Articles | Volume 8, issue 6
https://doi.org/10.5194/amt-8-2409-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-2409-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
08 Jun 2015
Research article |
| 08 Jun 2015
Characterisation and optimisation of a sample preparation method for the detection and quantification of atmospherically relevant carbonyl compounds in aqueous medium
M. Rodigast
Leibniz-Institute for Tropospheric Research (TROPOS), Atmospheric Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
A. Mutzel
Leibniz-Institute for Tropospheric Research (TROPOS), Atmospheric Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
Y. Iinuma
Leibniz-Institute for Tropospheric Research (TROPOS), Atmospheric Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
S. Haferkorn
Leibniz-Institute for Tropospheric Research (TROPOS), Atmospheric Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
Leibniz-Institute for Tropospheric Research (TROPOS), Atmospheric Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
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Cited
13 citations as recorded by crossref.
- Molecular Characterization of Atmospheric Organic Aerosol by Mass Spectrometry M. Johnston & D. Kerecman https://doi.org/10.1146/annurev-anchem-061516-045135
- A quantification method for heat-decomposable methylglyoxal oligomers and its application on 1,3,5-trimethylbenzene SOA M. Rodigast et al. https://doi.org/10.5194/acp-17-3929-2017
- Toxicity of Volatile Organic Compounds Produced by Pathogens Ewingella americana and Cedecea neteri Associated with Pleurotus pulmonarius Z. Wei et al. https://doi.org/10.3390/toxins17090449
- An Intensified Acrolein Exposure Can Affect Memory and Cognition in Rat M. Khoramjouy et al. https://doi.org/10.1007/s12640-020-00278-x
- Photochemistry of the sea-surface microlayer (SML) influenced by a phytoplankton bloom: a mesocosm study O. Jibaja Valderrama et al. https://doi.org/10.5194/bg-23-1965-2026
- Aqueous-phase photo-oxidation of selected green leaf volatiles initiated by OH radicals: Products and atmospheric implications K. Sarang et al. https://doi.org/10.1016/j.scitotenv.2023.162622
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. https://doi.org/10.1021/acs.analchem.7b04249
- Analysis of a broad range of volatile organic compounds in environmental air with dual-compartment micropreconcentrators S. Halder et al. https://doi.org/10.1016/j.chroma.2025.466071
- A fast and efficient method for the analysis of α-dicarbonyl compounds in aqueous solutions: Development and application N. Brun et al. https://doi.org/10.1016/j.chemosphere.2023.137977
- A new source of methylglyoxal in the aqueous phase M. Rodigast et al. https://doi.org/10.5194/acp-16-2689-2016
- COMPARISON OF DERIVATIZATION AND SOLID-PHASE MICROEXTRACTION OF A SET OF AROMATIC ALDEHYDES AND DIALDEHYDES FOR GC/FID DETERMINATION IN AQUEOUS SAMPLES A. Mosendz & M. Zui https://doi.org/10.17721/1728-2209.2024.1(59).3
- Compound‐specific carbon isotope compositions of aldehydes and ketones in the Murchison meteorite D. Simkus et al. https://doi.org/10.1111/maps.13202
- Determination of aliphatic aldehydes C1–C5 with headspace solid phase microextraction in tap water: derivatization in-solution versus on-fiber I. Zakharkiv et al. https://doi.org/10.1007/s11696-023-03100-y
13 citations as recorded by crossref.
- Molecular Characterization of Atmospheric Organic Aerosol by Mass Spectrometry M. Johnston & D. Kerecman https://doi.org/10.1146/annurev-anchem-061516-045135
- A quantification method for heat-decomposable methylglyoxal oligomers and its application on 1,3,5-trimethylbenzene SOA M. Rodigast et al. https://doi.org/10.5194/acp-17-3929-2017
- Toxicity of Volatile Organic Compounds Produced by Pathogens Ewingella americana and Cedecea neteri Associated with Pleurotus pulmonarius Z. Wei et al. https://doi.org/10.3390/toxins17090449
- An Intensified Acrolein Exposure Can Affect Memory and Cognition in Rat M. Khoramjouy et al. https://doi.org/10.1007/s12640-020-00278-x
- Photochemistry of the sea-surface microlayer (SML) influenced by a phytoplankton bloom: a mesocosm study O. Jibaja Valderrama et al. https://doi.org/10.5194/bg-23-1965-2026
- Aqueous-phase photo-oxidation of selected green leaf volatiles initiated by OH radicals: Products and atmospheric implications K. Sarang et al. https://doi.org/10.1016/j.scitotenv.2023.162622
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. https://doi.org/10.1021/acs.analchem.7b04249
- Analysis of a broad range of volatile organic compounds in environmental air with dual-compartment micropreconcentrators S. Halder et al. https://doi.org/10.1016/j.chroma.2025.466071
- A fast and efficient method for the analysis of α-dicarbonyl compounds in aqueous solutions: Development and application N. Brun et al. https://doi.org/10.1016/j.chemosphere.2023.137977
- A new source of methylglyoxal in the aqueous phase M. Rodigast et al. https://doi.org/10.5194/acp-16-2689-2016
- COMPARISON OF DERIVATIZATION AND SOLID-PHASE MICROEXTRACTION OF A SET OF AROMATIC ALDEHYDES AND DIALDEHYDES FOR GC/FID DETERMINATION IN AQUEOUS SAMPLES A. Mosendz & M. Zui https://doi.org/10.17721/1728-2209.2024.1(59).3
- Compound‐specific carbon isotope compositions of aldehydes and ketones in the Murchison meteorite D. Simkus et al. https://doi.org/10.1111/maps.13202
- Determination of aliphatic aldehydes C1–C5 with headspace solid phase microextraction in tap water: derivatization in-solution versus on-fiber I. Zakharkiv et al. https://doi.org/10.1007/s11696-023-03100-y
Saved (final revised paper)
Latest update: 06 Jun 2026
Short summary
An optimised method for derivatisation of carbonyl compounds with o-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) in aqueous samples is described. The comprehensive optimisation of the method leads to an improvement of the detection limit up to a factor of 10 highlighting the good sensitivity of the optimised method for atmospherically relevant carbonyl compounds. The optimised method was successfully applied to detect carbonyl compounds from the aqueous phase oxidation of 3-methylbutanone.
An optimised method for derivatisation of carbonyl compounds with...
