Articles | Volume 8, issue 5
https://doi.org/10.5194/amt-8-2121-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-2121-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
20 May 2015
Research article |
| 20 May 2015
Aircraft measurements of BrO, IO, glyoxal, NO2, H2O, O2–O2 and aerosol extinction profiles in the tropics: comparison with aircraft-/ship-based in situ and lidar measurements
Department of Chemistry & Biochemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
S. Baidar
Department of Chemistry & Biochemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
T. L. Campos
National Center for Atmospheric Research (NCAR), Atmospheric Chemistry Division (ACD), Boulder, CO, USA
S. Coburn
Department of Chemistry & Biochemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
J. P. DiGangi
Department of Civil and Environmental Engineering, Princeton University, Princeton, NJ, USA
now at: National Aeronautics and Space Administration (NASA) Langley Research Center, Hampton, VA, USA
Department of Chemistry & Biochemistry, University of Colorado, Boulder, CO, USA
E. W. Eloranta
Space Science and Engineering Center, University of Wisconsin, Madison, WI, USA
T. K. Koenig
Department of Chemistry & Biochemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
B. Morley
National Center for Atmospheric Research (NCAR), Research Aviation Facility/Earth Observing Laboratory (RAF/EOL), Broomfield, CO, USA
I. Ortega
Department of Chemistry & Biochemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
B. R. Pierce
National Oceanic and Atmospheric Administration (NOAA), The National Environmental Satellite, Data, and Information Service (NESDIS), Madison, WI, USA
M. Reeves
National Center for Atmospheric Research (NCAR), Research Aviation Facility/Earth Observing Laboratory (RAF/EOL), Broomfield, CO, USA
R. Sinreich
Department of Chemistry & Biochemistry, University of Colorado, Boulder, CO, USA
S. Wang
Department of Chemistry & Biochemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
now at: Department of Chemistry, Hong Kong University of Science and Technology, Hong Kong, China
M. A. Zondlo
Department of Civil and Environmental Engineering, Princeton University, Princeton, NJ, USA
P. A. Romashkin
National Center for Atmospheric Research (NCAR), Research Aviation Facility/Earth Observing Laboratory (RAF/EOL), Broomfield, CO, USA
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91 citations as recorded by crossref.
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- Primary effects of changes in meteorology vs. anthropogenic emissions on mercury wet deposition: A modeling study Z. Ye et al. 10.1016/j.atmosenv.2018.10.052
- Glyoxal tropospheric column retrievals from TROPOMI – multi-satellite intercomparison and ground-based validation C. Lerot et al. 10.5194/amt-14-7775-2021
- Impacts of ocean biogeochemistry on atmospheric chemistry L. Tinel et al. 10.1525/elementa.2023.00032
- Development of a digital mobile solar tracker S. Baidar et al. 10.5194/amt-9-963-2016
- Glyoxal yield from isoprene oxidation and relation to formaldehyde: chemical mechanism, constraints from SENEX aircraft observations, and interpretation of OMI satellite data C. Chan Miller et al. 10.5194/acp-17-8725-2017
- The O2/N2 Ratio and CO2 Airborne Southern Ocean Study B. Stephens et al. 10.1175/BAMS-D-16-0206.1
- Halogen chemistry reduces tropospheric O<sub>3</sub> radiative forcing T. Sherwen et al. 10.5194/acp-17-1557-2017
- Atmospheric Acetaldehyde: Importance of Air‐Sea Exchange and a Missing Source in the Remote Troposphere S. Wang et al. 10.1029/2019GL082034
- The gas-phase formation mechanism of iodic acid as an atmospheric aerosol source H. Finkenzeller et al. 10.1038/s41557-022-01067-z
- Injection of iodine to the stratosphere A. Saiz‐Lopez et al. 10.1002/2015GL064796
- Enhanced ozone loss by active inorganic bromine chemistry in the tropical troposphere M. Le Breton et al. 10.1016/j.atmosenv.2017.02.003
- Reassessing the ratio of glyoxal to formaldehyde as an indicator of hydrocarbon precursor speciation J. Kaiser et al. 10.5194/acp-15-7571-2015
- Undersizing of aged African biomass burning aerosol by an ultra-high-sensitivity aerosol spectrometer S. Howell et al. 10.5194/amt-14-7381-2021
- A new mechanism for atmospheric mercury redox chemistry: implications for the global mercury budget H. Horowitz et al. 10.5194/acp-17-6353-2017
- Detection of O<sub>4</sub> absorption around 328 and 419 nm in measured atmospheric absorption spectra J. Lampel et al. 10.5194/acp-18-1671-2018
- Observations and modelling of glyoxal in the tropical Atlantic marine boundary layer H. Walker et al. 10.5194/acp-22-5535-2022
- Technical note: Examining ozone deposition over seawater G. Sarwar et al. 10.1016/j.atmosenv.2016.06.072
