Articles | Volume 18, issue 16
https://doi.org/10.5194/amt-18-3945-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-18-3945-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
The coupling of a high-efficiency aerosol collector with electrospray ionisation–Orbitrap mass spectrometry as a novel tool for real-time chemical characterisation of fine and ultrafine particles
Yik-Sze Lau
International Laboratory for Air Quality and Health, School of Earth and Atmospheric Sciences, Queensland University of Technology, Brisbane, Australia
Zoran Ristovski
International Laboratory for Air Quality and Health, School of Earth and Atmospheric Sciences, Queensland University of Technology, Brisbane, Australia
Branka Miljevic
CORRESPONDING AUTHOR
International Laboratory for Air Quality and Health, School of Earth and Atmospheric Sciences, Queensland University of Technology, Brisbane, Australia
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E. Johanna Horchler, Joel Alroe, Luke Harrison, Luke Cravigan, Daniel P. Harrison, and Zoran D. Ristovski
EGUsphere, https://doi.org/10.5194/egusphere-2025-465, https://doi.org/10.5194/egusphere-2025-465, 2025
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Aerosols play a role in global climate by interacting with incoming solar radiation and by taking up water vapour from the atmosphere to form clouds. Enhancing local-scale cloud cover can reduce sea surface temperatures. Coral bleaching events increased in the Great Barrier Reef (GBR) as sea surface temperatures rise. Our study found that the number of aerosols and the cloud forming ability over the GBR increased if the aerosols were transported from inland Australia rather than the ocean.
Behnaz Alinaghipour, Sadegh Niazi, Robert Groth, Branka Miljevic, and Zoran Ristovski
Atmos. Meas. Tech., 18, 1063–1071, https://doi.org/10.5194/amt-18-1063-2025, https://doi.org/10.5194/amt-18-1063-2025, 2025
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Airborne particles are crucial in environmental and health studies, requiring precise sampling for accurate characterisation. Our study examines the optimal sampling time for the TSI Nanometer Aerosol Sampler 3089 at different input concentrations. Aerosols from low-, medium-, and high-concentration environments were sampled over 1, 3, and 6 h. A linear relationship was observed using a regression model between the deposition densities and the product of input concentration and sampling time.
Matthew Boyer, Diego Aliaga, Lauriane L. J. Quéléver, Silvia Bucci, Hélène Angot, Lubna Dada, Benjamin Heutte, Lisa Beck, Marina Duetsch, Andreas Stohl, Ivo Beck, Tiia Laurila, Nina Sarnela, Roseline C. Thakur, Branka Miljevic, Markku Kulmala, Tuukka Petäjä, Mikko Sipilä, Julia Schmale, and Tuija Jokinen
Atmos. Chem. Phys., 24, 12595–12621, https://doi.org/10.5194/acp-24-12595-2024, https://doi.org/10.5194/acp-24-12595-2024, 2024
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We analyze the seasonal cycle and sources of gases that are relevant for the formation of aerosol particles in the central Arctic. Since theses gases can form new particles, they can influence Arctic climate. We show that the sources of these gases are associated with changes in the Arctic environment during the year, especially with respect to sea ice. Therefore, the concentration of these gases will likely change in the future as the Arctic continues to warm.
Sonya L. Fiddes, Matthew T. Woodhouse, Marc D. Mallet, Liam Lamprey, Ruhi S. Humphries, Alain Protat, Simon P. Alexander, Hakase Hayashida, Samuel G. Putland, Branka Miljevic, and Robyn Schofield
EGUsphere, https://doi.org/10.5194/egusphere-2024-3125, https://doi.org/10.5194/egusphere-2024-3125, 2024
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The interaction between natural marine aerosols, clouds and radiation in the Southern Ocean is a major source of uncertainty in climate models. We evaluate the Australian climate model using aerosol observations and find it underestimates aerosol number often by over 50 %. Model changes were tested to improve aerosol concentrations, but some of our changes had severe negative effects on the larger climate system, highlighting issues in aerosol-cloud interaction modelling.
