Articles | Volume 8, issue 6
https://doi.org/10.5194/amt-8-2347-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-2347-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
08 Jun 2015
Research article |
| 08 Jun 2015
Determination of atmospheric organosulfates using HILIC chromatography with MS detection
A. P. S. Hettiyadura
Department of Chemistry, Chemistry Building, University of Iowa, Iowa City, IA 52242, USA
E. A. Stone
CORRESPONDING AUTHOR
Department of Chemistry, Chemistry Building, University of Iowa, Iowa City, IA 52242, USA
S. Kundu
Department of Chemistry, Chemistry Building, University of Iowa, Iowa City, IA 52242, USA
Z. Baker
Department of Chemistry, Chemistry Building, University of Iowa, Iowa City, IA 52242, USA
E. Geddes
Chemistry Department, Truman State University, Kirksville, MO 63501, USA
K. Richards
Chemistry Department, Truman State University, Kirksville, MO 63501, USA
T. Humphry
Chemistry Department, Truman State University, Kirksville, MO 63501, USA
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Cited
79 citations as recorded by crossref.
- Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama A. Hettiyadura et al. 10.5194/acp-17-1343-2017
- Secondary Organic Aerosol Formation from Isoprene: Selected Research, Historic Account and State of the Art M. Claeys & W. Maenhaut 10.3390/atmos12060728
- Green Leaf Volatiles in the Atmosphere—Properties, Transformation, and Significance K. Sarang et al. 10.3390/atmos12121655
- Chemical composition of isoprene SOA under acidic and non-acidic conditions: effect of relative humidity K. Nestorowicz et al. 10.5194/acp-18-18101-2018
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Tracing the biogenic secondary organic aerosol markers in rain, snow and hail G. Spolnik et al. 10.1016/j.chemosphere.2020.126439
- Interactions of organosulfates with water vapor under sub- and supersaturated conditions C. Peng et al. 10.5194/acp-21-7135-2021
- Physical properties of short chain aqueous organosulfate aerosol A. Bain et al. 10.1039/D3EA00088E
- Field observations of C2 and C3 organosulfates and insights into their formation mechanisms at a suburban site in Hong Kong Y. Wang et al. 10.1016/j.scitotenv.2023.166851
- Study on heterogeneous OH oxidation of 3-methyltetraol sulfate in the atmosphere under high NO conditions C. Guo et al. 10.1039/D2RA02958H
- Water Uptake and Hygroscopic Growth of Organosulfate Aerosol A. Estillore et al. 10.1021/acs.est.5b05014
- Deactivating Effect of Hydroxyl Radicals Reactivity by Sulfate and Sulfite Functional Groups in Aqueous Phase─Atmospheric Implications for Small Organosulfur Compounds D. Lai et al. 10.1021/acsestair.4c00033
- Determination of secondary organic aerosol in particulate matter – Short review J. Klyta & M. Czaplicka 10.1016/j.microc.2020.104997
- Response of the Aerodyne Aerosol Mass Spectrometer to Inorganic Sulfates and Organosulfur Compounds: Applications in Field and Laboratory Measurements Y. Chen et al. 10.1021/acs.est.9b00884
- Simulation of SOA formation from the photooxidation of monoalkylbenzenes in the presence of aqueous aerosols containing electrolytes under various NO<sub><i>x</i></sub> levels C. Zhou et al. 10.5194/acp-19-5719-2019
- Organosulfates in the Midwestern United States: abundance, composition and stability D. Hughes & E. Stone 10.1071/EN18260
- Effects of relative humidity on atmospheric organosulfur species derived from photooxidation and nocturnal chemistry in a forest environment L. Li et al. 10.1016/j.envpol.2024.125253
- Improved UHPLC-MS/MS Methods for Analysis of Isoprene-Derived Organosulfates G. Spolnik et al. 10.1021/acs.analchem.7b05060
- Organosulfates in atmospheric aerosol: synthesis and quantitative analysis of PM<sub>2.5</sub> from Xi'an, northwestern China R. Huang et al. 10.5194/amt-11-3447-2018
- OH Radical Oxidation of Organosulfates in the Atmospheric Aqueous Phase D. Gweme & S. Styler 10.1021/acs.jpca.4c02877
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Spatial and diurnal variations of aerosol organosulfates in summertime Shanghai, China: potential influence of photochemical processes and anthropogenic sulfate pollution T. Yang et al. 10.5194/acp-23-13433-2023
