Atmospheric Measurement Techniques
Atmospheric Measurement Techniques
AMT
Articles | Volume 9, issue 4
Articles | Volume 9, issue 4
https://doi.org/10.5194/amt-9-1473-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-1473-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Articles | Volume 9, issue 4
Research article
 | 
05 Apr 2016
Research article |  | 05 Apr 2016

Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds

Michelle J. Kim, Matthew C. Zoerb, Nicole R. Campbell, Kathryn J. Zimmermann, Byron W. Blomquist, Barry J. Huebert, and Timothy H. Bertram

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Short summary
Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory and field measurements were used to assess the sensitivity of the ionization scheme under a wide array of operating condition. Underway measurements of DMS in the North Atlantic were validated against an atmospheric pressure ionization mass spectrometer.
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