Ruhi S. Humphries, Melita D. Keywood, Jason P. Ward, James Harnwell, Simon P. Alexander, Andrew R. Klekociuk, Keiichiro Hara, Ian M. McRobert, Alain Protat, Joel Alroe, Luke T. Cravigan, Branka Miljevic, Zoran D. Ristovski, Robyn Schofield, Stephen R. Wilson, Connor J. Flynn, Gourihar R. Kulkarni, Gerald G. Mace, Greg M. McFarquhar, Scott D. Chambers, Alastair G. Williams, and Alan D. Griffiths
Atmos. Chem. Phys., 23, 3749–3777, https://doi.org/10.5194/acp-23-3749-2023, https://doi.org/10.5194/acp-23-3749-2023, 2023
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Observations of aerosols in pristine regions are rare but are vital to constraining the natural baseline from which climate simulations are calculated. Here we present recent seasonal observations of aerosols from the Southern Ocean and contrast them with measurements from Antarctica, Australia and regionally relevant voyages. Strong seasonal cycles persist, but striking differences occur at different latitudes. This study highlights the need for more long-term observations in remote regions.
Sonya L. Fiddes, Matthew T. Woodhouse, Steve Utembe, Robyn Schofield, Simon P. Alexander, Joel Alroe, Scott D. Chambers, Zhenyi Chen, Luke Cravigan, Erin Dunne, Ruhi S. Humphries, Graham Johnson, Melita D. Keywood, Todd P. Lane, Branka Miljevic, Yuko Omori, Alain Protat, Zoran Ristovski, Paul Selleck, Hilton B. Swan, Hiroshi Tanimoto, Jason P. Ward, and Alastair G. Williams
Atmos. Chem. Phys., 22, 2419–2445, https://doi.org/10.5194/acp-22-2419-2022, https://doi.org/10.5194/acp-22-2419-2022, 2022
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Coral reefs have been found to produce the climatically relevant chemical compound dimethyl sulfide (DMS). It has been suggested that corals can modify their environment via the production of DMS. We use an atmospheric chemistry model to test this theory at a regional scale for the first time. We find that it is unlikely that coral-reef-derived DMS has an influence over local climate, in part due to the proximity to terrestrial and anthropogenic aerosol sources.
Cited articles
Bates, J. T., Fang, T., Verma, V., Zeng, L., Weber, R. J., Tolbert, P. E., Abrams, J. Y., Sarnat, S. E., Klein, M., Mulholland, J. A., and Russell, A. G.: Review of acellular assays of ambient particulate matter oxidative potential: methods and relationships with composition, sources, and health effects, Environ. Sci. Technol., 53, 4003–4019, https://doi.org/10.1021/acs.est.8b03430, 2019.
Brown, R., Stevanovic, S., Brown, Z., Cai, M., Zhou, S., Song, W., Wang, X., Miljevic, B., Zhao, J., Bottle, S., and Ristovski, Z.: Application of a fluorescent probe for the online Measurement of PM-bound reactive oxygen species in chamber and ambient studies, Sensors, 19, 4564, https://doi.org/10.3390/s19204564, 2019a.
Brown, R. A., Stevanovic, S., Bottle, S., and Ristovski, Z. D.: An instrument for the rapid quantification of PM-bound ROS: the Particle Into Nitroxide Quencher (PINQ), Atmos. Meas. Tech., 12, 2387–2401, https://doi.org/10.5194/amt-12-2387-2019, 2019b.
Brown, R. A., Stevanovic, S., Bottle, S., Wang, H., Hu, Z., Wu, C., Wang, B., and Ristovski, Z.: Relationship between atmospheric PM-bound reactive oxygen species, their half-lives, and regulated pollutants: investigation and preliminary model, Environ. Sci. Technol., 54, 4995–5002, https://doi.org/10.1021/acs.est.9b06643, 2020.
Budisulistiorini, S. H., Li, X., Bairai, S. T., Renfro, J., Liu, Y., Liu, Y. J., McKinney, K. A., Martin, S. T., McNeill, V. F., Pye, H. O. T., Nenes, A., Neff, M. E., Stone, E. A., Mueller, S., Knote, C., Shaw, S. L., Zhang, Z., Gold, A., and Surratt, J. D.: Examining the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol formation during the 2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee ground site, Atmos. Chem. Phys., 15, 8871–8888, https://doi.org/10.5194/acp-15-8871-2015, 2015.
