Articles | Volume 9, issue 4
https://doi.org/10.5194/amt-9-1505-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-1505-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Constraining the sensitivity of iodide adduct chemical ionization mass spectrometry to multifunctional organic molecules using the collision limit and thermodynamic stability of iodide ion adducts
Felipe D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington,
Seattle, 98195 WA, USA
Siddarth Iyer
Department of Chemistry, University of Helsinki, Helsinki, Finland
Claudia Mohr
Department of Atmospheric Sciences, University of Washington,
Seattle, 98195 WA, USA
Ben H. Lee
Department of Atmospheric Sciences, University of Washington,
Seattle, 98195 WA, USA
Emma L. D'Ambro
Department of Atmospheric Sciences, University of Washington,
Seattle, 98195 WA, USA
Department of Chemistry, University of Washington, Seattle, 98195 WA,
USA
Theo Kurtén
Department of Chemistry, University of Helsinki, Helsinki, Finland
Joel A. Thornton
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington,
Seattle, 98195 WA, USA
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Latest update: 13 Dec 2024
Short summary
We present the maximum sensitivity of a TOF-CIMS using the collision limit and iodide adducts. We also present an ion adduct declustering scanning procedure which determines the effective binding energies of the detected ion adducts and therefore their approximate sensitivity. The combination of declustering scanning and the collision limit provides an approximate calibration for many compounds in the mass spectrum which would otherwise be impossible to obtain by traditional methods.
We present the maximum sensitivity of a TOF-CIMS using the collision limit and iodide adducts....