Articles | Volume 8, issue 4
https://doi.org/10.5194/amt-8-1835-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-1835-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
23 Apr 2015
Research article |
| 23 Apr 2015
Instrument intercomparison of glyoxal, methyl glyoxal and NO2 under simulated atmospheric conditions
R. Thalman
Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), Boulder, CO, USA
now at: Brookhaven National Laboratory, Upton, NY, USA
M. T. Baeza-Romero
Escuela de Ingeniería Industrial de Toledo, Universidad de Castilla la Mancha, Toledo, Spain
S. M. Ball
Department of Chemistry, University of Leicester, Leicester, LE1 7RH, UK
E. Borrás
Instituto Universitario UMH-CEAM, Valencia, Spain
M. J. S. Daniels
Department of Chemistry, University of Leicester, Leicester, LE1 7RH, UK
I. C. A. Goodall
Department of Chemistry, University of Leicester, Leicester, LE1 7RH, UK
S. B. Henry
Department of Chemistry, University of Wisconsin, Madison, WI, USA
T. Karl
National Center for Atmospheric Research, Boulder, CO, USA
Institute for Meteorology and Geophysics, University of Innsbruck, Innsbruck, Austria
F. N. Keutsch
Department of Chemistry, University of Wisconsin, Madison, WI, USA
National Center for Atmospheric Research, Boulder, CO, USA
Department of Earth System Science, University of California Irvine, Irvine, CA, USA
J. Mak
School of Marine and Atmospheric Sciences, State University of New York, Stony Brook, NY, USA
P. S. Monks
Department of Chemistry, University of Leicester, Leicester, LE1 7RH, UK
Instituto Universitario UMH-CEAM, Valencia, Spain
J. Orlando
National Center for Atmospheric Research, Boulder, CO, USA
S. Peppe
School of Earth and Environment, University of Leeds, Leeds, UK
A. R. Rickard
National Centre for Atmospheric Science, School of Chemistry, University of Leeds, Leeds, UK
now at: National Centre for Atmospheric Science, Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
M. Ródenas
Instituto Universitario UMH-CEAM, Valencia, Spain
P. Sánchez
Instituto Universitario UMH-CEAM, Valencia, Spain
National Center for Atmospheric Research, Boulder, CO, USA
Department of Earth System Science, University of California Irvine, Irvine, CA, USA
L. Su
School of Marine and Atmospheric Sciences, State University of New York, Stony Brook, NY, USA
G. Tyndall
National Center for Atmospheric Research, Boulder, CO, USA
M. Vázquez
Instituto Universitario UMH-CEAM, Valencia, Spain
T. Vera
Instituto Universitario UMH-CEAM, Valencia, Spain
E. Waxman
Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), Boulder, CO, USA
Viewed
Total article views: 5,080 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 19 Aug 2014)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,034 | 1,890 | 156 | 5,080 | 638 | 195 | 196 |
- HTML: 3,034
- PDF: 1,890
- XML: 156
- Total: 5,080
- Supplement: 638
- BibTeX: 195
- EndNote: 196
Total article views: 3,885 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 23 Apr 2015)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,382 | 1,374 | 129 | 3,885 | 431 | 142 | 168 |
- HTML: 2,382
- PDF: 1,374
- XML: 129
- Total: 3,885
- Supplement: 431
- BibTeX: 142
- EndNote: 168
Total article views: 1,195 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 19 Aug 2014)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 652 | 516 | 27 | 1,195 | 53 | 28 |
- HTML: 652
- PDF: 516
- XML: 27
- Total: 1,195
- BibTeX: 53
- EndNote: 28
Cited
44 citations as recorded by crossref.