Canagaratna, M. R., Jayne, J. T., Jimenez, J. L., Allan, J. D., Alfarra, M. R., Zhang, Q., Onasch, T. B., Drewnick, F., Coe, H., Middlebrook, A., Delia, A., Williams, L. R., Trimborn, A. M., Northway, M. J., DeCarlo, P. F., Kolb, C. E., Davidovits, P., and Worsnop, D. R.: Chemical and microphysical characterization of ambient aerosols with the aerodyne aerosol mass spectrometer, Mass Spectrom. Rev., 26, 185–222, https://doi.org/10.1002/mas.20115, 2007.
Ehrmann, B. M., Henriksen, T., and Cech, N. B.: Relative importance of basicity in the gas phase and in solution for determining selectivity in electrospray ionization mass spectrometry, J. Am. Soc. Mass Spectr., 19, 719–728, https://doi.org/10.1016/j.jasms.2008.01.003, 2008.
Fan, J., Wang, Y., Rosenfeld, D., and Liu, X.: Review of aerosol–cloud interactions: mechanisms, significance, and challenges, J. Atmos. Sci., 73, 4221–4252, https://doi.org/10.1175/JAS-D-16-0037.1, 2016.
Fleming, L. T., Lin, P., Roberts, J. M., Selimovic, V., Yokelson, R., Laskin, J., Laskin, A., and Nizkorodov, S. A.: Molecular composition and photochemical lifetimes of brown carbon chromophores in biomass burning organic aerosol, Atmos. Chem. Phys., 20, 1105–1129, https://doi.org/10.5194/acp-20-1105-2020, 2020.
Furey, A., Moriarty, M., Bane, V., Kinsella, B., and Lehane, M.: Ion suppression; A critical review on causes, evaluation, prevention and applications, Talanta, 115, 104–122, https://doi.org/10.1016/j.talanta.2013.03.048, 2013.
He, L., Diedrich, J., Chu, Y.-Y., and Yates III, J. R.: Extracting accurate precursor information for tandem mass spectra by RawConverter, Anal. Chem., 87, 11361–11367, https://doi.org/10.1021/acs.analchem.5b02721, 2015.
Huang, R.-J., Zhang, Y., Bozzetti, C., Ho, K.-F., Cao, J.-J., Han, Y., Daellenbach, K. R., Slowik, J. G., Platt, S. M., Canonaco, F., Zotter, P., Wolf, R., Pieber, S. M., Bruns, E. A., Crippa, M., Ciarelli, G., Piazzalunga, A., Schwikowski, M., Abbaszade, G., Schnelle-Kreis, J., Zimmermann, R., An, Z., Szidat, S., Baltensperger, U., Haddad, I. E., and Prévôt, A. S. H.: High secondary aerosol contribution to particulate pollution during haze events in China, Nature, 514, 218–222, https://doi.org/10.1038/nature13774, 2014.
Jimenez, J. L., Canagaratna, M. R., Donahue, N. M., Prevot, A. S. H., Zhang, Q., Kroll, J. H., DeCarlo, P. F., Allan, J. D., Coe, H., Ng, N. L., Aiken, A. C., Docherty, K. S., Ulbrich, I. M., Grieshop, A. P., Robinson, A. L., Duplissy, J., Smith, J. D., Wilson, K. R., Lanz, V. A., Hueglin, C., Sun, Y. L., Tian, J., Laaksonen, A., Raatikainen, T., Rautiainen, J., Vaattovaara, P., Ehn, M., Kulmala, M., Tomlinson, J. M., Collins, D. R., Cubison, M. J., Dunlea, J., Huffman, J. A., Onasch, T. B., Alfarra, M. R., Williams, P. I., Bower, K., Kondo, Y., Schneider, J., Drewnick, F., Borrmann, S., Weimer, S., Demerjian, K., Salcedo, D., Cottrell, L., Griffin, R., Takami, A., Miyoshi, T., Hatakeyama, S., Shimono, A., Sun, J. Y., Zhang, Y. M., Dzepina, K., Kimmel, J. R., Sueper, D., Jayne, J. T., Herndon, S. C., Trimborn, A. M., Williams, L. R., Wood, E. C., Middlebrook, A. M., Kolb, C. E., Baltensperger, U., and Worsnop, D. R.: Evolution of organic aerosols in the atmosphere, Science, 326, 1525, https://doi.org/10.1126/science.1180353, 2009.
