Articles | Volume 4, issue 12
https://doi.org/10.5194/amt-4-2607-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-4-2607-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Simultaneous stable isotope analysis of methane and nitrous oxide on ice core samples
C. J. Sapart
Institute for Marine and Atmospheric research Utrecht, Utrecht Univ., Princetonplein 5, 3584CC Utrecht, The Netherlands
C. van der Veen
Institute for Marine and Atmospheric research Utrecht, Utrecht Univ., Princetonplein 5, 3584CC Utrecht, The Netherlands
I. Vigano
Institute for Marine and Atmospheric research Utrecht, Utrecht Univ., Princetonplein 5, 3584CC Utrecht, The Netherlands
M. Brass,
Institute for Marine and Atmospheric research Utrecht, Utrecht Univ., Princetonplein 5, 3584CC Utrecht, The Netherlands
R. S. W. van de Wal
Institute for Marine and Atmospheric research Utrecht, Utrecht Univ., Princetonplein 5, 3584CC Utrecht, The Netherlands
M. Bock
Climate and Environmental Physics, Physics Institute and Oeschger Centre for Climate Change Research, Univ. of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
H. Fischer
Climate and Environmental Physics, Physics Institute and Oeschger Centre for Climate Change Research, Univ. of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
T. Sowers
Earth and Environmental Systems Institute, Geoscience, 237 Deike Building, Pennsylvania State Univ., University Park, PA 16802, USA
C. Buizert
Center for Ice and Climate, Niels Bohr Institute, Univ. of Copenhagen, Juliane Maries Vej 30, 2100 Copenhagen, Denmark
P. Sperlich
Center for Ice and Climate, Niels Bohr Institute, Univ. of Copenhagen, Juliane Maries Vej 30, 2100 Copenhagen, Denmark
T. Blunier
Center for Ice and Climate, Niels Bohr Institute, Univ. of Copenhagen, Juliane Maries Vej 30, 2100 Copenhagen, Denmark
M. Behrens
Alfred Wegener Institute for Polar and Marine Research, Am Handelshafen 12, 27570 Bremerhaven, Germany
J. Schmitt
Climate and Environmental Physics, Physics Institute and Oeschger Centre for Climate Change Research, Univ. of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
B. Seth
Climate and Environmental Physics, Physics Institute and Oeschger Centre for Climate Change Research, Univ. of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
T. Röckmann
Institute for Marine and Atmospheric research Utrecht, Utrecht Univ., Princetonplein 5, 3584CC Utrecht, The Netherlands
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Cited
35 citations as recorded by crossref.
- Recent, deep-sourced methane/mud discharge at the most active mud volcano in the western Mediterranean C. López-Rodríguez et al. 10.1016/j.margeo.2018.11.013
- Sources and sinks of methane in sea ice C. Jacques et al. 10.1525/elementa.2020.00167
- Methane in shallow subsurface sediments at the landward limit of the gas hydrate stability zone offshore western Svalbard C. Graves et al. 10.1016/j.gca.2016.11.015
- Online technique for isotope and mixing ratios of CH<sub>4</sub>, N<sub>2</sub>O, Xe and mixing ratios of organic trace gases on a single ice core sample J. Schmitt et al. 10.5194/amt-7-2645-2014
- N<sub>2</sub>O changes from the Last Glacial Maximum to the preindustrial – Part 1: Quantitative reconstruction of terrestrial and marine emissions using N<sub>2</sub>O stable isotopes in ice cores H. Fischer et al. 10.5194/bg-16-3997-2019
- An automated GC-C-GC-IRMS setup to measure palaeoatmospheric δ<sup>13</sup>C-CH<sub>4</sub>, δ<sup>15</sup>N-N<sub>2</sub>O and δ<sup>18</sup>O-N<sub>2</sub>O in one ice core sample P. Sperlich et al. 10.5194/amt-6-2027-2013
- Iron-Mediated Anaerobic Oxidation of Methane in Brackish Coastal Sediments M. Egger et al. 10.1021/es503663z
- Rapid Sediment Accumulation Results in High Methane Effluxes from Coastal Sediments M. Egger et al. 10.1371/journal.pone.0161609
- Assessment of diffusive isotopic fractionation in polar firn, and application to ice core trace gas records C. Buizert et al. 10.1016/j.epsl.2012.11.039
- Fully automated, high‐throughput instrumentation for measuring the δ13C value of methane and application of the instrumentation to rice paddy samples T. Tokida et al. 10.1002/rcm.7016
