Calibrating adsorptive and reactive losses of monoterpenes and sesquiterpenes in dynamic chambers using deuterated surrogates
Jianqiang Zeng,Yanli Zhang,Haofan Ran,Weihua Pang,Hao Guo,Zhaobin Mu,Wei Song,and Xinming Wang
Jianqiang Zeng
State Key Laboratory of Advanced Environmental Technology and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Advanced Environmental Technology and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
Haofan Ran
State Key Laboratory of Advanced Environmental Technology and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
Weihua Pang
State Key Laboratory of Advanced Environmental Technology and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
Hao Guo
State Key Laboratory of Advanced Environmental Technology and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Zhaobin Mu
State Key Laboratory of Advanced Environmental Technology and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Wei Song
State Key Laboratory of Advanced Environmental Technology and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
State Key Laboratory of Advanced Environmental Technology and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China
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This study revealed the existence of significant species-specific adsorptive and reactive losses of monoterpenes and sesquiterpenes in dynamic chambers. The deuterated α-pinene-d3 and β-caryophyllene-d2 were proven as effective surrogates in tracing these losses for some key monoterpenes and sesquiterpenes. The findings highlight the importance of selecting internal surrogates that closely match the adsorptive and reactive behaviors of target compounds for precise loss correction.
This study revealed the existence of significant species-specific adsorptive and reactive losses...