Articles | Volume 9, issue 4
https://doi.org/10.5194/amt-9-1473-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-1473-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds
Michelle J. Kim
Scripps Institution of Oceanography, University of
California San Diego, La Jolla, CA, USA
now at: Division of Geological and Planetary Sciences,
California Institute of Technology, Pasadena, CA, USA
Matthew C. Zoerb
Department of Chemistry and Biochemistry, University of
California San Diego, La Jolla, CA, USA
now at: Department of Chemistry and Biochemistry, California Polytechnic State University, San Luis Obispo, CA,
USA
Nicole R. Campbell
Department of Chemistry and Biochemistry, University of
California San Diego, La Jolla, CA, USA
Kathryn J. Zimmermann
Department of Chemistry and Biochemistry, University of
California San Diego, La Jolla, CA, USA
now at: School of Science and Technology, Georgia Gwinnett
College, Lawrenceville, GA, USA
Byron W. Blomquist
University of Colorado, Cooperative Institute for Research
in Environmental Sciences, Boulder, CO, USA
Barry J. Huebert
School of Oceanography and Earth Sciences and Technology,
University of Hawaii, Manoa, Honolulu, HI, USA
Timothy H. Bertram
CORRESPONDING AUTHOR
Department of Chemistry and Biochemistry, University of
California San Diego, La Jolla, CA, USA
now at: Department of Chemistry, University of
Wisconsin-Madison, Madison, WI, USA
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Latest update: 21 Nov 2024
Short summary
Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory and field measurements were used to assess the sensitivity of the ionization scheme under a wide array of operating condition. Underway measurements of DMS in the North Atlantic were validated against an atmospheric pressure ionization mass spectrometer.
Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical...