Articles | Volume 5, issue 12
https://doi.org/10.5194/amt-5-3029-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-5-3029-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Airborne observations of formic acid using a chemical ionization mass spectrometer
M. Le Breton
Centre for Atmospheric Science, School of Earth, Atmospheric and Environmental Science, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
M. R. McGillen
Centre for Atmospheric Science, School of Earth, Atmospheric and Environmental Science, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
currently at: Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration (NOAA), 325 Broadway, Boulder, CO 80305, USA
J. B. A. Muller
Centre for Atmospheric Science, School of Earth, Atmospheric and Environmental Science, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
A. Bacak
Centre for Atmospheric Science, School of Earth, Atmospheric and Environmental Science, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
D. E. Shallcross
Biogeochemistry Research Centre, School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK
P. Xiao
Biogeochemistry Research Centre, School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK
L. G. Huey
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, Georgia, USA
D. Tanner
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, Georgia, USA
H. Coe
Centre for Atmospheric Science, School of Earth, Atmospheric and Environmental Science, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
C. J. Percival
Centre for Atmospheric Science, School of Earth, Atmospheric and Environmental Science, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
Viewed
Total article views: 13,130 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 01 Feb 2013, article published on 14 Sep 2011)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
2,273 | 10,618 | 239 | 13,130 | 188 | 156 |
- HTML: 2,273
- PDF: 10,618
- XML: 239
- Total: 13,130
- BibTeX: 188
- EndNote: 156
Total article views: 11,770 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 01 Feb 2013, article published on 07 Dec 2012)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
1,928 | 9,655 | 187 | 11,770 | 158 | 143 |
- HTML: 1,928
- PDF: 9,655
- XML: 187
- Total: 11,770
- BibTeX: 158
- EndNote: 143
Total article views: 1,360 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 01 Feb 2013, article published on 14 Sep 2011)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
345 | 963 | 52 | 1,360 | 30 | 13 |
- HTML: 345
- PDF: 963
- XML: 52
- Total: 1,360
- BibTeX: 30
- EndNote: 13
Cited
52 citations as recorded by crossref.
- Online measurements of water-soluble organic acids in the gas and aerosol phase from the photooxidation of 1,3,5-trimethylbenzene A. Praplan et al. 10.5194/acp-14-8665-2014
- Comparison of negative-ion proton-transfer with iodide ion chemical ionization mass spectrometry for quantification of isocyanic acid in ambient air R. Woodward-Massey et al. 10.1016/j.atmosenv.2014.09.014
- Enhanced ozone loss by active inorganic bromine chemistry in the tropical troposphere M. Le Breton et al. 10.1016/j.atmosenv.2017.02.003
- Tropospheric Emission Spectrometer (TES) satellite observations of ammonia, methanol, formic acid, and carbon monoxide over the Canadian oil sands: validation and model evaluation M. Shephard et al. 10.5194/amt-8-5189-2015
- Observations of Isocyanate, Amide, Nitrate, and Nitro Compounds From an Anthropogenic Biomass Burning Event Using a ToF‐CIMS M. Priestley et al. 10.1002/2017JD027316
- A low-activity ion source for measurement of atmospheric gases by chemical ionization mass spectrometry Y. Lee et al. 10.5194/amt-13-2473-2020
