Atmospheric Measurement Techniques
Atmospheric Measurement Techniques
AMT
Articles | Volume 8, issue 6
Articles | Volume 8, issue 6
https://doi.org/10.5194/amt-8-2409-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-2409-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
Articles | Volume 8, issue 6
Research article
 | 
08 Jun 2015
Research article |  | 08 Jun 2015

Characterisation and optimisation of a sample preparation method for the detection and quantification of atmospherically relevant carbonyl compounds in aqueous medium

M. Rodigast, A. Mutzel, Y. Iinuma, S. Haferkorn, and H. Herrmann

Viewed

Total article views: 3,515 (including HTML, PDF, and XML)
HTML PDF XML Total Supplement BibTeX EndNote
2,094 1,278 143 3,515 620 153 178
  • HTML: 2,094
  • PDF: 1,278
  • XML: 143
  • Total: 3,515
  • Supplement: 620
  • BibTeX: 153
  • EndNote: 178
Views and downloads (calculated since 23 Jan 2015)
Cumulative views and downloads (calculated since 23 Jan 2015)
Latest update: 24 Nov 2025
Download
Short summary
An optimised method for derivatisation of carbonyl compounds with o-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) in aqueous samples is described. The comprehensive optimisation of the method leads to an improvement of the detection limit up to a factor of 10 highlighting the good sensitivity of the optimised method for atmospherically relevant carbonyl compounds. The optimised method was successfully applied to detect carbonyl compounds from the aqueous phase oxidation of 3-methylbutanone.
Read more
Share