- Monsoon circulations and tropical heterogeneous chlorine chemistry in the stratosphere S. Solomon et al. 10.1002/2016GL071778
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- Large hemispheric difference in nucleation mode aerosol concentrations in the lowermost stratosphere at mid- and high latitudes C. Williamson et al. 10.5194/acp-21-9065-2021
- Reconciling satellite aerosol optical thickness and surface fine particle mass through aerosol liquid water T. Nguyen et al. 10.1002/2016GL070994
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- Halogen activation and radical cycling initiated by imidazole-2-carboxaldehyde photochemistry P. Corral Arroyo et al. 10.5194/acp-19-10817-2019
- Active and widespread halogen chemistry in the tropical and subtropical free troposphere S. Wang et al. 10.1073/pnas.1505142112
- Impacts of bromine and iodine chemistry on tropospheric OH and HO<sub>2</sub>: comparing observations with box and global model perspectives D. Stone et al. 10.5194/acp-18-3541-2018
- The novel HALO mini-DOAS instrument: inferring trace gas concentrations from airborne UV/visible limb spectroscopy under all skies using the scaling method T. Hüneke et al. 10.5194/amt-10-4209-2017
- Quantitative detection of iodine in the stratosphere T. Koenig et al. 10.1073/pnas.1916828117
- Effects of thermodynamics, dynamics and aerosols on cirrus clouds based on in situ observations and NCAR CAM6 R. Patnaude et al. 10.5194/acp-21-1835-2021
- Ozone depletion due to dust release of iodine in the free troposphere T. Koenig et al. 10.1126/sciadv.abj6544
- Iodine's impact on tropospheric oxidants: a global model study in GEOS-Chem T. Sherwen et al. 10.5194/acp-16-1161-2016
- Elevated aerosol layers modify the O2–O2 absorption measured by ground-based MAX-DOAS I. Ortega et al. 10.1016/j.jqsrt.2016.02.021
- The CU 2-D-MAX-DOAS instrument – Part 2: Raman scattering probability measurements and retrieval of aerosol optical properties I. Ortega et al. 10.5194/amt-9-3893-2016
- Formaldehyde in the Tropical Western Pacific: Chemical Sources and Sinks, Convective Transport, and Representation in CAM‐Chem and the CCMI Models D. Anderson et al. 10.1002/2016JD026121
- Importance of reactive halogens in the tropical marine atmosphere: a regional modelling study using WRF-Chem A. Badia et al. 10.5194/acp-19-3161-2019
- MAX-DOAS measurements of NO<sub>2</sub>, SO<sub>2</sub>, HCHO, and BrO at the Mt. Waliguan WMO GAW global baseline station in the Tibetan Plateau J. Ma et al. 10.5194/acp-20-6973-2020
- An assessment of the radiative effects of ice supersaturation based on in situ observations X. Tan et al. 10.1002/2016GL071144
- Global Observations of Tropospheric Bromine Monoxide (BrO) Columns From TROPOMI Y. Chen et al. 10.1029/2023JD039091
- A broadband cavity enhanced absorption spectrometer for aircraft measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water vapor K. Min et al. 10.5194/amt-9-423-2016
- Nighttime atmospheric chemistry of iodine A. Saiz-Lopez et al. 10.5194/acp-16-15593-2016
- Role of iodine oxoacids in atmospheric aerosol nucleation X. He et al. 10.1126/science.abe0298
- The Two‐Column Aerosol Project: Phase I—Overview and impact of elevated aerosol layers on aerosol optical depth L. Berg et al. 10.1002/2015JD023848
- The CU 2-D-MAX-DOAS instrument – Part 1: Retrieval of 3-D distributions of NO<sub>2</sub> and azimuth-dependent OVOC ratios I. Ortega et al. 10.5194/amt-8-2371-2015
- Microlayer source of oxygenated volatile organic compounds in the summertime marine Arctic boundary layer E. Mungall et al. 10.1073/pnas.1620571114
- Mercury oxidation from bromine chemistry in the free troposphere over the southeastern US S. Coburn et al. 10.5194/acp-16-3743-2016
- Development of an incoherent broadband cavity-enhanced absorption spectrometer for measurements of ambient glyoxal and NO<sub>2</sub> in a polluted urban environment S. Liang et al. 10.5194/amt-12-2499-2019
- Airborne cavity enhanced absorption spectroscopy for high time resolution measurements of atmospheric NO2 . Liang Shuai-Xi et al. 10.7498/aps.66.090704
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Short summary
Tropospheric halogens and small oxygenated VOC (OVOC) modify tropospheric HOx and NOx, O3 and aerosols. We have measured bromine monoxide (BrO), iodine monoxide (IO), glyoxal (CHOCHO) profiles from research aircraft in the tropical troposphere and compare with ship- and aircraft-based in situ sensors. Our measurements point to the need to improve the representation of halogens and organic carbon sources in atmospheric models.
Tropospheric halogens and small oxygenated VOC (OVOC) modify tropospheric HOx and NOx, O3 and...