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- Chemical transformation of a long-chain alkyl organosulfate via heterogeneous OH oxidation: a case study of sodium dodecyl sulfate S. Madeleine Ng et al. 10.1039/D2EA00026A
- Synthesis of the Southeast Atmosphere Studies: Investigating Fundamental Atmospheric Chemistry Questions A. Carlton et al. 10.1175/BAMS-D-16-0048.1
- Quality assurance and quality control of atmospheric organosulfates measured using hydrophilic interaction liquid chromatography (HILIC) P. Liu et al. 10.5194/amt-17-3067-2024
- Ion mobility spectrometry–mass spectrometry (IMS–MS) for on- and offline analysis of atmospheric gas and aerosol species J. Krechmer et al. 10.5194/amt-9-3245-2016
- Determination of highly polar compounds in atmospheric aerosol particles at ultra‐trace levels using ion chromatography Orbitrap mass spectrometry C. Kwiezinski et al. 10.1002/jssc.202001048
- Molecular-Level Study of the Photo-Oxidation of Aqueous-Phase Guaiacyl Acetone in the Presence of 3C*: Formation of Brown Carbon Products M. Misovich et al. 10.1021/acsearthspacechem.1c00103
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- Molecular characteristics, sources, and formation pathways of organosulfur compounds in ambient aerosol in Guangzhou, South China H. Jiang et al. 10.5194/acp-22-6919-2022
- Inconsistency of ammonium–sulfate aerosol ratios with thermodynamic models in the eastern US: a possible role of organic aerosol R. Silvern et al. 10.5194/acp-17-5107-2017
- Abundance of organosulfates derived from biogenic volatile organic compounds: Seasonal and spatial contrasts at four sites in China Y. Wang et al. 10.1016/j.scitotenv.2021.151275
- Organosulfate produced from consumption of SO3 speeds up sulfuric acid–dimethylamine atmospheric nucleation X. Zhang et al. 10.5194/acp-24-3593-2024
- OH Group Orientation Leads to Organosulfate Formation at the Liquid Aerosol Surface S. Tan et al. 10.1021/jacs.2c05807
- Molecular Characterization of Organosulfates in Highly Polluted Atmosphere Using Ultra‐High‐Resolution Mass Spectrometry D. Cai et al. 10.1029/2019JD032253
- Comparative Study of Particulate Organosulfates in Contrasting Atmospheric Environments: Field Evidence for the Significant Influence of Anthropogenic Sulfate and NOx Y. Wang et al. 10.1021/acs.estlett.0c00550
- PM2.5 chemistry, organosulfates, and secondary organic aerosol during the 2017 Lake Michigan Ozone Study D. Hughes et al. 10.1016/j.atmosenv.2020.117939
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- Quantifying organic matter and functional groups in particulate matter filter samples from the southeastern United States – Part 1: Methods A. Boris et al. 10.5194/amt-12-5391-2019
- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- Field Evidence for Constraints of Nearly Dry and Weakly Acidic Aerosol Conditions on the Formation of Organosulfates T. Yang et al. 10.1021/acs.estlett.4c00522
- Organosulfates in Atlanta, Georgia: anthropogenic influences on biogenic secondary organic aerosol formation A. Hettiyadura et al. 10.5194/acp-19-3191-2019
- Synthesis, MS/MS characteristics and quantification of six aromatic organosulfates in atmospheric PM2.5 J. He et al. 10.1016/j.atmosenv.2022.119361
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Synthesis of Four Monoterpene-Derived Organosulfates and Their Quantification in Atmospheric Aerosol Samples Y. Wang et al. 10.1021/acs.est.7b01179
- Monoterpene and Sesquiterpene α-Hydroxy Organosulfates: Synthesis, MS/MS Characteristics, and Ambient Presence Y. Wang et al. 10.1021/acs.est.9b04703
- Chemical and optical characterization of aqueous secondary organic aerosol generated by reaction of pyruvaldehyde with sodium sulfite M. Zhu et al. 10.1016/j.apr.2024.102124
- Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS M. Le Breton et al. 10.5194/acp-18-10355-2018
- Heterogeneous Hydroxyl Radical Oxidation of Isoprene-Epoxydiol-Derived Methyltetrol Sulfates: Plausible Formation Mechanisms of Previously Unexplained Organosulfates in Ambient Fine Aerosols Y. Chen et al. 10.1021/acs.estlett.0c00276
- Accurate Computational Model for the Hydration Extent of Atmospherically Relevant Carbonyls on Aqueous Atmospheric Particles M. Elrod et al. 10.1021/acsearthspacechem.0c00322