- Aqueous phase oxidation of sulphur dioxide by ozone in cloud droplets C. Hoyle et al. 10.5194/acp-16-1693-2016
- Nitrous acid (HONO) emissions under real-world driving conditions from vehicles in a UK road tunnel L. Kramer et al. 10.5194/acp-20-5231-2020
- Aircraft measurements of BrO, IO, glyoxal, NO<sub>2</sub>, H<sub>2</sub>O, O<sub>2</sub>–O<sub>2</sub> and aerosol extinction profiles in the tropics: comparison with aircraft-/ship-based in situ and lidar measurements R. Volkamer et al. 10.5194/amt-8-2121-2015
- Sensitive detection of glyoxal by cluster-mediated CH2Br2+ chemical ionization time-of-flight mass spectrometry N. Wan et al. 10.1016/j.aca.2022.339612
- Intercomparison of open-path trace gas measurements with two dual-frequency-comb spectrometers E. Waxman et al. 10.5194/amt-10-3295-2017
- An IBBCEAS system for atmospheric measurements of glyoxal and methylglyoxal in the presence of high NO<sub>2</sub> concentrations J. Liu et al. 10.5194/amt-12-4439-2019
- Simultaneous detection of atmospheric HONO and NO<sub>2</sub> utilising an IBBCEAS system based on an iterative algorithm K. Tang et al. 10.5194/amt-13-6487-2020
- Emissions of Glyoxal and Other Carbonyl Compounds from Agricultural Biomass Burning Plumes Sampled by Aircraft K. Zarzana et al. 10.1021/acs.est.7b03517
- Glyoxal in a nocturnal atmosphere measured by incoherent broadband cavity-enhanced absorption spectroscopy K. Suhail et al. 10.1007/s11869-021-01131-6
- Glyoxal measurement with a proton transfer reaction time of flight mass spectrometer (PTR‐TOF‐MS): characterization and calibration C. Stönner et al. 10.1002/jms.3893
- Detection of Sulfur Dioxide by Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) R. Thalman et al. 10.3390/s22072626
- Comparison of VOC measurements made by PTR-MS, adsorbent tubes–GC-FID-MS and DNPH derivatization–HPLC during the Sydney Particle Study, 2012: a contribution to the assessment of uncertainty in routine atmospheric VOC measurements E. Dunne et al. 10.5194/amt-11-141-2018
- Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) Coupled with an Interferometer for On-Band and Off-Band Detection of Glyoxal C. Flowerday et al. 10.3390/toxics12010026
- Heterogeneous photochemistry of imidazole-2-carboxaldehyde: HO<sub>2</sub> radical formation and aerosol growth L. González Palacios et al. 10.5194/acp-16-11823-2016
- Portable broadband cavity-enhanced spectrometer utilizing Kalman filtering: application to real-time, in situ monitoring of glyoxal and nitrogen dioxide B. Fang et al. 10.1364/OE.25.026910
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO<sub>2</sub>, RO<sub>2</sub>NO<sub>2</sub>, and RONO<sub>2</sub> in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- On-line solid phase microextraction derivatization for the sensitive determination of multi-oxygenated volatile compounds in air E. Borrás et al. 10.5194/amt-14-4989-2021
- Profiling of formaldehyde, glyoxal, methylglyoxal, and CO over the Amazon: normalized excess mixing ratios and related emission factors in biomass burning plumes F. Kluge et al. 10.5194/acp-20-12363-2020
- Confirmation of PNNL Quantitative Infrared Cross-Sections for Isobutane T. Johnson et al. 10.1021/acs.jpca.1c01933
- Incoherent broad-band cavity enhanced absorption spectroscopy for sensitive and rapid molecular iodine detection in the presence of aerosols and water vapour C. Bahrini et al. 10.1016/j.optlastec.2018.06.050
- Determination of glyoxal and methylglyoxal in atmospheric fine particulate matter by vortex-assisted micro-solid phase extraction and liquid chromatography-diode array detection N. Naing & H. Lee 10.1016/j.chroma.2018.08.060
