Articles | Volume 8, issue 11
https://doi.org/10.5194/amt-8-4637-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-4637-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
04 Nov 2015
Research article |
| 04 Nov 2015
Real-time monitoring of trace-level VOCs by an ultrasensitive lamp-based VUV photoionization mass spectrometer
W. Q. Sun
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China
J. N. Shu
CORRESPONDING AUTHOR
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China
P. Zhang
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China
Z. Li
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China
N. N. Li
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China
M. Liang
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China
B. Yang
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China
Viewed
Total article views: 3,504 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 15 Jun 2015)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 1,818 | 1,584 | 102 | 3,504 | 86 | 126 |
- HTML: 1,818
- PDF: 1,584
- XML: 102
- Total: 3,504
- BibTeX: 86
- EndNote: 126
Total article views: 2,746 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 04 Nov 2015)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 1,492 | 1,170 | 84 | 2,746 | 78 | 114 |
- HTML: 1,492
- PDF: 1,170
- XML: 84
- Total: 2,746
- BibTeX: 78
- EndNote: 114
Total article views: 758 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 15 Jun 2015)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 326 | 414 | 18 | 758 | 8 | 12 |
- HTML: 326
- PDF: 414
- XML: 18
- Total: 758
- BibTeX: 8
- EndNote: 12
Cited
36 citations as recorded by crossref.
- Pressure-Driven Switching of Photoelectron Impact Ionization-Chemical Ionization/Penning Ionization in Vacuum Ultraviolet Photoionization Mass Spectrometry Y. Yu et al. 10.1021/acs.analchem.4c00686
- Rapid Detection of Potential Natural Food Preservatives and Identification of Artemisia Species via High-Sensitivity Photoionization Mass Spectrometry T. Yang et al. 10.1021/acs.jafc.3c00290
- Photoinduced Associative Ionization Time-of-Flight Mass Spectrometry for the Sensitive Determination of Monoterpenes Z. Zhang et al. 10.1080/00032719.2022.2049284
- Characterization of crucial fragments during the nucleation and growth of secondary organic aerosol from the high-NO photo-oxidation of α-pinene P. Zhang et al. 10.1016/j.atmosenv.2019.05.007
- Simultaneous on-line vacuum single- and multi-photon ionization on an orthogonal acceleration time-of-flight mass spectrometer platform J. Heide et al. 10.1039/D2AN00774F
- Direct detection of acetonitrile at the pptv level with photoinduced associative ionization time-of-flight mass spectrometry K. Jiang et al. 10.1039/D2AY01865A
- Vacuum ultraviolet photoionization on-line mass spectrometry: Instrumentation developments and applications M. Dang et al. 10.1016/j.trac.2022.116542
- A rapid detection method for policy-sensitive amines real-time supervision H. Zhang et al. 10.1016/j.talanta.2017.09.088
- Radiofrequency field enhanced chemical ionization with vacuum ultraviolet lamp for miniature time-of-flight mass spectrometer L. Zhou et al. 10.1016/j.cclet.2017.11.021
- Protonation enhancement by dichloromethane doping in low-pressure photoionization J. Shu et al. 10.1038/srep36820
- Rapid detection of taste and odor compounds in water using the newly invented chemi-ionization technique coupled with time-of-flight mass spectrometry H. Zhang et al. 10.1016/j.aca.2018.07.051
- Detection of sub-pptv benzene, toluene, and ethylbenzene via low-pressure photoionization mass spectrometry Z. Li et al. 10.1016/j.aca.2017.01.065
- Online monitoring of trace chlorinated benzenes in flue gas of municipal solid waste incinerator by windowless VUV lamp single photon ionization TOFMS coupled with automatic enrichment system W. Liu et al. 10.1016/j.talanta.2016.09.026