Kamel, A. M., Brown, P. R., and Munson, B.: Effects of mobile-phase additives, solution pH, ionization constant, and analyte concentration on the sensitivities and electrospray ionization mass spectra of nucleoside antiviral agents, Anal. Chem., 71, 5481–5492, https://doi.org/10.1021/ac9906429, 1999.
Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, Atmos. Chem. Phys., 5, 1053–1123, https://doi.org/10.5194/acp-5-1053-2005, 2005.
Kautzman, K. E., Surratt, J. D., Chan, M. N., Chan, A. W. H., Hersey, S. P., Chhabra, P. S., Dalleska, N. F., Wennberg, P. O., Flagan, R. C., and Seinfeld, J. H.: Chemical composition of gas- and aerosol-phase products from the photooxidation of naphthalene, J. Phys. Chem. A, 114, 913–934, https://doi.org/10.1021/jp908530s, 2010.
Kirchstetter, T. W., Corrigan, C. E., and Novakov, T.: Laboratory and field investigation of the adsorption of gaseous organic compounds onto quartz filters, Atmos. Environ., 35, 1663–1671, https://doi.org/10.1016/S1352-2310(00)00448-9, 2001.
Krechmer, J. E., Groessl, M., Zhang, X., Junninen, H., Massoli, P., Lambe, A. T., Kimmel, J. R., Cubison, M. J., Graf, S., Lin, Y.-H., Budisulistiorini, S. H., Zhang, H., Surratt, J. D., Knochenmuss, R., Jayne, J. T., Worsnop, D. R., Jimenez, J.-L., and Canagaratna, M. R.: Ion mobility spectrometry–mass spectrometry (IMS–MS) for on- and offline analysis of atmospheric gas and aerosol species, Atmos. Meas. Tech., 9, 3245–3262, https://doi.org/10.5194/amt-9-3245-2016, 2016.
Kulkarni, P., Baron, P. A., and Willeke, K.: Aerosol measurement: principles, techniques, and applications, 3rd edn., John Wiley and Sons, Incorporated, https://doi.org/10.1002/9781118001684, 2011.
Kwon, H.-S., Ryu, M. H., and Carlsten, C.: Ultrafine particles: unique physicochemical properties relevant to health and disease, Exp. Mol. Med., 52, 318–328, https://doi.org/10.1038/s12276-020-0405-1, 2020.
Lopez-Hilfiker, F. D., Pospisilova, V., Huang, W., Kalberer, M., Mohr, C., Stefenelli, G., Thornton, J. A., Baltensperger, U., Prevot, A. S. H., and Slowik, J. G.: An extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF) for online measurement of atmospheric aerosol particles, Atmos. Meas. Tech., 12, 4867–4886, https://doi.org/10.5194/amt-12-4867-2019, 2019.
Mahowald, N., Ward, D. S., Kloster, S., Flanner, M. G., Heald, C. L., Heavens, N. G., Hess, P. G., Lamarque, J.-F., and Chuang, P. Y.: Aerosol impacts on climate and biogeochemistry, Annu. Rev. Env. Resour., 36, 45–74, https://doi.org/10.1146/annurev-environ-042009-094507, 2011.
McNeill, V. F.: Atmospheric aerosols: clouds, chemistry, and climate, Annu. Rev. Chem. Biomol., 8, 427–444, https://doi.org/10.1146/annurev-chembioeng-060816-101538, 2017.