- An aircraft gas chromatograph–mass spectrometer System for Organic Fast Identification Analysis (SOFIA): design, performance and a case study of Asian monsoon pollution outflow E. Bourtsoukidis et al. 10.5194/amt-10-5089-2017
- Coordinated Airborne Studies in the Tropics (CAST) N. Harris et al. 10.1175/BAMS-D-14-00290.1
- Derivation of Hydroperoxyl Radical Levels at an Urban Site via Measurement of Pernitric Acid by Iodide Chemical Ionization Mass Spectrometry D. Chen et al. 10.1021/acs.est.6b05169
- A potential source of atmospheric sulfate from O<sub>2</sub><sup>−</sup>-induced SO<sub>2</sub> oxidation by ozone N. Tsona & L. Du 10.5194/acp-19-649-2019
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- High-resolution chemical ionization mass spectrometry (ToF-CIMS): application to study SOA composition and processing D. Aljawhary et al. 10.5194/amt-6-3211-2013
- Aromatic Photo-oxidation, A New Source of Atmospheric Acidity S. Wang et al. 10.1021/acs.est.0c00526
- A dopant-assisted iodide-adduct chemical ionization time-of-flight mass spectrometer based on VUV lamp photoionization for atmospheric low-molecular-weight organic acids analysis Y. Zhang et al. 10.1016/j.jes.2024.01.008
- WRF-Chem model predictions of the regional impacts of N<sub>2</sub>O<sub>5</sub> heterogeneous processes on night-time chemistry over north-western Europe D. Lowe et al. 10.5194/acp-15-1385-2015
- Understanding the primary emissions and secondary formation of gaseous organic acids in the oil sands region of Alberta, Canada J. Liggio et al. 10.5194/acp-17-8411-2017
- An Iodide-Adduct High-Resolution Time-of-Flight Chemical-Ionization Mass Spectrometer: Application to Atmospheric Inorganic and Organic Compounds B. Lee et al. 10.1021/es500362a
- A large and ubiquitous source of atmospheric formic acid D. Millet et al. 10.5194/acp-15-6283-2015
- Airborne hydrogen cyanide measurements using a chemical ionisation mass spectrometer for the plume identification of biomass burning forest fires M. Le Breton et al. 10.5194/acp-13-9217-2013
- A decade’s (2014–2024) perspective on cassava’s (Manihot esculenta Crantz) contribution to the global hydrogen cyanide load in the environment E. Itoba-Tombo et al. 10.1080/00207233.2016.1227209
- Measuring acetic and formic acid by proton-transfer-reaction mass spectrometry: sensitivity, humidity dependence, and quantifying interferences M. Baasandorj et al. 10.5194/amt-8-1303-2015
- Optimizing the iodide-adduct chemical ionization mass spectrometry (CIMS) quantitative method for toluene oxidation intermediates: experimental insights into functional-group differences M. Song et al. 10.5194/amt-17-5113-2024
- Observations of organic and inorganic chlorinated compounds and their contribution to chlorine radical concentrations in an urban environment in northern Europe during the wintertime M. Priestley et al. 10.5194/acp-18-13481-2018
- Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air G. Li et al. 10.5194/acp-19-2209-2019
- Performance of a new coaxial ion–molecule reaction region for low-pressure chemical ionization mass spectrometry with reduced instrument wall interactions B. Palm et al. 10.5194/amt-12-5829-2019
- Assessing formic and acetic acid emissions and chemistry in western U.S. wildfire smoke: implications for atmospheric modeling W. Permar et al. 10.1039/D3EA00098B
- Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures H. Kang et al. 10.5194/acp-23-14307-2023
- Limited Formation of CO3+ through Strong-Field Ionization and Coulomb Explosion of Formic Acid Clusters S. Sutton et al. 10.1021/acs.jpca.2c06141
- Aircraft observations of the lower troposphere above a megacity: Alkyl nitrate and ozone chemistry E. Aruffo et al. 10.1016/j.atmosenv.2014.05.040
- A Large Underestimate of Formic Acid from Tropical Fires: Constraints from Space-Borne Measurements S. Chaliyakunnel et al. 10.1021/acs.est.5b06385