- Photolysis of multifunctional carbonyl compounds under natural irradiation at EUPHORE A. Tomas et al. 10.1016/j.atmosenv.2021.118352
- Characterization of the organic matter in submicron urban aerosols using a Thermo-Desorption Proton-Transfer-Reaction Time-of-Flight Mass Spectrometer (TD-PTR-TOF-MS) C. Salvador et al. 10.1016/j.atmosenv.2016.06.029
- A broadband cavity enhanced absorption spectrometer for aircraft measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water vapor K. Min et al. 10.5194/amt-9-423-2016
- The CU 2-D-MAX-DOAS instrument – Part 1: Retrieval of 3-D distributions of NO<sub>2</sub> and azimuth-dependent OVOC ratios I. Ortega et al. 10.5194/amt-8-2371-2015
- Is the ocean surface a source of nitrous acid (HONO) in the marine boundary layer? L. Crilley et al. 10.5194/acp-21-18213-2021
- Model representations of aerosol layers transported from North America over the Atlantic Ocean during the Two‐Column Aerosol Project J. Fast et al. 10.1002/2016JD025248
- On the relative absorption strengths of water vapour in the blue wavelength range J. Lampel et al. 10.5194/amt-8-4329-2015
- The Two‐Column Aerosol Project: Phase I—Overview and impact of elevated aerosol layers on aerosol optical depth L. Berg et al. 10.1002/2015JD023848
- What effect does VOC sampling time have on derived OH reactivity? H. Sonderfeld et al. 10.5194/acp-16-6303-2016
- Sensitive Detection of Gas-Phase Glyoxal by Electron Attachment Reaction Ionization Mass Spectrometry X. Lu et al. 10.1021/acs.analchem.9b02029
- Research on detection technology of photolysis rate of atmospheric trace gases Z. Liu et al. 10.1051/e3sconf/202456001004
- Electron Attachment Reaction Ionization of Gas-Phase Methylglyoxal X. Lu et al. 10.1021/acs.analchem.8b03305
- Development of an incoherent broadband cavity-enhanced absorption spectrometer for measurements of ambient glyoxal and NO<sub>2</sub> in a polluted urban environment S. Liang et al. 10.5194/amt-12-2499-2019
- Techniques for measuring indoor radicals and radical precursors E. Alvarez et al. 10.1080/05704928.2022.2087666
- Seasonal and geographical variability of nitryl chloride and its precursors in Northern Europe R. Sommariva et al. 10.1002/asl.844
- A broadband cavity-enhanced spectrometer for atmospheric trace gas measurements and Rayleigh scattering cross sections in the cyan region (470–540 nm) N. Jordan et al. 10.5194/amt-12-1277-2019
- Enhanced wintertime oxidation of VOCs via sustained radical sources in the urban atmosphere R. Sommariva et al. 10.1016/j.envpol.2021.116563
- Formaldehyde and glyoxal measurement deploying a selected ion flow tube mass spectrometer (SIFT-MS) A. Zogka et al. 10.5194/amt-15-2001-2022
- Field measurements of methylglyoxal using proton transfer reaction time-of-flight mass spectrometry and comparison to the DNPH–HPLC–UV method V. Michoud et al. 10.5194/amt-11-5729-2018
- Primary emissions of glyoxal and methylglyoxal from laboratory measurements of open biomass burning K. Zarzana et al. 10.5194/acp-18-15451-2018
- Measurements of diurnal variations and eddy covariance (EC) fluxes of glyoxal in the tropical marine boundary layer: description of the Fast LED-CE-DOAS instrument S. Coburn et al. 10.5194/amt-7-3579-2014
- Direct Absorption and Photoacoustic Spectroscopy for Gas Sensing and Analysis: A Critical Review A. Fathy et al. 10.1002/lpor.202100556
- Seasonal in situ observations of glyoxal and methylglyoxal over the temperate oceans of the Southern Hemisphere S. Lawson et al. 10.5194/acp-15-223-2015
41 citations as recorded by crossref.