Miljevic, B., Hedayat, F., Stevanovic, S., Fairfull-Smith, K. E., Bottle, S. E., and Ristovski, Z. D.: To sonicate or not to Sonicate PM filters: reactive oxygen species generation upon ultrasonic irradiation, Aerosol Sci. Tech., 48, 1276–1284, https://doi.org/10.1080/02786826.2014.981330, 2014.
Molteni, U., Simon, M., Heinritzi, M., Hoyle, C. R., Bernhammer, A.-K., Bianchi, F., Breitenlechner, M., Brilke, S., Dias, A., Duplissy, J., Frege, C., Gordon, H., Heyn, C., Jokinen, T., Kürten, A., Lehtipalo, K., Makhmutov, V., Petäjä, T., Pieber, S. M., Praplan, A. P., Schobesberger, S., Steiner, G., Stozhkov, Y., Tomé, A., Tröstl, J., Wagner, A. C., Wagner, R., Williamson, C., Yan, C., Baltensperger, U., Curtius, J., Donahue, N. M., Hansel, A., Kirkby, J., Kulmala, M., Worsnop, D. R., and Dommen, J.: Formation of highly oxygenated organic molecules from α-pinene ozonolysis: chemical characteristics, mechanism, and kinetic model development, ACS Earth Space Chem., 3, 873–883, https://doi.org/10.1021/acsearthspacechem.9b00035, 2019.
Myers, O. D., Sumner, S. J., Li, S., Barnes, S., and Du, X.: One step forward for reducing false positive and false negative compound identifications from mass spectrometry metabolomics data: new algorithms for constructing extracted ion chromatograms and detecting chromatographic peaks, Anal. Chem., 89, 8696–8703, https://doi.org/10.1021/acs.analchem.7b00947, 2017.
Orsini, D. A., Rhoads, K., McElhoney, K., Schick, E., Koehler, D., and Hogrefe, O.: A water cyclone to preserve insoluble aerosols in liquid flow – an interface to flow cytometry to detect airborne nucleic acid, Aerosol Sci. Tech., 42, 343–356, https://doi.org/10.1080/02786820802072881, 2008.
Oss, M., Kruve, A., Herodes, K., and Leito, I.: Electrospray ionization efficiency scale of organic compounds, Anal. Chem., 82, 2865–2872, https://doi.org/10.1021/ac902856t, 2010.
Parshintsev, J. and Hyötyläinen, T.: Methods for characterization of organic compounds in atmospheric aerosol particles, Anal. Bioanal. Chem., 407, 5877–5897, https://doi.org/10.1007/s00216-014-8394-3, 2015.
Parshintsev, J., Kivilompolo, M., Ruiz-Jimenez, J., Hartonen, K., Kulmala, M., and Riekkola, M.-L.: Particle-into-liquid sampler on-line coupled with solid-phase extraction-liquid chromatography–mass spectrometry for the determination of organic acids in atmospheric aerosols, J. Chromatogr. A, 1217, 5427–5433, https://doi.org/10.1016/j.chroma.2010.06.026, 2010.
Piel, F., Müller, M., Mikoviny, T., Pusede, S. E., and Wisthaler, A.: Airborne measurements of particulate organic matter by proton-transfer-reaction mass spectrometry (PTR-MS): a pilot study, Atmos. Meas. Tech., 12, 5947–5958, https://doi.org/10.5194/amt-12-5947-2019, 2019.
Pluskal, T., Castillo, S., Villar-Briones, A., and Orešič, M.: MZmine 2: Modular framework for processing, visualizing, and analyzing mass spectrometry-based molecular profile data, BMC Bioinformatics, 11, 395, https://doi.org/10.1186/1471-2105-11-395, 2010.
Pöschl, U.: Atmospheric aerosols: composition, transformation, climate and health effects, Angew. Chem. Int. Edit., 44, 7520–7540, https://doi.org/10.1002/anie.200501122, 2005.
R Development Core Team: R: A language and environment for statistical computing, R foundation for statistical computing [code], https://www.R-project.org/ (last access: 19 August 2025), 2023.
Quinn, P. K., Collins, D. B., Grassian, V. H., Prather, K. A., and Bates, T. S.: Chemistry and related properties of freshly emitted sea spray aerosol, Chem. Rev., 115, 4383–4399, https://doi.org/10.1021/cr500713g, 2015.
