Articles | Volume 8, issue 6
https://doi.org/10.5194/amt-8-2333-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-2333-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
05 Jun 2015
Research article |
| 05 Jun 2015
Statistical precision of the intensities retrieved from constrained fitting of overlapping peaks in high-resolution mass spectra
M. J. Cubison
CORRESPONDING AUTHOR
CIRES and Dept. of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
TOFWERK AG, Thun, Switzerland
J. L. Jimenez
CIRES and Dept. of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
Viewed
Total article views: 5,151 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 17 Dec 2014)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,124 | 1,874 | 153 | 5,151 | 555 | 174 | 214 |
- HTML: 3,124
- PDF: 1,874
- XML: 153
- Total: 5,151
- Supplement: 555
- BibTeX: 174
- EndNote: 214
Total article views: 4,384 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 05 Jun 2015)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,763 | 1,483 | 138 | 4,384 | 429 | 149 | 188 |
- HTML: 2,763
- PDF: 1,483
- XML: 138
- Total: 4,384
- Supplement: 429
- BibTeX: 149
- EndNote: 188
Total article views: 767 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 17 Dec 2014)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 361 | 391 | 15 | 767 | 25 | 26 |
- HTML: 361
- PDF: 391
- XML: 15
- Total: 767
- BibTeX: 25
- EndNote: 26
Cited
55 citations as recorded by crossref.
- Temperature and volatile organic compound concentrations as controlling factors for chemical composition of α-pinene-derived secondary organic aerosol L. Jensen et al. 10.5194/acp-21-11545-2021
- Arctic observations of hydroperoxymethyl thioformate (HPMTF) – seasonal behavior and relationship to other oxidation products of dimethyl sulfide at the Zeppelin Observatory, Svalbard K. Siegel et al. 10.5194/acp-23-7569-2023
- Capability of CI-Orbitrap for Gas-Phase Analysis in Atmospheric Chemistry: A Comparison with the CI-APi-TOF Technique M. Riva et al. 10.1021/acs.analchem.0c00111
- AutoSpect: an all-in-one software solution for automated processing of LA-ICP-TOF-MS datasets A. Crawford et al. 10.1039/D5JA00145E
- Real-time organic aerosol characterization via Orbitrap mass spectrometry in urban and agricultural environments J. David et al. 10.5194/amt-18-4573-2025
- Generalized Kendrick analysis for improved visualization of atmospheric mass spectral data M. Alton et al. 10.5194/amt-16-3273-2023
- CI-Orbitrap: An Analytical Instrument To Study Atmospheric Reactive Organic Species M. Riva et al. 10.1021/acs.analchem.9b02093
- Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry J. Pfeifer et al. 10.5194/amt-13-2501-2020
- An algorithm for automatic fitting and formula assignment in atmospheric mass spectra V. Mickwitz et al. 10.5194/amt-18-1537-2025
- Dimensionality-reduction techniques for complex mass spectrometric datasets: application to laboratory atmospheric organic oxidation experiments A. Koss et al. 10.5194/acp-20-1021-2020
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- Black carbon surface oxidation and organic composition of beech-wood soot aerosols J. Corbin et al. 10.5194/acp-15-11885-2015
- Measurements of volatile organic compounds in ambient air by gas-chromatography and real-time Vocus PTR-TOF-MS: calibrations, instrument background corrections, and introducing a PTR Data Toolkit A. Jensen et al. 10.5194/amt-16-5261-2023
- Gas-Phase Detection of Fluorotelomer Alcohols and Other Oxygenated Per- and Polyfluoroalkyl Substances by Chemical Ionization Mass Spectrometry T. Riedel et al. 10.1021/acs.estlett.9b00196
- Semi-differential analysis of irreversible voltammetric peaks M. Grdeń 10.1007/s10008-016-3461-7
- Applications and limitations of constrained high-resolution peak fitting on low resolving power mass spectra from the ToF-ACSM H. Timonen et al. 10.5194/amt-9-3263-2016
- Application of Calorimetric Low-Temperature Detectors for the Investigation of Z-Yield Distributions of Fission Fragments S. Dubey et al. 10.1007/s10909-018-1988-y
- Calorimetric low temperature detectors for heavy ion physics and their application in nuclear and atomic physics P. Egelhof & S. Kraft-Bermuth 10.1016/j.ppnp.2023.104031
- Field intercomparison of the gas/particle partitioning of oxygenated organics during the Southern Oxidant and Aerosol Study (SOAS) in 2013 S. Thompson et al. 10.1080/02786826.2016.1254719
- Secondary formation of nitrated phenols: insights from observations during the Uintah Basin Winter Ozone Study (UBWOS) 2014 B. Yuan et al. 10.5194/acp-16-2139-2016
- A novel approach for simple statistical analysis of high-resolution mass spectra Y. Zhang et al. 10.5194/amt-12-3761-2019
- Intensity-dependent mass search for improving metabolite database matches in chemical isotope labeling LC-QTOF-MS-based metabolomics Y. Li et al. 10.1016/j.aca.2023.341467