- A Simple High-Flux Switchable VUV Lamp Based on an Electrodeless Fluorescent Lamp for SPI/PAI Mass Spectrometry Z. Yan et al. 10.1021/acs.analchem.3c01021
- Application of Vacuum Ultraviolet Single-photon Ionization Mass Spectrometer in Online Analysis of Volatile Organic Compounds W. SUN et al. 10.1016/S1872-2040(19)61170-9
- Ultrasensitive detection of explosives and chemical warfare agents by low-pressure photoionization mass spectrometry W. Sun et al. 10.1016/j.talanta.2016.05.025
- Kinetic Understanding of the Ultrahigh Ionization Efficiencies (up to 28%) of Excited-State CH2Cl2-Induced Associative Ionization: A Case Study with Nitro Compounds J. Huang et al. 10.1021/acs.analchem.8b04813
- Aerosol mass spectrometry of neutral species based on a tunable vacuum ultraviolet free electron laser X. Zang et al. 10.1039/D2CP01733D
- Doping-assisted low-pressure photoionization mass spectrometry for the real-time detection of lung cancer-related volatile organic compounds Z. Li et al. 10.1016/j.talanta.2016.12.039
- Characterization of trace aerosol compositions produced during the OH radical-initiated photooxidation of β-pinene P. Zhang et al. 10.1016/j.atmosenv.2019.04.060
- Simulation of Light Intensity of VUV Lamp Based on Inductively Coupled Plasma Discharge in Low-pressure Kr-He Mixture Z. Yan et al. 10.1007/s11090-023-10386-z
- Characterization of secondary organic aerosol from photo-oxidation of gasoline exhaust and specific sources of major components P. Ma et al. 10.1016/j.envpol.2017.09.018
- Comparison of secondary organic aerosol (SOA) formation during o-, m-, and p-xylene photooxidation P. Zhang et al. 10.1016/j.envpol.2018.10.118
- Vacuum-Ultraviolet-Excited and CH2Cl2/H2O-Amplified Ionization-Coupled Mass Spectrometry for Oxygenated Organics Analysis B. Yang et al. 10.1021/acs.analchem.7b04122
- Ultrasensitive detection of volatile aldehydes with chemi-ionization-coupled time-of-flight mass spectrometry B. Yang et al. 10.1016/j.talanta.2018.11.004
- Ultrasensitive detection of trace chemical warfare agent-related compounds by thermal desorption associative ionization time-of-flight mass spectrometry J. Huang et al. 10.1016/j.talanta.2021.122788
- Online analysis of gas-phase radical reactions using vacuum ultraviolet lamp photoionization and time-of-flight mass spectrometry Z. Wen et al. 10.1063/1.5135387
- VOC Monitoring and Ozone Generation Potential Analysis Based on a Single-Photon Ionization Time-of-Flight Mass Spectrometer Y. Zhao et al. 10.3390/photonics7030061
- An ultrasensitive SPI/PAI ion source based on a high-flux VUV lamp and its applications for the online mass spectrometric detection of sub-pptv sulfur ethers Y. Guo et al. 10.1016/j.talanta.2022.123558
- Insight into the crucial reason causing the difference in secondary organic aerosol yields of monocyclic aromatic hydrocarbons with different methyl substituent numbers Z. Yu et al. 10.1016/j.scitotenv.2023.166353
- Single photon ionization time-of-flight mass spectrometry with a windowless RF-discharge lamp for high temporal resolution monitoring of the initial stage of methanol-to-olefins reaction Q. Li et al. 10.1039/C8AN01840E
- Formation mechanism of secondary organic aerosol from ozonolysis of gasoline vehicle exhaust B. Yang et al. 10.1016/j.envpol.2017.12.048
- Gas-Phase Reactions of Methoxyphenols with NO3 Radicals: Kinetics, Products, and Mechanisms H. Zhang et al. 10.1021/acs.jpca.5b10406
- Real-time ultrasensitive VUV-PIMS detection of representative endogenous volatile markers in cancers Z. Li et al. 10.3233/CBM-160587
- Research and Application of Mass Spectrometry with Low Energy Electron Impact Ionization Source G. LIU et al. 10.1016/S1872-2040(19)61159-X
- Application of VUV-PIMS coupled with GC-MS in chemical characterization, identification and comparative analysis of organic components in both vehicular-derived SOA and haze particles P. Zhang et al. 10.1016/j.atmosenv.2017.06.013
31 citations as recorded by crossref.