- Aqueous phase oxidation of sulphur dioxide by ozone in cloud droplets C. Hoyle et al. 10.5194/acp-16-1693-2016
- Nitrous acid (HONO) emissions under real-world driving conditions from vehicles in a UK road tunnel L. Kramer et al. 10.5194/acp-20-5231-2020
- Aircraft measurements of BrO, IO, glyoxal, NO<sub>2</sub>, H<sub>2</sub>O, O<sub>2</sub>–O<sub>2</sub> and aerosol extinction profiles in the tropics: comparison with aircraft-/ship-based in situ and lidar measurements R. Volkamer et al. 10.5194/amt-8-2121-2015
- Sensitive detection of glyoxal by cluster-mediated CH2Br2+ chemical ionization time-of-flight mass spectrometry N. Wan et al. 10.1016/j.aca.2022.339612
- Intercomparison of open-path trace gas measurements with two dual-frequency-comb spectrometers E. Waxman et al. 10.5194/amt-10-3295-2017
- An IBBCEAS system for atmospheric measurements of glyoxal and methylglyoxal in the presence of high NO<sub>2</sub> concentrations J. Liu et al. 10.5194/amt-12-4439-2019
- Simultaneous detection of atmospheric HONO and NO<sub>2</sub> utilising an IBBCEAS system based on an iterative algorithm K. Tang et al. 10.5194/amt-13-6487-2020
- Emissions of Glyoxal and Other Carbonyl Compounds from Agricultural Biomass Burning Plumes Sampled by Aircraft K. Zarzana et al. 10.1021/acs.est.7b03517
- Glyoxal in a nocturnal atmosphere measured by incoherent broadband cavity-enhanced absorption spectroscopy K. Suhail et al. 10.1007/s11869-021-01131-6
- Glyoxal measurement with a proton transfer reaction time of flight mass spectrometer (PTR‐TOF‐MS): characterization and calibration C. Stönner et al. 10.1002/jms.3893
- Detection of Sulfur Dioxide by Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) R. Thalman et al. 10.3390/s22072626
- Comparison of VOC measurements made by PTR-MS, adsorbent tubes–GC-FID-MS and DNPH derivatization–HPLC during the Sydney Particle Study, 2012: a contribution to the assessment of uncertainty in routine atmospheric VOC measurements E. Dunne et al. 10.5194/amt-11-141-2018
- Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) Coupled with an Interferometer for On-Band and Off-Band Detection of Glyoxal C. Flowerday et al. 10.3390/toxics12010026
- Heterogeneous photochemistry of imidazole-2-carboxaldehyde: HO<sub>2</sub> radical formation and aerosol growth L. González Palacios et al. 10.5194/acp-16-11823-2016
- Portable broadband cavity-enhanced spectrometer utilizing Kalman filtering: application to real-time, in situ monitoring of glyoxal and nitrogen dioxide B. Fang et al. 10.1364/OE.25.026910
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO<sub>2</sub>, RO<sub>2</sub>NO<sub>2</sub>, and RONO<sub>2</sub> in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- On-line solid phase microextraction derivatization for the sensitive determination of multi-oxygenated volatile compounds in air E. Borrás et al. 10.5194/amt-14-4989-2021
- Profiling of formaldehyde, glyoxal, methylglyoxal, and CO over the Amazon: normalized excess mixing ratios and related emission factors in biomass burning plumes F. Kluge et al. 10.5194/acp-20-12363-2020
- Confirmation of PNNL Quantitative Infrared Cross-Sections for Isobutane T. Johnson et al. 10.1021/acs.jpca.1c01933
- Incoherent broad-band cavity enhanced absorption spectroscopy for sensitive and rapid molecular iodine detection in the presence of aerosols and water vapour C. Bahrini et al. 10.1016/j.optlastec.2018.06.050
- Determination of glyoxal and methylglyoxal in atmospheric fine particulate matter by vortex-assisted micro-solid phase extraction and liquid chromatography-diode array detection N. Naing & H. Lee 10.1016/j.chroma.2018.08.060
- Photolysis of multifunctional carbonyl compounds under natural irradiation at EUPHORE A. Tomas et al. 10.1016/j.atmosenv.2021.118352
- Characterization of the organic matter in submicron urban aerosols using a Thermo-Desorption Proton-Transfer-Reaction Time-of-Flight Mass Spectrometer (TD-PTR-TOF-MS) C. Salvador et al. 10.1016/j.atmosenv.2016.06.029