Saarnio, K., Teinilä, K., Saarikoski, S., Carbone, S., Gilardoni, S., Timonen, H., Aurela, M., and Hillamo, R.: Online determination of levoglucosan in ambient aerosols with particle-into-liquid sampler–high-performance anion-exchange chromatography–mass spectrometry (PILS–HPAEC–MS), Atmos. Meas. Tech., 6, 2839–2849, https://doi.org/10.5194/amt-6-2839-2013, 2013.
Schmid, R., Heuckeroth, S., Korf, A., Smirnov, A., Myers, O., Dyrlund, T. S., Bushuiev, R., Murray, K. J., Hoffmann, N., Lu, M., Sarvepalli, A., Zhang, Z., Fleischauer, M., Dührkop, K., Wesner, M., Hoogstra, S. J., Rudt, E., Mokshyna, O., Brungs, C., Ponomarov, K., Mutabdžija, L., Damiani, T., Pudney, C. J., Earll, M., Helmer, P. O., Fallon, T. R., Schulze, T., Rivas-Ubach, A., Bilbao, A., Richter, H., Nothias, L.-F., Wang, M., Orešič, M., Weng, J.-K., Böcker, S., Jeibmann, A., Hayen, H., Karst, U., Dorrestein, P. C., Petras, D., Du, X., and Pluskal, T.: Integrative analysis of multimodal mass spectrometry data in MZmine 3, Nat. Biotechnol., 41, 447–449, https://doi.org/10.1038/s41587-023-01690-2, 2023.
Shilling, J. E., Chen, Q., King, S. M., Rosenoern, T., Kroll, J. H., Worsnop, D. R., DeCarlo, P. F., Aiken, A. C., Sueper, D., Jimenez, J. L., and Martin, S. T.: Loading-dependent elemental composition of α-pinene SOA particles, Atmos. Chem. Phys., 9, 771–782, https://doi.org/10.5194/acp-9-771-2009, 2009.
Shiraiwa, M., Ueda, K., Pozzer, A., Lammel, G., Kampf, C. J., Fushimi, A., Enami, S., Arangio, A. M., Fröhlich-Nowoisky, J., Fujitani, Y., Furuyama, A., Lakey, P. S. J., Lelieveld, J., Lucas, K., Morino, Y., Pöschl, U., Takahama, S., Takami, A., Tong, H., Weber, B., Yoshino, A., and Sato, K.: Aerosol health effects from molecular to global scales, Environ. Sci. Technol., 51, 13545–13567, https://doi.org/10.1021/acs.est.7b04417, 2017.
Shrivastava, M., Cappa, C. D., Fan, J., Goldstein, A. H., Guenther, A. B., Jimenez, J. L., Kuang, C., Laskin, A., Martin, S. T., Ng, N. L., Petaja, T., Pierce, J. R., Rasch, P. J., Roldin, P., Seinfeld, J. H., Shilling, J., Smith, J. N., Thornton, J. A., Volkamer, R., Wang, J., Worsnop, D. R., Zaveri, R. A., Zelenyuk, A., and Zhang, Q.: Recent advances in understanding secondary organic aerosol: Implications for global climate forcing, Rev. Geophys., 55, 509–559, https://doi.org/10.1002/2016rg000540, 2017.
Smith, C. A., Want, E. J., O'Maille, G., Abagyan, R., and Siuzdak, G.: XCMS: Processing Mass Spectrometry Data for Metabolite Profiling Using Nonlinear Peak Alignment, Matching, and Identification, Anal. Chem., 78, 779–787, https://doi.org/10.1021/ac051437y, 2006.
Stockwell, C. E., Kupc, A., Witkowski, B., Talukdar, R. K., Liu, Y., Selimovic, V., Zarzana, K. J., Sekimoto, K., Warneke, C., Washenfelder, R. A., Yokelson, R. J., Middlebrook, A. M., and Roberts, J. M.: Characterization of a catalyst-based conversion technique to measure total particulate nitrogen and organic carbon and comparison to a particle mass measurement instrument, Atmos. Meas. Tech., 11, 2749–2768, https://doi.org/10.5194/amt-11-2749-2018, 2018.