- Chemical composition, microstructure, and hygroscopic properties of aerosol particles at the Zotino Tall Tower Observatory (ZOTTO), Siberia, during a summer campaign E. Mikhailov et al. 10.5194/acp-15-8847-2015
- Ubiquitous Production of Organosulfates during Treatment of Organic Contaminants with Sulfate Radicals J. Van Buren et al. 10.1021/acs.estlett.1c00316
- Exploring sources of biogenic secondary organic aerosol compounds using chemical analysis and the FLEXPART model J. Martinsson et al. 10.5194/acp-17-11025-2017
- Importance of sulfate radical anion formation and chemistry in heterogeneous OH oxidation of sodium methyl sulfate, the smallest organosulfate K. Kwong et al. 10.5194/acp-18-2809-2018
- Heterogeneous Oxidation Products of Fine Particulate Isoprene Epoxydiol-Derived Methyltetrol Sulfates Increase Oxidative Stress and Inflammatory Gene Responses in Human Lung Cells F. Khan et al. 10.1021/acs.chemrestox.3c00278
- Structural Characterization of Lactone-Containing MW 212 Organosulfates Originating from Isoprene Oxidation in Ambient Fine Aerosol P. Wach et al. 10.1021/acs.est.9b06190
- Isoprene-Derived Organosulfates: Vibrational Mode Analysis by Raman Spectroscopy, Acidity-Dependent Spectral Modes, and Observation in Individual Atmospheric Particles A. Bondy et al. 10.1021/acs.jpca.7b10587
- Stability assessment of organic sulfur and organosulfate compounds in filter samples for quantification by Fourier- transform infrared spectroscopy M. Anunciado et al. 10.5194/amt-16-3515-2023
- Revealing Brown Carbon Chromophores Produced in Reactions of Methylglyoxal with Ammonium Sulfate P. Lin et al. 10.1021/acs.est.5b03608
- General Mechanism for Sulfate Radical Addition to Olefinic Volatile Organic Compounds in Secondary Organic Aerosol H. Ren et al. 10.1021/acs.est.0c05256
- Source apportionment of organic carbon in Centreville, AL using organosulfates in organic tracer-based positive matrix factorization A. Hettiyadura et al. 10.1016/j.atmosenv.2018.05.007
- Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol T. Cui et al. 10.1039/C8EM00308D
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Nontarget Screening Exhibits a Seasonal Cycle of PM2.5 Organic Aerosol Composition in Beijing J. Ma et al. 10.1021/acs.est.1c06905
- Molecular composition of organic aerosols in central Amazonia: an ultra-high-resolution mass spectrometry study I. Kourtchev et al. 10.5194/acp-16-11899-2016
- Important Roles and Formation of Atmospheric Organosulfates in Marine Organic Aerosols: Influence of Phytoplankton Emissions and Anthropogenic Pollutants Y. Wang et al. 10.1021/acs.est.3c01422
- Development and application of a quantification method for water soluble organosulfates in atmospheric aerosols G. Cao et al. 10.1016/j.envpol.2017.01.086
- Creating Meaningful Learning Opportunities through Incorporating Local Research into Chemistry Classroom Activities N. States et al. 10.3390/educsci13020192
- Evaluation of the new capture vaporizer for aerosol mass spectrometers (AMS) through field studies of inorganic species W. Hu et al. 10.1080/02786826.2017.1296104
- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
- Advances in the Separation and Detection of Secondary Organic Aerosol Produced by Decamethylcyclopentasiloxane (D5) in Laboratory-Generated and Ambient Aerosol J. Meepage et al. 10.1021/acsestair.3c00073
- Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-<i>E</i>-pentenal, 2-<i>E</i>-hexenal, and 3-<i>Z</i>-hexenal M. Shalamzari et al. 10.5194/acp-16-7135-2016
- Synthesis Enabled Investigations into the Acidity and Stability of Atmospherically-Relevant Isoprene-Derived Organosulfates J. Varelas et al. 10.1021/acsearthspacechem.2c00295
- Quantification of known and unknown terpenoid organosulfates in PM10 using untargeted LC–HRMS/MS: contrasting summertime rural Germany and the North China Plain M. Brüggemann et al. 10.1071/EN19089
- Evidence for an Unrecognized Secondary Anthropogenic Source of Organosulfates and Sulfonates: Gas-Phase Oxidation of Polycyclic Aromatic Hydrocarbons in the Presence of Sulfate Aerosol M. Riva et al. 10.1021/acs.est.5b00836
78 citations as recorded by crossref.
- Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama A. Hettiyadura et al. 10.5194/acp-17-1343-2017
- Secondary Organic Aerosol Formation from Isoprene: Selected Research, Historic Account and State of the Art M. Claeys & W. Maenhaut 10.3390/atmos12060728
- Green Leaf Volatiles in the Atmosphere—Properties, Transformation, and Significance K. Sarang et al. 10.3390/atmos12121655
- Chemical composition of isoprene SOA under acidic and non-acidic conditions: effect of relative humidity K. Nestorowicz et al. 10.5194/acp-18-18101-2018
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Tracing the biogenic secondary organic aerosol markers in rain, snow and hail G. Spolnik et al. 10.1016/j.chemosphere.2020.126439
- Interactions of organosulfates with water vapor under sub- and supersaturated conditions C. Peng et al. 10.5194/acp-21-7135-2021
- Physical properties of short chain aqueous organosulfate aerosol A. Bain et al. 10.1039/D3EA00088E
- Field observations of C2 and C3 organosulfates and insights into their formation mechanisms at a suburban site in Hong Kong Y. Wang et al. 10.1016/j.scitotenv.2023.166851
- Study on heterogeneous OH oxidation of 3-methyltetraol sulfate in the atmosphere under high NO conditions C. Guo et al. 10.1039/D2RA02958H
- Water Uptake and Hygroscopic Growth of Organosulfate Aerosol A. Estillore et al. 10.1021/acs.est.5b05014
- Deactivating Effect of Hydroxyl Radicals Reactivity by Sulfate and Sulfite Functional Groups in Aqueous Phase─Atmospheric Implications for Small Organosulfur Compounds D. Lai et al. 10.1021/acsestair.4c00033
- Determination of secondary organic aerosol in particulate matter – Short review J. Klyta & M. Czaplicka 10.1016/j.microc.2020.104997
- Response of the Aerodyne Aerosol Mass Spectrometer to Inorganic Sulfates and Organosulfur Compounds: Applications in Field and Laboratory Measurements Y. Chen et al. 10.1021/acs.est.9b00884
- Simulation of SOA formation from the photooxidation of monoalkylbenzenes in the presence of aqueous aerosols containing electrolytes under various NO<sub><i>x</i></sub> levels C. Zhou et al. 10.5194/acp-19-5719-2019
- Organosulfates in the Midwestern United States: abundance, composition and stability D. Hughes & E. Stone 10.1071/EN18260
- Effects of relative humidity on atmospheric organosulfur species derived from photooxidation and nocturnal chemistry in a forest environment L. Li et al. 10.1016/j.envpol.2024.125253
- Improved UHPLC-MS/MS Methods for Analysis of Isoprene-Derived Organosulfates G. Spolnik et al. 10.1021/acs.analchem.7b05060
- Organosulfates in atmospheric aerosol: synthesis and quantitative analysis of PM<sub>2.5</sub> from Xi'an, northwestern China R. Huang et al. 10.5194/amt-11-3447-2018
- OH Radical Oxidation of Organosulfates in the Atmospheric Aqueous Phase D. Gweme & S. Styler 10.1021/acs.jpca.4c02877
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Spatial and diurnal variations of aerosol organosulfates in summertime Shanghai, China: potential influence of photochemical processes and anthropogenic sulfate pollution T. Yang et al. 10.5194/acp-23-13433-2023
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- Chemical transformation of a long-chain alkyl organosulfate via heterogeneous OH oxidation: a case study of sodium dodecyl sulfate S. Madeleine Ng et al. 10.1039/D2EA00026A
- Synthesis of the Southeast Atmosphere Studies: Investigating Fundamental Atmospheric Chemistry Questions A. Carlton et al. 10.1175/BAMS-D-16-0048.1