- A broadband cavity enhanced absorption spectrometer for aircraft measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water vapor K. Min et al. 10.5194/amt-9-423-2016
- The CU 2-D-MAX-DOAS instrument – Part 1: Retrieval of 3-D distributions of NO<sub>2</sub> and azimuth-dependent OVOC ratios I. Ortega et al. 10.5194/amt-8-2371-2015
- Is the ocean surface a source of nitrous acid (HONO) in the marine boundary layer? L. Crilley et al. 10.5194/acp-21-18213-2021
- Model representations of aerosol layers transported from North America over the Atlantic Ocean during the Two‐Column Aerosol Project J. Fast et al. 10.1002/2016JD025248
- On the relative absorption strengths of water vapour in the blue wavelength range J. Lampel et al. 10.5194/amt-8-4329-2015
- The Two‐Column Aerosol Project: Phase I—Overview and impact of elevated aerosol layers on aerosol optical depth L. Berg et al. 10.1002/2015JD023848
- What effect does VOC sampling time have on derived OH reactivity? H. Sonderfeld et al. 10.5194/acp-16-6303-2016
- Sensitive Detection of Gas-Phase Glyoxal by Electron Attachment Reaction Ionization Mass Spectrometry X. Lu et al. 10.1021/acs.analchem.9b02029
- Research on detection technology of photolysis rate of atmospheric trace gases Z. Liu et al. 10.1051/e3sconf/202456001004
- Electron Attachment Reaction Ionization of Gas-Phase Methylglyoxal X. Lu et al. 10.1021/acs.analchem.8b03305
- Development of an incoherent broadband cavity-enhanced absorption spectrometer for measurements of ambient glyoxal and NO<sub>2</sub> in a polluted urban environment S. Liang et al. 10.5194/amt-12-2499-2019
- Techniques for measuring indoor radicals and radical precursors E. Alvarez et al. 10.1080/05704928.2022.2087666
- Seasonal and geographical variability of nitryl chloride and its precursors in Northern Europe R. Sommariva et al. 10.1002/asl.844
- A broadband cavity-enhanced spectrometer for atmospheric trace gas measurements and Rayleigh scattering cross sections in the cyan region (470–540 nm) N. Jordan et al. 10.5194/amt-12-1277-2019
- Enhanced wintertime oxidation of VOCs via sustained radical sources in the urban atmosphere R. Sommariva et al. 10.1016/j.envpol.2021.116563
- Formaldehyde and glyoxal measurement deploying a selected ion flow tube mass spectrometer (SIFT-MS) A. Zogka et al. 10.5194/amt-15-2001-2022
- Field measurements of methylglyoxal using proton transfer reaction time-of-flight mass spectrometry and comparison to the DNPH–HPLC–UV method V. Michoud et al. 10.5194/amt-11-5729-2018
- Primary emissions of glyoxal and methylglyoxal from laboratory measurements of open biomass burning K. Zarzana et al. 10.5194/acp-18-15451-2018
3 citations as recorded by crossref.
- Measurements of diurnal variations and eddy covariance (EC) fluxes of glyoxal in the tropical marine boundary layer: description of the Fast LED-CE-DOAS instrument S. Coburn et al. 10.5194/amt-7-3579-2014
- Direct Absorption and Photoacoustic Spectroscopy for Gas Sensing and Analysis: A Critical Review A. Fathy et al. 10.1002/lpor.202100556
- Seasonal in situ observations of glyoxal and methylglyoxal over the temperate oceans of the Southern Hemisphere S. Lawson et al. 10.5194/acp-15-223-2015
Saved (final revised paper)
Saved (preprint)
Latest update: 23 Nov 2024
Short summary
Measurements of α-dicarbonyl compounds, like glyoxal (CHOCHO) and methyl glyoxal (CH3C(O)CHO), are informative about the rate of hydrocarbon oxidation, oxidative capacity, and secondary organic aerosol (SOA) formation in the atmosphere. We have compared nine instruments and seven techniques to measure α-dicarbonyl, using simulation chamber facilities in the US and Europe. We assess our understanding of calibration, precision, accuracy and detection limits, as well as possible sampling biases.
Measurements of α-dicarbonyl compounds, like glyoxal (CHOCHO) and methyl glyoxal (CH3C(O)CHO),...
