipe Lopez-Hilfiker
CORRESPONDING AUTHOR
TOFWERK, 3645 Thun, Switzerland
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Cited
18 citations as recorded by crossref.
- Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer D. Kilgour et al.
- Iodine Activation from Iodate Reduction in Aqueous Films via Photocatalyzed and Dark Reactions M. Reza et al.
- Speciated measurement of bicyclic peroxy radicals via iodide-CIMS and its implication on OH-initiated aromatic oxidation Y. Liu et al.
- A point-of-need framework for illicit drug identification with high-resolution mass spectrometry T. Forbes et al.
- All-in-one: validation and versatile applications of a novel chemical ionization mass spectrometer for simultaneous measurements of volatile organic and inorganic compounds Y. Chang et al.
- Chemical ionization mass spectrometry utilizing benzene cations for measurements of volatile organic compounds and nitric oxide U. Puttu et al.
- A novel technique for the humidity dependent calibration of hypoiodous acid (HOI) and iodine (I2) L. Marden et al.
- Online Iodide Chemical Ionization Mass Spectrometry (I-CIMS) Enables Occupational Inhalation Exposure Assessment of 6:2 Fluorotelomer Alcohol (6:2 FTOH) Emitted to Air during Floor Waxing M. Davern et al.
- Volatile organic compounds in pea plants: a comprehensive review S. Avesani et al.
- Removal of trace gases can both increase and decrease cloud droplet formation E. Ravichandran et al.
- Hydroxyl Radical-Initiated Oxidation of Isoprene Leads to a Cyclic Peroxyhemiacetal via 1,6-Hydrogen Shift Chemistry That Yields Secondary Organic Aerosol R. Rice et al.
- Measurements and Modeling of GUV222-Driven Increases in SOA Concentrations in an Unoccupied Office M. Rutherford et al.
- Identifying key parameters that affect sensitivity of flow tube chemical ionization mass spectrometers S. Aggarwal et al.
- Humidity drives spontaneous OH oxidation of organic particles M. Angelaki et al.
- The determination of ClNO2 via thermal dissociation–tunable infrared laser direct absorption spectroscopy J. Halfacre et al.
- From Hydrocarbons to Highly Functionalized Molecules in a Single Measurement: Comprehensive Analysis of Complex Gas Mixtures by Multi-Pressure Chemical Ionization Mass Spectrometry A. Shcherbinin et al.
- A simple, versatile approach for coupling a liquid chromatograph and chemical ionization mass spectrometer for offline analysis of organic aerosol A. Schaum et al.
- Comparing Proton Transfer Reaction (PTR) and Adduct Ionization Mechanism (AIM) for the Study of Volatile Organic Compounds S. Avesani et al.
18 citations as recorded by crossref.
- Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer D. Kilgour et al.
- Iodine Activation from Iodate Reduction in Aqueous Films via Photocatalyzed and Dark Reactions M. Reza et al.
- Speciated measurement of bicyclic peroxy radicals via iodide-CIMS and its implication on OH-initiated aromatic oxidation Y. Liu et al.
- A point-of-need framework for illicit drug identification with high-resolution mass spectrometry T. Forbes et al.
- All-in-one: validation and versatile applications of a novel chemical ionization mass spectrometer for simultaneous measurements of volatile organic and inorganic compounds Y. Chang et al.
- Chemical ionization mass spectrometry utilizing benzene cations for measurements of volatile organic compounds and nitric oxide U. Puttu et al.
- A novel technique for the humidity dependent calibration of hypoiodous acid (HOI) and iodine (I2) L. Marden et al.
- Online Iodide Chemical Ionization Mass Spectrometry (I-CIMS) Enables Occupational Inhalation Exposure Assessment of 6:2 Fluorotelomer Alcohol (6:2 FTOH) Emitted to Air during Floor Waxing M. Davern et al.
- Volatile organic compounds in pea plants: a comprehensive review S. Avesani et al.
- Removal of trace gases can both increase and decrease cloud droplet formation E. Ravichandran et al.
- Hydroxyl Radical-Initiated Oxidation of Isoprene Leads to a Cyclic Peroxyhemiacetal via 1,6-Hydrogen Shift Chemistry That Yields Secondary Organic Aerosol R. Rice et al.
- Measurements and Modeling of GUV222-Driven Increases in SOA Concentrations in an Unoccupied Office M. Rutherford et al.
- Identifying key parameters that affect sensitivity of flow tube chemical ionization mass spectrometers S. Aggarwal et al.
- Humidity drives spontaneous OH oxidation of organic particles M. Angelaki et al.
- The determination of ClNO2 via thermal dissociation–tunable infrared laser direct absorption spectroscopy J. Halfacre et al.
- From Hydrocarbons to Highly Functionalized Molecules in a Single Measurement: Comprehensive Analysis of Complex Gas Mixtures by Multi-Pressure Chemical Ionization Mass Spectrometry A. Shcherbinin et al.
- A simple, versatile approach for coupling a liquid chromatograph and chemical ionization mass spectrometer for offline analysis of organic aerosol A. Schaum et al.
- Comparing Proton Transfer Reaction (PTR) and Adduct Ionization Mechanism (AIM) for the Study of Volatile Organic Compounds S. Avesani et al.
Saved (final revised paper)
Latest update: 10 May 2026
Short summary
We present a newly designed reduced-pressure chemical ionization reactor for detection of gas-phase organic and inorganic species. The system operates through the combined use of vacuum ultraviolet ionization and photosensitizers to generate numerous adduct ionization schemes. As a result, it offers the ability to simultaneously measure a wide variety of organic and inorganic species in terms of compound volatility and functionality, while being largely independent of changes in sample humidity.
We present a newly designed reduced-pressure chemical ionization reactor for detection of...