- Quality assurance and quality control of atmospheric organosulfates measured using hydrophilic interaction liquid chromatography (HILIC) P. Liu et al. 10.5194/amt-17-3067-2024
- Ion mobility spectrometry–mass spectrometry (IMS–MS) for on- and offline analysis of atmospheric gas and aerosol species J. Krechmer et al. 10.5194/amt-9-3245-2016
- Determination of highly polar compounds in atmospheric aerosol particles at ultra‐trace levels using ion chromatography Orbitrap mass spectrometry C. Kwiezinski et al. 10.1002/jssc.202001048
- Molecular-Level Study of the Photo-Oxidation of Aqueous-Phase Guaiacyl Acetone in the Presence of 3C*: Formation of Brown Carbon Products M. Misovich et al. 10.1021/acsearthspacechem.1c00103
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- Molecular characteristics, sources, and formation pathways of organosulfur compounds in ambient aerosol in Guangzhou, South China H. Jiang et al. 10.5194/acp-22-6919-2022
- Inconsistency of ammonium–sulfate aerosol ratios with thermodynamic models in the eastern US: a possible role of organic aerosol R. Silvern et al. 10.5194/acp-17-5107-2017
- Abundance of organosulfates derived from biogenic volatile organic compounds: Seasonal and spatial contrasts at four sites in China Y. Wang et al. 10.1016/j.scitotenv.2021.151275
- Organosulfate produced from consumption of SO3 speeds up sulfuric acid–dimethylamine atmospheric nucleation X. Zhang et al. 10.5194/acp-24-3593-2024
- OH Group Orientation Leads to Organosulfate Formation at the Liquid Aerosol Surface S. Tan et al. 10.1021/jacs.2c05807
- Molecular Characterization of Organosulfates in Highly Polluted Atmosphere Using Ultra‐High‐Resolution Mass Spectrometry D. Cai et al. 10.1029/2019JD032253
- Comparative Study of Particulate Organosulfates in Contrasting Atmospheric Environments: Field Evidence for the Significant Influence of Anthropogenic Sulfate and NOx Y. Wang et al. 10.1021/acs.estlett.0c00550
- PM2.5 chemistry, organosulfates, and secondary organic aerosol during the 2017 Lake Michigan Ozone Study D. Hughes et al. 10.1016/j.atmosenv.2020.117939
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- Quantifying organic matter and functional groups in particulate matter filter samples from the southeastern United States – Part 1: Methods A. Boris et al. 10.5194/amt-12-5391-2019
- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- Field Evidence for Constraints of Nearly Dry and Weakly Acidic Aerosol Conditions on the Formation of Organosulfates T. Yang et al. 10.1021/acs.estlett.4c00522
- Organosulfates in Atlanta, Georgia: anthropogenic influences on biogenic secondary organic aerosol formation A. Hettiyadura et al. 10.5194/acp-19-3191-2019
- Synthesis, MS/MS characteristics and quantification of six aromatic organosulfates in atmospheric PM2.5 J. He et al. 10.1016/j.atmosenv.2022.119361
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Synthesis of Four Monoterpene-Derived Organosulfates and Their Quantification in Atmospheric Aerosol Samples Y. Wang et al. 10.1021/acs.est.7b01179
- Monoterpene and Sesquiterpene α-Hydroxy Organosulfates: Synthesis, MS/MS Characteristics, and Ambient Presence Y. Wang et al. 10.1021/acs.est.9b04703
- Chemical and optical characterization of aqueous secondary organic aerosol generated by reaction of pyruvaldehyde with sodium sulfite M. Zhu et al. 10.1016/j.apr.2024.102124
- Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS M. Le Breton et al. 10.5194/acp-18-10355-2018
- Heterogeneous Hydroxyl Radical Oxidation of Isoprene-Epoxydiol-Derived Methyltetrol Sulfates: Plausible Formation Mechanisms of Previously Unexplained Organosulfates in Ambient Fine Aerosols Y. Chen et al. 10.1021/acs.estlett.0c00276