- Seasonality of Formic Acid (HCOOH) in London during the ClearfLo Campaign T. Bannan et al. 10.1002/2017JD027064
- High-Performance Sensing of Formic Acid Vapor Enabled by a Newly Developed Nanofilm-Based Fluorescent Sensor Y. Wu et al. 10.1021/acs.analchem.1c00576
- A switchable reagent ion high resolution time-of-flight chemical ionization mass spectrometer for real-time measurement of gas phase oxidized species: characterization from the 2013 southern oxidant and aerosol study P. Brophy & D. Farmer 10.5194/amt-8-2945-2015
- An ion-neutral model to investigate chemical ionization mass spectrometry analysis of atmospheric molecules – application to a mixed reagent ion system for hydroperoxides and organic acids B. Heikes et al. 10.5194/amt-11-1851-2018
- Are the Fenno-Scandinavian Arctic Wetlands a Significant Regional Source of Formic Acid? B. Jones et al. 10.3390/atmos8070112
- Investigation of secondary formation of formic acid: urban environment vs. oil and gas producing region B. Yuan et al. 10.5194/acp-15-1975-2015
- Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS M. Le Breton et al. 10.5194/acp-18-10355-2018
- Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement P. Eger et al. 10.5194/amt-12-1935-2019
- Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications O. Welz et al. 10.1002/ange.201400964
- Measurement of formic acid, acetic acid and hydroxyacetaldehyde, hydrogen peroxide, and methyl peroxide in air by chemical ionization mass spectrometry: airborne method development V. Treadaway et al. 10.5194/amt-11-1901-2018
- Photochemical ageing of aerosols contributes significantly to the production of atmospheric formic acid Y. Jiang et al. 10.5194/acp-23-14813-2023
- High gas-phase mixing ratios of formic and acetic acid in the High Arctic E. Mungall et al. 10.5194/acp-18-10237-2018
- Computational Comparison of Different Reagent Ions in the Chemical Ionization of Oxidized Multifunctional Compounds N. Hyttinen et al. 10.1021/acs.jpca.7b10015
- Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications O. Welz et al. 10.1002/anie.201400964
- Computational and Experimental Investigation of the Detection of HO2 Radical and the Products of Its Reaction with Cyclohexene Ozonolysis Derived RO2 Radicals by an Iodide-Based Chemical Ionization Mass Spectrometer S. Iyer et al. 10.1021/acs.jpca.7b01588
- Properties and evolution of biomass burning organic aerosol from Canadian boreal forest fires M. Jolleys et al. 10.5194/acp-15-3077-2015
- Non-radioactive Chemical Ionization Mass Spectrometry Using Acetic Acid–Acetate Cluster as a Reagent Ion for the Real-time Measurement of Acids and Hydroperoxides S. Inomata & J. Hirokawa 10.1246/cl.160828
- Airborne measurements of HC(O)OH in the European Arctic: A winter – summer comparison B. Jones et al. 10.1016/j.atmosenv.2014.10.030
- Importance of direct anthropogenic emissions of formic acid measured by a chemical ionisation mass spectrometer (CIMS) during the Winter ClearfLo Campaign in London, January 2012 T. Bannan et al. 10.1016/j.atmosenv.2013.10.029
- The first UK measurements of nitryl chloride using a chemical ionization mass spectrometer in central London in the summer of 2012, and an investigation of the role of Cl atom oxidation T. Bannan et al. 10.1002/2014JD022629
- The first airborne comparison of N2O5 measurements over the UK using a CIMS and BBCEAS during the RONOCO campaign M. Le Breton et al. 10.1039/C4AY02273D
- Simultaneous airborne nitric acid and formic acid measurements using a chemical ionization mass spectrometer around the UK: Analysis of primary and secondary production pathways M. Le Breton et al. 10.1016/j.atmosenv.2013.10.008
47 citations as recorded by crossref.