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Characterization of a new higher-resolution time-of-flight aerosol chemical speciation monitor: Application for measurements of atmospheric aerosols B. Nault et al. 10.1080/02786826.2025.2481221
- Clustering, methodology, and mechanistic insights into acetate chemical ionization using high-resolution time-of-flight mass spectrometry P. Brophy & D. Farmer 10.5194/amt-9-3969-2016
- The Impact of Molecular Oxygen on Anion Composition in a Hazy Archean Earth Atmosphere M. Ugelow et al. 10.1089/ast.2019.2145
- PTR3: An Instrument for Studying the Lifecycle of Reactive Organic Carbon in the Atmosphere M. Breitenlechner et al. 10.1021/acs.analchem.6b05110
- A high-resolution time-of-flight chemical ionization mass spectrometer utilizing hydronium ions (H3O+ ToF-CIMS) for measurements of volatile organic compounds in the atmosphere B. Yuan et al. 10.5194/amt-9-2735-2016
- Formation of oxidized organic compounds from Cl-initiated oxidation of toluene S. Dhulipala et al. 10.1016/j.atmosenv.2018.11.002
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
- Examining the chemical composition of black carbon particles from biomass burning with SP-AMS E. Fortner et al. 10.1016/j.jaerosci.2018.03.001
- Noncombustion Emissions of Organic Acids at a Site near Boise, Idaho A. Lindsay et al. 10.1021/acsestair.4c00138
- Measurement report: Effects of NOx and seed aerosol on highly oxygenated organic molecules (HOMs) from cyclohexene ozonolysis M. Räty et al. 10.5194/acp-21-7357-2021
- Chemical Composition of Gas-Phase Positive Ions during Laboratory Simulations of Titan’s Haze Formation J. Berry et al. 10.1021/acsearthspacechem.8b00139
- Measurements of higher alkanes using NO+ chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China C. Wang et al. 10.5194/acp-20-14123-2020
- Orbitool: a software tool for analyzing online Orbitrap mass spectrometry data R. Cai et al. 10.5194/amt-14-2377-2021
- Observations of highly oxidized molecules and particle nucleation in the atmosphere of Beijing J. Brean et al. 10.5194/acp-19-14933-2019
- Development of High Throughput Microscope Mode Secondary Ion Mass Spectrometry Imaging F. Green et al. 10.1021/jasms.2c00371
- Quantitative elemental mapping of chondritic meteorites using laser ablation-inductively coupled plasma-time of flight-mass spectrometry (LA-ICP-TOF-MS) R. Maeda et al. 10.1039/D2JA00317A
- Real-Time Measurements of Gas-Phase Medium-Chain Chlorinated Paraffins Reveal Daily Changes in Gas-Particle Partitioning Controlled by Ambient Temperature D. Katz et al. 10.1021/acsenvironau.5c00038
- Application of Calorimetric Low-Temperature Detectors for the Investigation of Z-Yield Distributions of Fission Fragments S. Dubey et al. 10.1051/epjconf/201819304002
- Experimental investigation into the volatilities of highly oxygenated organic molecules (HOMs) O. Peräkylä et al. 10.5194/acp-20-649-2020
- Online Aerosol Chemical Characterization by Extractive Electrospray Ionization–Ultrahigh-Resolution Mass Spectrometry (EESI-Orbitrap) C. Lee et al. 10.1021/acs.est.9b07090
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- Product ion distributions using H3O+ proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS): mechanisms, transmission effects, and instrument-to-instrument variability M. Link et al. 10.5194/amt-18-1013-2025
- Evaluating the performance of five different chemical ionization techniques for detecting gaseous oxygenated organic species M. Riva et al. 10.5194/amt-12-2403-2019
- Peak-fitting and integration imprecision in the Aerodyne aerosol mass spectrometer: effects of mass accuracy on location-constrained fits J. C. Corbin et al. 10.5194/amt-8-4615-2015
- A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements S. Schobesberger et al. 10.5194/acp-18-14757-2018
- Ion mobility spectrometry–mass spectrometry (IMS–MS) for on- and offline analysis of atmospheric gas and aerosol species J. Krechmer et al. 10.5194/amt-9-3245-2016
- Evaluation of NO+ reagent ion chemistry for online measurements of atmospheric volatile organic compounds A. Koss et al. 10.5194/amt-9-2909-2016
- The Influence of Gas-phase Chemistry on Organic Haze Formation J. Berry et al. 10.3847/2041-8213/ab4b5b
- Precision comparison of intensity ratios and area ratios in spectral analysis Y. Hagiwara & T. Kuwatani 10.1038/s41598-024-71653-3
- Review of technologies and their applications for the speciated detection of RO2 radicals Y. Gao et al. 10.1016/j.jes.2022.09.028
- Emission of Volatile Organic Compounds to the Atmosphere from Photochemistry in Thermokarst Ponds in Subarctic Canada D. Fillion et al. 10.1021/acsearthspacechem.3c00336
- Methods to extract molecular and bulk chemical information from series of complex mass spectra with limited mass resolution H. Stark et al. 10.1016/j.ijms.2015.08.011
54 citations as recorded by crossref.