- Accurate Computational Model for the Hydration Extent of Atmospherically Relevant Carbonyls on Aqueous Atmospheric Particles M. Elrod et al. 10.1021/acsearthspacechem.0c00322
- Chemical composition, microstructure, and hygroscopic properties of aerosol particles at the Zotino Tall Tower Observatory (ZOTTO), Siberia, during a summer campaign E. Mikhailov et al. 10.5194/acp-15-8847-2015
- Ubiquitous Production of Organosulfates during Treatment of Organic Contaminants with Sulfate Radicals J. Van Buren et al. 10.1021/acs.estlett.1c00316
- Exploring sources of biogenic secondary organic aerosol compounds using chemical analysis and the FLEXPART model J. Martinsson et al. 10.5194/acp-17-11025-2017
- Importance of sulfate radical anion formation and chemistry in heterogeneous OH oxidation of sodium methyl sulfate, the smallest organosulfate K. Kwong et al. 10.5194/acp-18-2809-2018
- Heterogeneous Oxidation Products of Fine Particulate Isoprene Epoxydiol-Derived Methyltetrol Sulfates Increase Oxidative Stress and Inflammatory Gene Responses in Human Lung Cells F. Khan et al. 10.1021/acs.chemrestox.3c00278
- Structural Characterization of Lactone-Containing MW 212 Organosulfates Originating from Isoprene Oxidation in Ambient Fine Aerosol P. Wach et al. 10.1021/acs.est.9b06190
- Isoprene-Derived Organosulfates: Vibrational Mode Analysis by Raman Spectroscopy, Acidity-Dependent Spectral Modes, and Observation in Individual Atmospheric Particles A. Bondy et al. 10.1021/acs.jpca.7b10587
- Stability assessment of organic sulfur and organosulfate compounds in filter samples for quantification by Fourier- transform infrared spectroscopy M. Anunciado et al. 10.5194/amt-16-3515-2023
- Revealing Brown Carbon Chromophores Produced in Reactions of Methylglyoxal with Ammonium Sulfate P. Lin et al. 10.1021/acs.est.5b03608
- General Mechanism for Sulfate Radical Addition to Olefinic Volatile Organic Compounds in Secondary Organic Aerosol H. Ren et al. 10.1021/acs.est.0c05256
- Source apportionment of organic carbon in Centreville, AL using organosulfates in organic tracer-based positive matrix factorization A. Hettiyadura et al. 10.1016/j.atmosenv.2018.05.007
- Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol T. Cui et al. 10.1039/C8EM00308D
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Nontarget Screening Exhibits a Seasonal Cycle of PM2.5 Organic Aerosol Composition in Beijing J. Ma et al. 10.1021/acs.est.1c06905
- Molecular composition of organic aerosols in central Amazonia: an ultra-high-resolution mass spectrometry study I. Kourtchev et al. 10.5194/acp-16-11899-2016
- Important Roles and Formation of Atmospheric Organosulfates in Marine Organic Aerosols: Influence of Phytoplankton Emissions and Anthropogenic Pollutants Y. Wang et al. 10.1021/acs.est.3c01422
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Saved (final revised paper)
Latest update: 13 Dec 2024
Short summary
Organosulfates are SOA products that have proven difficult to quantify. This study addresses the need for authentic quantification standards with a straightforward approach to synthesizing highly pure organosulfate potassium salts. New standards are used to develop a new separation protocol for small, functionalized organosulfates. Upon validation, this method is used to assess sample preparation protocols and to make new measurements of organosulfates in Centreville, Alabama.
Organosulfates are SOA products that have proven difficult to quantify. This study addresses the...