- Online measurements of water-soluble organic acids in the gas and aerosol phase from the photooxidation of 1,3,5-trimethylbenzene A. Praplan et al. 10.5194/acp-14-8665-2014
- Comparison of negative-ion proton-transfer with iodide ion chemical ionization mass spectrometry for quantification of isocyanic acid in ambient air R. Woodward-Massey et al. 10.1016/j.atmosenv.2014.09.014
- Enhanced ozone loss by active inorganic bromine chemistry in the tropical troposphere M. Le Breton et al. 10.1016/j.atmosenv.2017.02.003
- Tropospheric Emission Spectrometer (TES) satellite observations of ammonia, methanol, formic acid, and carbon monoxide over the Canadian oil sands: validation and model evaluation M. Shephard et al. 10.5194/amt-8-5189-2015
- Observations of Isocyanate, Amide, Nitrate, and Nitro Compounds From an Anthropogenic Biomass Burning Event Using a ToF‐CIMS M. Priestley et al. 10.1002/2017JD027316
- A low-activity ion source for measurement of atmospheric gases by chemical ionization mass spectrometry Y. Lee et al. 10.5194/amt-13-2473-2020
- An aircraft gas chromatograph–mass spectrometer System for Organic Fast Identification Analysis (SOFIA): design, performance and a case study of Asian monsoon pollution outflow E. Bourtsoukidis et al. 10.5194/amt-10-5089-2017
- Coordinated Airborne Studies in the Tropics (CAST) N. Harris et al. 10.1175/BAMS-D-14-00290.1
- Derivation of Hydroperoxyl Radical Levels at an Urban Site via Measurement of Pernitric Acid by Iodide Chemical Ionization Mass Spectrometry D. Chen et al. 10.1021/acs.est.6b05169
- A potential source of atmospheric sulfate from O<sub>2</sub><sup>−</sup>-induced SO<sub>2</sub> oxidation by ozone N. Tsona & L. Du 10.5194/acp-19-649-2019
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- High-resolution chemical ionization mass spectrometry (ToF-CIMS): application to study SOA composition and processing D. Aljawhary et al. 10.5194/amt-6-3211-2013
- Aromatic Photo-oxidation, A New Source of Atmospheric Acidity S. Wang et al. 10.1021/acs.est.0c00526
- A dopant-assisted iodide-adduct chemical ionization time-of-flight mass spectrometer based on VUV lamp photoionization for atmospheric low-molecular-weight organic acids analysis Y. Zhang et al. 10.1016/j.jes.2024.01.008
- WRF-Chem model predictions of the regional impacts of N<sub>2</sub>O<sub>5</sub> heterogeneous processes on night-time chemistry over north-western Europe D. Lowe et al. 10.5194/acp-15-1385-2015
- Understanding the primary emissions and secondary formation of gaseous organic acids in the oil sands region of Alberta, Canada J. Liggio et al. 10.5194/acp-17-8411-2017
- An Iodide-Adduct High-Resolution Time-of-Flight Chemical-Ionization Mass Spectrometer: Application to Atmospheric Inorganic and Organic Compounds B. Lee et al. 10.1021/es500362a
- A large and ubiquitous source of atmospheric formic acid D. Millet et al. 10.5194/acp-15-6283-2015
- Airborne hydrogen cyanide measurements using a chemical ionisation mass spectrometer for the plume identification of biomass burning forest fires M. Le Breton et al. 10.5194/acp-13-9217-2013
- A decade’s (2014–2024) perspective on cassava’s (Manihot esculenta Crantz) contribution to the global hydrogen cyanide load in the environment E. Itoba-Tombo et al. 10.1080/00207233.2016.1227209
- Measuring acetic and formic acid by proton-transfer-reaction mass spectrometry: sensitivity, humidity dependence, and quantifying interferences M. Baasandorj et al. 10.5194/amt-8-1303-2015
- Optimizing the iodide-adduct chemical ionization mass spectrometry (CIMS) quantitative method for toluene oxidation intermediates: experimental insights into functional-group differences M. Song et al. 10.5194/amt-17-5113-2024
- Observations of organic and inorganic chlorinated compounds and their contribution to chlorine radical concentrations in an urban environment in northern Europe during the wintertime M. Priestley et al. 10.5194/acp-18-13481-2018
- Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air G. Li et al. 10.5194/acp-19-2209-2019
- Performance of a new coaxial ion–molecule reaction region for low-pressure chemical ionization mass spectrometry with reduced instrument wall interactions B. Palm et al. 10.5194/amt-12-5829-2019
- Assessing formic and acetic acid emissions and chemistry in western U.S. wildfire smoke: implications for atmospheric modeling W. Permar et al. 10.1039/D3EA00098B
- Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures H. Kang et al. 10.5194/acp-23-14307-2023
- Limited Formation of CO3+ through Strong-Field Ionization and Coulomb Explosion of Formic Acid Clusters S. Sutton et al. 10.1021/acs.jpca.2c06141
- Aircraft observations of the lower troposphere above a megacity: Alkyl nitrate and ozone chemistry E. Aruffo et al. 10.1016/j.atmosenv.2014.05.040
- A Large Underestimate of Formic Acid from Tropical Fires: Constraints from Space-Borne Measurements S. Chaliyakunnel et al. 10.1021/acs.est.5b06385
- Seasonality of Formic Acid (HCOOH) in London during the ClearfLo Campaign T. Bannan et al. 10.1002/2017JD027064
- High-Performance Sensing of Formic Acid Vapor Enabled by a Newly Developed Nanofilm-Based Fluorescent Sensor Y. Wu et al. 10.1021/acs.analchem.1c00576
- A switchable reagent ion high resolution time-of-flight chemical ionization mass spectrometer for real-time measurement of gas phase oxidized species: characterization from the 2013 southern oxidant and aerosol study P. Brophy & D. Farmer 10.5194/amt-8-2945-2015
- An ion-neutral model to investigate chemical ionization mass spectrometry analysis of atmospheric molecules – application to a mixed reagent ion system for hydroperoxides and organic acids B. Heikes et al. 10.5194/amt-11-1851-2018
- Are the Fenno-Scandinavian Arctic Wetlands a Significant Regional Source of Formic Acid? B. Jones et al. 10.3390/atmos8070112
- Investigation of secondary formation of formic acid: urban environment vs. oil and gas producing region B. Yuan et al. 10.5194/acp-15-1975-2015
- Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS M. Le Breton et al. 10.5194/acp-18-10355-2018
- Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement P. Eger et al. 10.5194/amt-12-1935-2019
- Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications O. Welz et al. 10.1002/ange.201400964
- Measurement of formic acid, acetic acid and hydroxyacetaldehyde, hydrogen peroxide, and methyl peroxide in air by chemical ionization mass spectrometry: airborne method development V. Treadaway et al. 10.5194/amt-11-1901-2018
- Photochemical ageing of aerosols contributes significantly to the production of atmospheric formic acid Y. Jiang et al. 10.5194/acp-23-14813-2023
- High gas-phase mixing ratios of formic and acetic acid in the High Arctic E. Mungall et al. 10.5194/acp-18-10237-2018
- Computational Comparison of Different Reagent Ions in the Chemical Ionization of Oxidized Multifunctional Compounds N. Hyttinen et al. 10.1021/acs.jpca.7b10015
- Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications O. Welz et al. 10.1002/anie.201400964
- Computational and Experimental Investigation of the Detection of HO2 Radical and the Products of Its Reaction with Cyclohexene Ozonolysis Derived RO2 Radicals by an Iodide-Based Chemical Ionization Mass Spectrometer S. Iyer et al. 10.1021/acs.jpca.7b01588
- Properties and evolution of biomass burning organic aerosol from Canadian boreal forest fires M. Jolleys et al. 10.5194/acp-15-3077-2015
- Non-radioactive Chemical Ionization Mass Spectrometry Using Acetic Acid–Acetate Cluster as a Reagent Ion for the Real-time Measurement of Acids and Hydroperoxides S. Inomata & J. Hirokawa 10.1246/cl.160828
5 citations as recorded by crossref.
- Airborne measurements of HC(O)OH in the European Arctic: A winter – summer comparison B. Jones et al. 10.1016/j.atmosenv.2014.10.030
- Importance of direct anthropogenic emissions of formic acid measured by a chemical ionisation mass spectrometer (CIMS) during the Winter ClearfLo Campaign in London, January 2012 T. Bannan et al. 10.1016/j.atmosenv.2013.10.029
- The first UK measurements of nitryl chloride using a chemical ionization mass spectrometer in central London in the summer of 2012, and an investigation of the role of Cl atom oxidation T. Bannan et al. 10.1002/2014JD022629
- The first airborne comparison of N2O5 measurements over the UK using a CIMS and BBCEAS during the RONOCO campaign M. Le Breton et al. 10.1039/C4AY02273D
- Simultaneous airborne nitric acid and formic acid measurements using a chemical ionization mass spectrometer around the UK: Analysis of primary and secondary production pathways M. Le Breton et al. 10.1016/j.atmosenv.2013.10.008
Saved (final revised paper)
Saved (preprint)
Latest update: 13 Dec 2024