Articles | Volume 9, issue 7
https://doi.org/10.5194/amt-9-2909-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-2909-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
08 Jul 2016
Research article |
| 08 Jul 2016
Evaluation of NO+ reagent ion chemistry for online measurements of atmospheric volatile organic compounds
Abigail R. Koss
CORRESPONDING AUTHOR
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado at Boulder, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado at Boulder, CO, USA
Carsten Warneke
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado at Boulder, Boulder, CO, USA
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado at Boulder, Boulder, CO, USA
Matthew M. Coggon
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado at Boulder, Boulder, CO, USA
Patrick R. Veres
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado at Boulder, Boulder, CO, USA
Joost A. de Gouw
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado at Boulder, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado at Boulder, CO, USA
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Cited
48 citations as recorded by crossref.
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- Fugitive Emissions of Volatile Organic Compounds from a Tailings Pond in the Oil Sands Region of Alberta S. Moussa et al. 10.1021/acs.est.1c02325
- Online measurements of cycloalkanes based on NO+ chemical ionization in proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) Y. Chen et al. 10.5194/amt-15-6935-2022
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- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- Emission characteristics of reactive organic gases (ROGs) from industrial volatile chemical products (VCPs) in the Pearl River Delta (PRD), China S. Wang et al. 10.5194/acp-24-7101-2024
- Nonuniform Electric Field-Enhanced In-Source Declustering in High-Pressure Photoionization/Photoionization-Induced Chemical Ionization Mass Spectrometry for Operando Catalytic Reaction Monitoring N. Wan et al. 10.1021/acs.analchem.0c04081
- New Insights into the Radical Chemistry and Product Distribution in the OH-Initiated Oxidation of Benzene L. Xu et al. 10.1021/acs.est.0c04780
- Empirical Approach to Quantifying Sensitivity in Different Chemical Ionization Techniques for Organonitrates and Nitroaromatics Constrained by Ion–Molecule Reaction and Transmission Efficiency S. He et al. 10.1021/acs.analchem.4c03751
- Integrating density functional theory and chemical ionization mass spectrometry techniques to assess benzophenone derivatives in food packaging: implications for enhancing food quality and safety M. Bhatia 10.1002/jms.5011
- Calculation of the sensitivity of proton-transfer-reaction mass spectrometry (PTR-MS) for organic trace gases using molecular properties K. Sekimoto et al. 10.1016/j.ijms.2017.04.006
- Measurement report: Underestimated reactive organic gases from residential combustion – insights from a near-complete speciation Y. Gao et al. 10.5194/acp-23-6633-2023
- Temperature-dependent sensitivity of iodide chemical ionization mass spectrometers M. Robinson et al. 10.5194/amt-15-4295-2022
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Theoretical Investigation of Charge Transfer from NO+ and O2+ Ions to Wine-Related Volatile Compounds for Mass Spectrometry M. Bhatia et al. 10.1021/jasms.1c00253
- Rapid Identification of Atmospheric Gaseous Pollutants Using Fourier-Transform Infrared Spectroscopy Combined with Independent Component Analysis W. Ju et al. 10.1155/2020/8920732
- Chemical Ionization of Large Linear Alkanes and Small Oxidized Volatile Organic Compounds by the Reactions with Atomic Gold Cations T. Zhang et al. 10.1021/acs.analchem.7b01791
- Atmospheric oxidation of C10~14 n-alkanes initiated by Cl atoms: Kinetics and mechanism B. Shi et al. 10.1016/j.atmosenv.2019.117166
- Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization A. Ringsdorf et al. 10.5194/acp-24-11883-2024