- Temperature and volatile organic compound concentrations as controlling factors for chemical composition of α-pinene-derived secondary organic aerosol L. Jensen et al. 10.5194/acp-21-11545-2021
- Arctic observations of hydroperoxymethyl thioformate (HPMTF) – seasonal behavior and relationship to other oxidation products of dimethyl sulfide at the Zeppelin Observatory, Svalbard K. Siegel et al. 10.5194/acp-23-7569-2023
- Capability of CI-Orbitrap for Gas-Phase Analysis in Atmospheric Chemistry: A Comparison with the CI-APi-TOF Technique M. Riva et al. 10.1021/acs.analchem.0c00111
- AutoSpect: an all-in-one software solution for automated processing of LA-ICP-TOF-MS datasets A. Crawford et al. 10.1039/D5JA00145E
- Real-time organic aerosol characterization via Orbitrap mass spectrometry in urban and agricultural environments J. David et al. 10.5194/amt-18-4573-2025
- Generalized Kendrick analysis for improved visualization of atmospheric mass spectral data M. Alton et al. 10.5194/amt-16-3273-2023
- CI-Orbitrap: An Analytical Instrument To Study Atmospheric Reactive Organic Species M. Riva et al. 10.1021/acs.analchem.9b02093
- Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry J. Pfeifer et al. 10.5194/amt-13-2501-2020
- An algorithm for automatic fitting and formula assignment in atmospheric mass spectra V. Mickwitz et al. 10.5194/amt-18-1537-2025
- Dimensionality-reduction techniques for complex mass spectrometric datasets: application to laboratory atmospheric organic oxidation experiments A. Koss et al. 10.5194/acp-20-1021-2020
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- Black carbon surface oxidation and organic composition of beech-wood soot aerosols J. Corbin et al. 10.5194/acp-15-11885-2015
- Measurements of volatile organic compounds in ambient air by gas-chromatography and real-time Vocus PTR-TOF-MS: calibrations, instrument background corrections, and introducing a PTR Data Toolkit A. Jensen et al. 10.5194/amt-16-5261-2023
- Gas-Phase Detection of Fluorotelomer Alcohols and Other Oxygenated Per- and Polyfluoroalkyl Substances by Chemical Ionization Mass Spectrometry T. Riedel et al. 10.1021/acs.estlett.9b00196
- Semi-differential analysis of irreversible voltammetric peaks M. Grdeń 10.1007/s10008-016-3461-7
- Applications and limitations of constrained high-resolution peak fitting on low resolving power mass spectra from the ToF-ACSM H. Timonen et al. 10.5194/amt-9-3263-2016
- Application of Calorimetric Low-Temperature Detectors for the Investigation of Z-Yield Distributions of Fission Fragments S. Dubey et al. 10.1007/s10909-018-1988-y
- Calorimetric low temperature detectors for heavy ion physics and their application in nuclear and atomic physics P. Egelhof & S. Kraft-Bermuth 10.1016/j.ppnp.2023.104031
- Field intercomparison of the gas/particle partitioning of oxygenated organics during the Southern Oxidant and Aerosol Study (SOAS) in 2013 S. Thompson et al. 10.1080/02786826.2016.1254719
- Secondary formation of nitrated phenols: insights from observations during the Uintah Basin Winter Ozone Study (UBWOS) 2014 B. Yuan et al. 10.5194/acp-16-2139-2016
- A novel approach for simple statistical analysis of high-resolution mass spectra Y. Zhang et al. 10.5194/amt-12-3761-2019
- Intensity-dependent mass search for improving metabolite database matches in chemical isotope labeling LC-QTOF-MS-based metabolomics Y. Li et al. 10.1016/j.aca.2023.341467
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Characterization of a new higher-resolution time-of-flight aerosol chemical speciation monitor: Application for measurements of atmospheric aerosols B. Nault et al. 10.1080/02786826.2025.2481221
- Clustering, methodology, and mechanistic insights into acetate chemical ionization using high-resolution time-of-flight mass spectrometry P. Brophy & D. Farmer 10.5194/amt-9-3969-2016
- The Impact of Molecular Oxygen on Anion Composition in a Hazy Archean Earth Atmosphere M. Ugelow et al. 10.1089/ast.2019.2145
- PTR3: An Instrument for Studying the Lifecycle of Reactive Organic Carbon in the Atmosphere M. Breitenlechner et al. 10.1021/acs.analchem.6b05110