- High-precision dual-inlet IRMS measurements of the stable isotopes of CO<sub>2</sub> and the N<sub>2</sub>O / CO<sub>2</sub> ratio from polar ice core samples T. Bauska et al. 10.5194/amt-7-3825-2014
- Iron oxide reduction in methane-rich deep Baltic Sea sediments M. Egger et al. 10.1016/j.gca.2017.03.019
- Pathways of methane removal in the sediment and water column of a seasonally anoxic eutrophic marine basin O. Żygadłowska et al. 10.3389/fmars.2023.1085728
- Improving accuracy and precision of ice core δD(CH<sub>4</sub>) analyses using methane pre-pyrolysis and hydrogen post-pyrolysis trapping and subsequent chromatographic separation M. Bock et al. 10.5194/amt-7-1999-2014
- Isotopic constraints on marine and terrestrial N2O emissions during the last deglaciation A. Schilt et al. 10.1038/nature13971
- Automated simultaneous measurement of the δ13C and δ2H values of methane and the δ13C and δ18O values of carbon dioxide in flask air samples using a new multi cryo‐trap/gas chromatography/isotope ratio mass spectrometry system W. Brand et al. 10.1002/rcm.7587
- A combustion setup to precisely reference δ<sup>13</sup>C and δ<sup>2</sup>H isotope ratios of pure CH<sub>4</sub> to produce isotope reference gases of δ<sup>13</sup>C-CH<sub>4</sub> in synthetic air P. Sperlich et al. 10.5194/amt-5-2227-2012
- Natural and anthropogenic variations in methane sources during the past two millennia C. Sapart et al. 10.1038/nature11461
- Constraining N<sub>2</sub>O emissions since 1940 using firn air isotope measurements in both hemispheres M. Prokopiou et al. 10.5194/acp-17-4539-2017
- In situ observations of the isotopic composition of methane at the Cabauw tall tower site T. Röckmann et al. 10.5194/acp-16-10469-2016
- The origin of methane in the East Siberian Arctic Shelf unraveled with triple isotope analysis C. Sapart et al. 10.5194/bg-14-2283-2017
- Carbon Emissions From the Edge of the Greenland Ice Sheet Reveal Subglacial Processes of Methane and Carbon Dioxide Turnover J. Christiansen et al. 10.1029/2021JG006308
- Eutrophication and Deoxygenation Drive High Methane Emissions from a Brackish Coastal System O. Żygadłowska et al. 10.1021/acs.est.4c00702
- Anaerobic oxidation of methane alters sediment records of sulfur, iron and phosphorus in the Black Sea M. Egger et al. 10.5194/bg-13-5333-2016
- Changes in the Isotopic Signature of Atmospheric Nitrous Oxide and Its Global Average Source During the Last Three Millennia M. Prokopiou et al. 10.1029/2018JD029008
- Ebullition drives high methane emissions from a eutrophic coastal basin O. Żygadłowska et al. 10.1016/j.gca.2024.08.028
- Carbon isotope ratios suggest no additional methane from boreal wetlands during the rapid Greenland Interstadial 21.2 P. Sperlich et al. 10.1002/2014GB005007
- Carbon and Hydrogen Isotope Signatures of Dissolved Methane in the Scheldt Estuary C. Jacques et al. 10.1007/s12237-020-00768-3
- Interlaboratory comparison of <i>δ</i><sup>13</sup>C and <i>δ</i>D measurements of atmospheric CH<sub>4</sub> for combined use of data sets from different laboratories T. Umezawa et al. 10.5194/amt-11-1207-2018
- Excess methane in Greenland ice cores associated with high dust concentrations J. Lee et al. 10.1016/j.gca.2019.11.020
- Validation of methane measurement using headspace‐GC–MS and quantification by a stable isotope‐labeled internal standard generated in situ V. Varlet et al. 10.1002/jssc.201300080
- On the interference of Kr during carbon isotope analysis of methane using continuous-flow combustion–isotope ratio mass spectrometry J. Schmitt et al. 10.5194/amt-6-1425-2013
- Fractionation of Methane Isotopologues during Preparation for Analysis from Ambient Air E. Safi et al. 10.1021/acs.analchem.3c04891
- Development and evaluation of a suite of isotope reference gases for methane in air P. Sperlich et al. 10.5194/amt-9-3717-2016
- Can the carbon isotopic composition of methane be reconstructed from multi-site firn air measurements? C. Sapart et al. 10.5194/acp-13-6993-2013
35 citations as recorded by crossref.