- Pressure-Driven Switching of Photoelectron Impact Ionization-Chemical Ionization/Penning Ionization in Vacuum Ultraviolet Photoionization Mass Spectrometry Y. Yu et al. 10.1021/acs.analchem.4c00686
- Rapid Detection of Potential Natural Food Preservatives and Identification of Artemisia Species via High-Sensitivity Photoionization Mass Spectrometry T. Yang et al. 10.1021/acs.jafc.3c00290
- Photoinduced Associative Ionization Time-of-Flight Mass Spectrometry for the Sensitive Determination of Monoterpenes Z. Zhang et al. 10.1080/00032719.2022.2049284
- Characterization of crucial fragments during the nucleation and growth of secondary organic aerosol from the high-NO photo-oxidation of α-pinene P. Zhang et al. 10.1016/j.atmosenv.2019.05.007
- Simultaneous on-line vacuum single- and multi-photon ionization on an orthogonal acceleration time-of-flight mass spectrometer platform J. Heide et al. 10.1039/D2AN00774F
- Direct detection of acetonitrile at the pptv level with photoinduced associative ionization time-of-flight mass spectrometry K. Jiang et al. 10.1039/D2AY01865A
- Vacuum ultraviolet photoionization on-line mass spectrometry: Instrumentation developments and applications M. Dang et al. 10.1016/j.trac.2022.116542
- A rapid detection method for policy-sensitive amines real-time supervision H. Zhang et al. 10.1016/j.talanta.2017.09.088
- Radiofrequency field enhanced chemical ionization with vacuum ultraviolet lamp for miniature time-of-flight mass spectrometer L. Zhou et al. 10.1016/j.cclet.2017.11.021
- Protonation enhancement by dichloromethane doping in low-pressure photoionization J. Shu et al. 10.1038/srep36820
- Rapid detection of taste and odor compounds in water using the newly invented chemi-ionization technique coupled with time-of-flight mass spectrometry H. Zhang et al. 10.1016/j.aca.2018.07.051
- Detection of sub-pptv benzene, toluene, and ethylbenzene via low-pressure photoionization mass spectrometry Z. Li et al. 10.1016/j.aca.2017.01.065
- Online monitoring of trace chlorinated benzenes in flue gas of municipal solid waste incinerator by windowless VUV lamp single photon ionization TOFMS coupled with automatic enrichment system W. Liu et al. 10.1016/j.talanta.2016.09.026
- A Simple High-Flux Switchable VUV Lamp Based on an Electrodeless Fluorescent Lamp for SPI/PAI Mass Spectrometry Z. Yan et al. 10.1021/acs.analchem.3c01021
- Application of Vacuum Ultraviolet Single-photon Ionization Mass Spectrometer in Online Analysis of Volatile Organic Compounds W. SUN et al. 10.1016/S1872-2040(19)61170-9
- Ultrasensitive detection of explosives and chemical warfare agents by low-pressure photoionization mass spectrometry W. Sun et al. 10.1016/j.talanta.2016.05.025
- Kinetic Understanding of the Ultrahigh Ionization Efficiencies (up to 28%) of Excited-State CH2Cl2-Induced Associative Ionization: A Case Study with Nitro Compounds J. Huang et al. 10.1021/acs.analchem.8b04813
- Aerosol mass spectrometry of neutral species based on a tunable vacuum ultraviolet free electron laser X. Zang et al. 10.1039/D2CP01733D
- Doping-assisted low-pressure photoionization mass spectrometry for the real-time detection of lung cancer-related volatile organic compounds Z. Li et al. 10.1016/j.talanta.2016.12.039
- Characterization of trace aerosol compositions produced during the OH radical-initiated photooxidation of β-pinene P. Zhang et al. 10.1016/j.atmosenv.2019.04.060