- A high-resolution time-of-flight chemical ionization mass spectrometer utilizing hydronium ions (H3O+ ToF-CIMS) for measurements of volatile organic compounds in the atmosphere B. Yuan et al. 10.5194/amt-9-2735-2016
- Formation of oxidized organic compounds from Cl-initiated oxidation of toluene S. Dhulipala et al. 10.1016/j.atmosenv.2018.11.002
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
- Examining the chemical composition of black carbon particles from biomass burning with SP-AMS E. Fortner et al. 10.1016/j.jaerosci.2018.03.001
- Noncombustion Emissions of Organic Acids at a Site near Boise, Idaho A. Lindsay et al. 10.1021/acsestair.4c00138
- Measurement report: Effects of NOx and seed aerosol on highly oxygenated organic molecules (HOMs) from cyclohexene ozonolysis M. Räty et al. 10.5194/acp-21-7357-2021
- Chemical Composition of Gas-Phase Positive Ions during Laboratory Simulations of Titan’s Haze Formation J. Berry et al. 10.1021/acsearthspacechem.8b00139
- Measurements of higher alkanes using NO+ chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China C. Wang et al. 10.5194/acp-20-14123-2020
- Orbitool: a software tool for analyzing online Orbitrap mass spectrometry data R. Cai et al. 10.5194/amt-14-2377-2021
- Observations of highly oxidized molecules and particle nucleation in the atmosphere of Beijing J. Brean et al. 10.5194/acp-19-14933-2019
- Development of High Throughput Microscope Mode Secondary Ion Mass Spectrometry Imaging F. Green et al. 10.1021/jasms.2c00371
- Quantitative elemental mapping of chondritic meteorites using laser ablation-inductively coupled plasma-time of flight-mass spectrometry (LA-ICP-TOF-MS) R. Maeda et al. 10.1039/D2JA00317A
- Real-Time Measurements of Gas-Phase Medium-Chain Chlorinated Paraffins Reveal Daily Changes in Gas-Particle Partitioning Controlled by Ambient Temperature D. Katz et al. 10.1021/acsenvironau.5c00038
- Application of Calorimetric Low-Temperature Detectors for the Investigation of Z-Yield Distributions of Fission Fragments S. Dubey et al. 10.1051/epjconf/201819304002
- Experimental investigation into the volatilities of highly oxygenated organic molecules (HOMs) O. Peräkylä et al. 10.5194/acp-20-649-2020
- Online Aerosol Chemical Characterization by Extractive Electrospray Ionization–Ultrahigh-Resolution Mass Spectrometry (EESI-Orbitrap) C. Lee et al. 10.1021/acs.est.9b07090
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- Product ion distributions using H3O+ proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS): mechanisms, transmission effects, and instrument-to-instrument variability M. Link et al. 10.5194/amt-18-1013-2025
- Evaluating the performance of five different chemical ionization techniques for detecting gaseous oxygenated organic species M. Riva et al. 10.5194/amt-12-2403-2019
- Peak-fitting and integration imprecision in the Aerodyne aerosol mass spectrometer: effects of mass accuracy on location-constrained fits J. C. Corbin et al. 10.5194/amt-8-4615-2015
- A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements S. Schobesberger et al. 10.5194/acp-18-14757-2018
- Ion mobility spectrometry–mass spectrometry (IMS–MS) for on- and offline analysis of atmospheric gas and aerosol species J. Krechmer et al. 10.5194/amt-9-3245-2016
- Evaluation of NO+ reagent ion chemistry for online measurements of atmospheric volatile organic compounds A. Koss et al. 10.5194/amt-9-2909-2016
- The Influence of Gas-phase Chemistry on Organic Haze Formation J. Berry et al. 10.3847/2041-8213/ab4b5b
- Precision comparison of intensity ratios and area ratios in spectral analysis Y. Hagiwara & T. Kuwatani 10.1038/s41598-024-71653-3
- Review of technologies and their applications for the speciated detection of RO2 radicals Y. Gao et al. 10.1016/j.jes.2022.09.028
- Emission of Volatile Organic Compounds to the Atmosphere from Photochemistry in Thermokarst Ponds in Subarctic Canada D. Fillion et al. 10.1021/acsearthspacechem.3c00336
Saved (final revised paper)
Latest update: 09 Oct 2025