- Recent, deep-sourced methane/mud discharge at the most active mud volcano in the western Mediterranean C. López-Rodríguez et al. 10.1016/j.margeo.2018.11.013
- Sources and sinks of methane in sea ice C. Jacques et al. 10.1525/elementa.2020.00167
- Methane in shallow subsurface sediments at the landward limit of the gas hydrate stability zone offshore western Svalbard C. Graves et al. 10.1016/j.gca.2016.11.015
- Online technique for isotope and mixing ratios of CH<sub>4</sub>, N<sub>2</sub>O, Xe and mixing ratios of organic trace gases on a single ice core sample J. Schmitt et al. 10.5194/amt-7-2645-2014
- N<sub>2</sub>O changes from the Last Glacial Maximum to the preindustrial – Part 1: Quantitative reconstruction of terrestrial and marine emissions using N<sub>2</sub>O stable isotopes in ice cores H. Fischer et al. 10.5194/bg-16-3997-2019
- An automated GC-C-GC-IRMS setup to measure palaeoatmospheric δ<sup>13</sup>C-CH<sub>4</sub>, δ<sup>15</sup>N-N<sub>2</sub>O and δ<sup>18</sup>O-N<sub>2</sub>O in one ice core sample P. Sperlich et al. 10.5194/amt-6-2027-2013
- Iron-Mediated Anaerobic Oxidation of Methane in Brackish Coastal Sediments M. Egger et al. 10.1021/es503663z
- Rapid Sediment Accumulation Results in High Methane Effluxes from Coastal Sediments M. Egger et al. 10.1371/journal.pone.0161609
- Assessment of diffusive isotopic fractionation in polar firn, and application to ice core trace gas records C. Buizert et al. 10.1016/j.epsl.2012.11.039
- Fully automated, high‐throughput instrumentation for measuring the δ13C value of methane and application of the instrumentation to rice paddy samples T. Tokida et al. 10.1002/rcm.7016
- High-precision dual-inlet IRMS measurements of the stable isotopes of CO<sub>2</sub> and the N<sub>2</sub>O / CO<sub>2</sub> ratio from polar ice core samples T. Bauska et al. 10.5194/amt-7-3825-2014
- Iron oxide reduction in methane-rich deep Baltic Sea sediments M. Egger et al. 10.1016/j.gca.2017.03.019
- Pathways of methane removal in the sediment and water column of a seasonally anoxic eutrophic marine basin O. Żygadłowska et al. 10.3389/fmars.2023.1085728
- Improving accuracy and precision of ice core δD(CH<sub>4</sub>) analyses using methane pre-pyrolysis and hydrogen post-pyrolysis trapping and subsequent chromatographic separation M. Bock et al. 10.5194/amt-7-1999-2014
- Isotopic constraints on marine and terrestrial N2O emissions during the last deglaciation A. Schilt et al. 10.1038/nature13971
- Automated simultaneous measurement of the δ13C and δ2H values of methane and the δ13C and δ18O values of carbon dioxide in flask air samples using a new multi cryo‐trap/gas chromatography/isotope ratio mass spectrometry system W. Brand et al. 10.1002/rcm.7587
- A combustion setup to precisely reference δ<sup>13</sup>C and δ<sup>2</sup>H isotope ratios of pure CH<sub>4</sub> to produce isotope reference gases of δ<sup>13</sup>C-CH<sub>4</sub> in synthetic air P. Sperlich et al. 10.5194/amt-5-2227-2012
- Natural and anthropogenic variations in methane sources during the past two millennia C. Sapart et al. 10.1038/nature11461
- Constraining N<sub>2</sub>O emissions since 1940 using firn air isotope measurements in both hemispheres M. Prokopiou et al. 10.5194/acp-17-4539-2017
- In situ observations of the isotopic composition of methane at the Cabauw tall tower site T. Röckmann et al. 10.5194/acp-16-10469-2016
- The origin of methane in the East Siberian Arctic Shelf unraveled with triple isotope analysis C. Sapart et al. 10.5194/bg-14-2283-2017
- Carbon Emissions From the Edge of the Greenland Ice Sheet Reveal Subglacial Processes of Methane and Carbon Dioxide Turnover J. Christiansen et al. 10.1029/2021JG006308
- Eutrophication and Deoxygenation Drive High Methane Emissions from a Brackish Coastal System O. Żygadłowska et al. 10.1021/acs.est.4c00702
- Anaerobic oxidation of methane alters sediment records of sulfur, iron and phosphorus in the Black Sea M. Egger et al. 10.5194/bg-13-5333-2016
- Changes in the Isotopic Signature of Atmospheric Nitrous Oxide and Its Global Average Source During the Last Three Millennia M. Prokopiou et al. 10.1029/2018JD029008
- Ebullition drives high methane emissions from a eutrophic coastal basin O. Żygadłowska et al. 10.1016/j.gca.2024.08.028
- Carbon isotope ratios suggest no additional methane from boreal wetlands during the rapid Greenland Interstadial 21.2 P. Sperlich et al. 10.1002/2014GB005007
- Carbon and Hydrogen Isotope Signatures of Dissolved Methane in the Scheldt Estuary C. Jacques et al. 10.1007/s12237-020-00768-3
- Interlaboratory comparison of <i>δ</i><sup>13</sup>C and <i>δ</i>D measurements of atmospheric CH<sub>4</sub> for combined use of data sets from different laboratories T. Umezawa et al. 10.5194/amt-11-1207-2018
- Excess methane in Greenland ice cores associated with high dust concentrations J. Lee et al. 10.1016/j.gca.2019.11.020
- Validation of methane measurement using headspace‐GC–MS and quantification by a stable isotope‐labeled internal standard generated in situ V. Varlet et al. 10.1002/jssc.201300080
- On the interference of Kr during carbon isotope analysis of methane using continuous-flow combustion–isotope ratio mass spectrometry J. Schmitt et al. 10.5194/amt-6-1425-2013
- Fractionation of Methane Isotopologues during Preparation for Analysis from Ambient Air E. Safi et al. 10.1021/acs.analchem.3c04891
- Development and evaluation of a suite of isotope reference gases for methane in air P. Sperlich et al. 10.5194/amt-9-3717-2016
- Can the carbon isotopic composition of methane be reconstructed from multi-site firn air measurements? C. Sapart et al. 10.5194/acp-13-6993-2013
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