Articles | Volume 7, issue 12
https://doi.org/10.5194/amt-7-4417-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-7-4417-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Online derivatization for hourly measurements of gas- and particle-phase semi-volatile oxygenated organic compounds by thermal desorption aerosol gas chromatography (SV-TAG)
G. Isaacman
CORRESPONDING AUTHOR
Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA, USA
N. M. Kreisberg
Aerosol Dynamics Inc., Berkeley, CA, USA
L. D. Yee
Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA, USA
D. R. Worton
Aerosol Dynamics Inc., Berkeley, CA, USA
Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA, USA
A. W. H. Chan
now at: Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Canada
Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA, USA
J. A. Moss
Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA, USA
S. V. Hering
Aerosol Dynamics Inc., Berkeley, CA, USA
A. H. Goldstein
Department of Civil and Environmental Engineering, University of California, Berkeley, CA, USA
Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA, USA
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- Hourly measurement of PM2.5-bound nonpolar organic compounds in Shanghai: Characteristics, sources and health risk assessment K. Zhang et al. 10.1016/j.scitotenv.2021.148070
- Influence of the vapor wall loss on the degradation rate constants in chamber experiments of levoglucosan and other biomass burning markers A. Bertrand et al. 10.5194/acp-18-10915-2018
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Underestimation of biomass burning contribution to PM2.5 due to its chemical degradation based on hourly measurements of organic tracers: A case study in the Yangtze River Delta (YRD) region, China Q. Li et al. 10.1016/j.scitotenv.2023.162071
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- Comprehensive detection of analytes in large chromatographic datasets by coupling factor analysis with a decision tree S. Kim et al. 10.5194/amt-15-5061-2022
- Coupling Filter-Based Thermal Desorption Chemical Ionization Mass Spectrometry with Liquid Chromatography/Electrospray Ionization Mass Spectrometry for Molecular Analysis of Secondary Organic Aerosol Y. Huang et al. 10.1021/acs.est.0c01779
- Speciated measurements of semivolatile and intermediate volatility organic compounds (S/IVOCs) in a pine forest during BEACHON-RoMBAS 2011 A. Chan et al. 10.5194/acp-16-1187-2016
- Tracking indoor volatile organic compounds with online mass spectrometry W. Liu et al. 10.1016/j.trac.2023.117514
- Analytical Challenges and Opportunities For Indoor Air Chemistry Field Studies D. Farmer 10.1021/acs.analchem.9b00277
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Latest update: 21 Nov 2024
Short summary
We present here a new in situ instrument for ambient measurements of highly polar organic semi-volatile and low-volatility compounds in both the gas and particle phase by gas chromatography. Compounds previously measured only through filter collection and offline analysis can now be measured hourly with, in most cases, less than 20% uncertainty. This instrument provides unprecedented time resolution and the first ever observations of gas-particle partitioning for most of these compounds.
We present here a new in situ instrument for ambient measurements of highly polar organic...