- A detailed study of the ion chemistry of alkenes focusing on heptenes aimed at their SIFT-MS quantification R. Brůhová Michalčíková et al. 10.1016/j.ijms.2017.12.004
- Measurements of higher alkanes using NO<sup>+</sup> chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China C. Wang et al. 10.5194/acp-20-14123-2020
- Calculated rate coefficients between CI-MS reagent ions and organosulfur compounds causing food taints and off-flavours M. Bhatia et al. 10.1016/j.ijms.2022.116860
- Photoionization-induced NO+ chemical ionization time-of-flight mass spectrometry for rapid measurement of aldehydes and benzenes in vehicles H. Li et al. 10.1016/j.talanta.2021.122722
- Increase of the Charge Transfer Rate Coefficients for NO+ and O2+• Reactions with Isoprene Molecules at Elevated Interaction Energies A. Spesyvyi et al. 10.1021/acs.jpca.8b08580
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- CF3+and CF2H+: new reagents for n-alkane determination in chemical ionisation reaction mass spectrometry R. Blake et al. 10.1039/C6AN02118B
- Coupling a gas chromatograph simultaneously to a flame ionization detector and chemical ionization mass spectrometer for isomer-resolved measurements of particle-phase organic compounds C. Bi et al. 10.5194/amt-14-3895-2021
- A review of microbial and chemical assessment of indoor surfaces V. Mihucz et al. 10.1080/05704928.2021.1995870
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
- Modern mass spectrometry in atmospheric sciences: Measurement of volatile organic compounds in the troposphere using proton‐transfer‐reaction mass spectrometry K. Sekimoto & A. Koss 10.1002/jms.4619
- Volatile organic compound emissions from solvent- and water-borne coatings – compositional differences and tracer compound identifications C. Stockwell et al. 10.5194/acp-21-6005-2021
- Quantification of isomer-resolved iodide chemical ionization mass spectrometry sensitivity and uncertainty using a voltage-scanning approach C. Bi et al. 10.5194/amt-14-6835-2021
- Pitfalls in the Detection of Volatiles Associated with Heated Tobacco and e-Vapor Products When Using PTR-TOF-MS N. Bielik et al. 10.1021/jasms.4c00062
- Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment A. Koss et al. 10.5194/acp-18-3299-2018
- Reactions of C12–C14 n-Alkylcyclohexanes with Cl Atoms: Kinetics and Secondary Organic Aerosol Formation K. Wang et al. 10.1021/acs.est.1c08958
- Real-Time Measurements of Evaporative Emissions from Gasoline Cars by NO<sup>+</sup> Chemical Ionization Mass Spectrometry S. Inomata et al. 10.5702/massspec.S18-22
- Kinetics and mechanisms of the gas-phase reactions of OH radicals with three C15 alkanes B. Shi et al. 10.1016/j.atmosenv.2019.03.028
- Rapid screening of volatile chemicals in surface water samples from the East Palestine, Ohio chemical disaster site with proton transfer reaction mass spectrometry J. Jiang et al. 10.1016/j.scitotenv.2024.176056
- Exploration of the utility of CF3+ as a reagent for chemical ionisation reaction mass spectrometry R. Blake et al. 10.1016/j.ijms.2017.07.012
- Characteristic wavelength selection of volatile organic compounds infrared spectra based on improved interval partial least squares W. Ju et al. 10.1142/S1793545819500056
- Temperature effects on optical properties and chemical composition of secondary organic aerosol derived from <i>n</i>-dodecane J. Li et al. 10.5194/acp-20-8123-2020
- Sensitive detection of <i>n</i>-alkanes using a mixed ionization mode proton-transfer-reaction mass spectrometer O. Amador-Muñoz et al. 10.5194/amt-9-5315-2016
- The potential of NO+ and O2+• in switchable reagent ion proton transfer reaction time‐of‐flight mass spectrometry O. Hegen et al. 10.1002/mas.21770
- A method for the identification of COVID-19 biomarkers in human breath using Proton Transfer Reaction Time-of-Flight Mass Spectrometry A. Liangou et al. 10.1016/j.eclinm.2021.101207
48 citations as recorded by crossref.