- Simulation of Light Intensity of VUV Lamp Based on Inductively Coupled Plasma Discharge in Low-pressure Kr-He Mixture Z. Yan et al. 10.1007/s11090-023-10386-z
- Characterization of secondary organic aerosol from photo-oxidation of gasoline exhaust and specific sources of major components P. Ma et al. 10.1016/j.envpol.2017.09.018
- Comparison of secondary organic aerosol (SOA) formation during o-, m-, and p-xylene photooxidation P. Zhang et al. 10.1016/j.envpol.2018.10.118
- Vacuum-Ultraviolet-Excited and CH2Cl2/H2O-Amplified Ionization-Coupled Mass Spectrometry for Oxygenated Organics Analysis B. Yang et al. 10.1021/acs.analchem.7b04122
- Ultrasensitive detection of volatile aldehydes with chemi-ionization-coupled time-of-flight mass spectrometry B. Yang et al. 10.1016/j.talanta.2018.11.004
- Ultrasensitive detection of trace chemical warfare agent-related compounds by thermal desorption associative ionization time-of-flight mass spectrometry J. Huang et al. 10.1016/j.talanta.2021.122788
- Online analysis of gas-phase radical reactions using vacuum ultraviolet lamp photoionization and time-of-flight mass spectrometry Z. Wen et al. 10.1063/1.5135387
- VOC Monitoring and Ozone Generation Potential Analysis Based on a Single-Photon Ionization Time-of-Flight Mass Spectrometer Y. Zhao et al. 10.3390/photonics7030061
- An ultrasensitive SPI/PAI ion source based on a high-flux VUV lamp and its applications for the online mass spectrometric detection of sub-pptv sulfur ethers Y. Guo et al. 10.1016/j.talanta.2022.123558
- Insight into the crucial reason causing the difference in secondary organic aerosol yields of monocyclic aromatic hydrocarbons with different methyl substituent numbers Z. Yu et al. 10.1016/j.scitotenv.2023.166353
- Single photon ionization time-of-flight mass spectrometry with a windowless RF-discharge lamp for high temporal resolution monitoring of the initial stage of methanol-to-olefins reaction Q. Li et al. 10.1039/C8AN01840E
5 citations as recorded by crossref.
- Formation mechanism of secondary organic aerosol from ozonolysis of gasoline vehicle exhaust B. Yang et al. 10.1016/j.envpol.2017.12.048
- Gas-Phase Reactions of Methoxyphenols with NO3 Radicals: Kinetics, Products, and Mechanisms H. Zhang et al. 10.1021/acs.jpca.5b10406
- Real-time ultrasensitive VUV-PIMS detection of representative endogenous volatile markers in cancers Z. Li et al. 10.3233/CBM-160587
- Research and Application of Mass Spectrometry with Low Energy Electron Impact Ionization Source G. LIU et al. 10.1016/S1872-2040(19)61159-X
- Application of VUV-PIMS coupled with GC-MS in chemical characterization, identification and comparative analysis of organic components in both vehicular-derived SOA and haze particles P. Zhang et al. 10.1016/j.atmosenv.2017.06.013
Saved (final revised paper)
Latest update: 13 Dec 2024
Short summary
A novel ultrasensitive VUV photoionization mass spectrometer is developed to monitor trace-level VOCs in real time. By employing a light baffle in the photoionizer, the background noise is efficiently suppressed and the detection limit reaches to a low pptv level. Continuous monitoring of VOCs in urban air demonstrates the strength of this instrument. This study reveals that the new technique may have the capability of ranking with the PTR-MS for field measurements.
A novel ultrasensitive VUV photoionization mass spectrometer is developed to monitor trace-level...