Sun, Y., Du, W., Fu, P., Wang, Q., Li, J., Ge, X., Zhang, Q., Zhu, C., Ren, L., Xu, W., Zhao, J., Han, T., Worsnop, D. R., and Wang, Z.: Primary and secondary aerosols in Beijing in winter: sources, variations and processes, Atmos. Chem. Phys., 16, 8309–8329, https://doi.org/10.5194/acp-16-8309-2016, 2016.
Tao, J., Zhang, L., Cao, J., and Zhang, R.: A review of current knowledge concerning PM2.5 chemical composition, aerosol optical properties and their relationships across China, Atmos. Chem. Phys., 17, 9485–9518, https://doi.org/10.5194/acp-17-9485-2017, 2017.
Vermeesch, P.: IsoplotR: A free and open toolbox for geochronology, Geosci. Front., 9, 1479–1493, https://doi.org/10.1016/j.gsf.2018.04.001, 2018.
Wang, Y., Zhao, Y., Li, Z., Li, C., Yan, N., and Xiao, H.: Importance of hydroxyl radical chemistry in isoprene suppression of particle formation from α-pinene ozonolysis, ACS Earth Space Chem., 5, 487–499, https://doi.org/10.1021/acsearthspacechem.0c00294, 2021.
Wickham, H.: Data Analysis, in: ggplot2: Elegant Graphics for Data Analysis, edited by: Wickham, H., Springer International Publishing, Cham, 189–201, https://doi.org/10.1007/978-3-319-24277-4_9, 2016.
Yang, Y., Kong, W., and Cai, X.: Solvent-free preparation and performance of novel xylitol based solid-solid phase change materials for thermal energy storage, Energ. Buildings, 158, 37–42, https://doi.org/10.1016/j.enbuild.2017.09.096, 2018.
York, D., Evensen, N. M., Martı́nez, M. L., and De Basabe Delgado, J.: Unified equations for the slope, intercept, and standard errors of the best straight line, Am. J. Phys., 72, 367–375, https://doi.org/10.1119/1.1632486, 2004.
Zhang, X., Dalleska, N. F., Huang, D. D., Bates, K. H., Sorooshian, A., Flagan, R. C., and Seinfeld, J. H.: Time-resolved molecular characterization of organic aerosols by PILS + UPLC/ESI-Q-TOFMS, Atmos. Environ., 130, 180–189, https://doi.org/10.1016/j.atmosenv.2015.08.049, 2016.
Zhang, X., Lambe, A. T., Upshur, M. A., Brooks, W. A., Gray Bé, A., Thomson, R. J., Geiger, F. M., Surratt, J. D., Zhang, Z., Gold, A., Graf, S., Cubison, M. J., Groessl, M., Jayne, J. T., Worsnop, D. R., and Canagaratna, M. R.: Highly oxygenated multifunctional compounds in α-pinene secondary organic aerosol, Environ. Sci. Technol., 51, 5932–5940, https://doi.org/10.1021/acs.est.6b06588, 2017.
Zhou, W., Shuang, Y., and and Wang, P. G.: Matrix effects and application of matrix effect factor, Bioanalysis, 9, 1839–1844, https://doi.org/10.4155/bio-2017-0214, 2017.
Zubarev, R. A. and Makarov, A.: Orbitrap mass spectrometry, Anal. Chem., 85, 5288–5296, https://doi.org/10.1021/ac4001223, 2013.
Short summary
The chemical properties of aerosols in the atmosphere significantly influence their impact on global climate and human health. The current study constructed an instrumental system (HEAC (high-efficiency aerosol collector)/ESI (electrospray ionisation)-Orbitrap-MS (mass spectrometer)) for the real-time chemical analysis of aerosol samples. The combined system successfully identified over 30 chemical compounds in aerosol samples in real time, showing the robustness of the technique for the chemical characterisation of aerosols under atmospherically relevant conditions.
The chemical properties of aerosols in the atmosphere significantly influence their impact on...