- Volatile Organic Compound Emissions from Humans Indoors X. Tang et al. 10.1021/acs.est.6b04415
- The sensitivity of benzene cluster cation chemical ionization mass spectrometry to select biogenic terpenes A. Lavi et al. 10.5194/amt-11-3251-2018
- Identification and quantification of VOCs by proton transfer reaction time of flight mass spectrometry: An experimental workflow for the optimization of specificity, sensitivity, and accuracy A. Romano & G. Hanna 10.1002/jms.4063
- Measuring Photodissociation Product Quantum Yields Using Chemical Ionization Mass Spectrometry: A Case Study with Ketones M. Link et al. 10.1021/acs.jpca.1c03140
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Fugitive Emissions of Volatile Organic Compounds from a Tailings Pond in the Oil Sands Region of Alberta S. Moussa et al. 10.1021/acs.est.1c02325
- Online measurements of cycloalkanes based on NO+ chemical ionization in proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) Y. Chen et al. 10.5194/amt-15-6935-2022
- Monitoring techniques of airborne carbonyl compounds: Principles, performance and challenges Y. Xu et al. 10.1016/j.trac.2023.117395
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- Emission characteristics of reactive organic gases (ROGs) from industrial volatile chemical products (VCPs) in the Pearl River Delta (PRD), China S. Wang et al. 10.5194/acp-24-7101-2024
- Nonuniform Electric Field-Enhanced In-Source Declustering in High-Pressure Photoionization/Photoionization-Induced Chemical Ionization Mass Spectrometry for Operando Catalytic Reaction Monitoring N. Wan et al. 10.1021/acs.analchem.0c04081
- New Insights into the Radical Chemistry and Product Distribution in the OH-Initiated Oxidation of Benzene L. Xu et al. 10.1021/acs.est.0c04780
- Empirical Approach to Quantifying Sensitivity in Different Chemical Ionization Techniques for Organonitrates and Nitroaromatics Constrained by Ion–Molecule Reaction and Transmission Efficiency S. He et al. 10.1021/acs.analchem.4c03751
- Integrating density functional theory and chemical ionization mass spectrometry techniques to assess benzophenone derivatives in food packaging: implications for enhancing food quality and safety M. Bhatia 10.1002/jms.5011
- Calculation of the sensitivity of proton-transfer-reaction mass spectrometry (PTR-MS) for organic trace gases using molecular properties K. Sekimoto et al. 10.1016/j.ijms.2017.04.006
- Measurement report: Underestimated reactive organic gases from residential combustion – insights from a near-complete speciation Y. Gao et al. 10.5194/acp-23-6633-2023
- Temperature-dependent sensitivity of iodide chemical ionization mass spectrometers M. Robinson et al. 10.5194/amt-15-4295-2022
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Theoretical Investigation of Charge Transfer from NO+ and O2+ Ions to Wine-Related Volatile Compounds for Mass Spectrometry M. Bhatia et al. 10.1021/jasms.1c00253
- Rapid Identification of Atmospheric Gaseous Pollutants Using Fourier-Transform Infrared Spectroscopy Combined with Independent Component Analysis W. Ju et al. 10.1155/2020/8920732
- Chemical Ionization of Large Linear Alkanes and Small Oxidized Volatile Organic Compounds by the Reactions with Atomic Gold Cations T. Zhang et al. 10.1021/acs.analchem.7b01791
- Atmospheric oxidation of C10~14 n-alkanes initiated by Cl atoms: Kinetics and mechanism B. Shi et al. 10.1016/j.atmosenv.2019.117166
- Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization A. Ringsdorf et al. 10.5194/acp-24-11883-2024
- A detailed study of the ion chemistry of alkenes focusing on heptenes aimed at their SIFT-MS quantification R. Brůhová Michalčíková et al. 10.1016/j.ijms.2017.12.004
- Measurements of higher alkanes using NO<sup>+</sup> chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China C. Wang et al. 10.5194/acp-20-14123-2020
- Calculated rate coefficients between CI-MS reagent ions and organosulfur compounds causing food taints and off-flavours M. Bhatia et al. 10.1016/j.ijms.2022.116860
- Photoionization-induced NO+ chemical ionization time-of-flight mass spectrometry for rapid measurement of aldehydes and benzenes in vehicles H. Li et al. 10.1016/j.talanta.2021.122722
- Increase of the Charge Transfer Rate Coefficients for NO+ and O2+• Reactions with Isoprene Molecules at Elevated Interaction Energies A. Spesyvyi et al. 10.1021/acs.jpca.8b08580
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- CF3+and CF2H+: new reagents for n-alkane determination in chemical ionisation reaction mass spectrometry R. Blake et al. 10.1039/C6AN02118B
- Coupling a gas chromatograph simultaneously to a flame ionization detector and chemical ionization mass spectrometer for isomer-resolved measurements of particle-phase organic compounds C. Bi et al. 10.5194/amt-14-3895-2021
- A review of microbial and chemical assessment of indoor surfaces V. Mihucz et al. 10.1080/05704928.2021.1995870
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
- Modern mass spectrometry in atmospheric sciences: Measurement of volatile organic compounds in the troposphere using proton‐transfer‐reaction mass spectrometry K. Sekimoto & A. Koss 10.1002/jms.4619
- Volatile organic compound emissions from solvent- and water-borne coatings – compositional differences and tracer compound identifications C. Stockwell et al. 10.5194/acp-21-6005-2021
- Quantification of isomer-resolved iodide chemical ionization mass spectrometry sensitivity and uncertainty using a voltage-scanning approach C. Bi et al. 10.5194/amt-14-6835-2021
- Pitfalls in the Detection of Volatiles Associated with Heated Tobacco and e-Vapor Products When Using PTR-TOF-MS N. Bielik et al. 10.1021/jasms.4c00062
- Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment A. Koss et al. 10.5194/acp-18-3299-2018
- Reactions of C12–C14 n-Alkylcyclohexanes with Cl Atoms: Kinetics and Secondary Organic Aerosol Formation K. Wang et al. 10.1021/acs.est.1c08958
- Real-Time Measurements of Evaporative Emissions from Gasoline Cars by NO<sup>+</sup> Chemical Ionization Mass Spectrometry S. Inomata et al. 10.5702/massspec.S18-22
- Kinetics and mechanisms of the gas-phase reactions of OH radicals with three C15 alkanes B. Shi et al. 10.1016/j.atmosenv.2019.03.028
- Rapid screening of volatile chemicals in surface water samples from the East Palestine, Ohio chemical disaster site with proton transfer reaction mass spectrometry J. Jiang et al. 10.1016/j.scitotenv.2024.176056
- Exploration of the utility of CF3+ as a reagent for chemical ionisation reaction mass spectrometry R. Blake et al. 10.1016/j.ijms.2017.07.012
- Characteristic wavelength selection of volatile organic compounds infrared spectra based on improved interval partial least squares W. Ju et al. 10.1142/S1793545819500056
- Temperature effects on optical properties and chemical composition of secondary organic aerosol derived from <i>n</i>-dodecane J. Li et al. 10.5194/acp-20-8123-2020
- Sensitive detection of <i>n</i>-alkanes using a mixed ionization mode proton-transfer-reaction mass spectrometer O. Amador-Muñoz et al. 10.5194/amt-9-5315-2016
- The potential of NO+ and O2+• in switchable reagent ion proton transfer reaction time‐of‐flight mass spectrometry O. Hegen et al. 10.1002/mas.21770
- A method for the identification of COVID-19 biomarkers in human breath using Proton Transfer Reaction Time-of-Flight Mass Spectrometry A. Liangou et al. 10.1016/j.eclinm.2021.101207
Discussed (preprint)
Latest update: 14 Dec 2024
Short summary
Using laboratory and field experiments, we have explored how the technique of NO+ chemical ionization mass spectrometry can be used to measure volatile organic compounds (VOCs) in the troposphere. Results include the design and operation of the instrument, an evaluation of the technique’s utility for atmospheric measurement, and a guide for data interpretation. Use of this technique will improve our understanding of VOC chemistry.
Using laboratory and field experiments, we have explored how the technique of NO+ chemical...
