Articles | Volume 9, issue 8
https://doi.org/10.5194/amt-9-3717-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-3717-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
12 Aug 2016
Research article |
| 12 Aug 2016
Development and evaluation of a suite of isotope reference gases for methane in air
Max Planck Institute for Biogeochemistry (MPI-BGC), Jena, Germany
National Institute of Water and Atmospheric Research (NIWA),
Wellington, New Zealand
Nelly A. M. Uitslag
Max Planck Institute for Biogeochemistry (MPI-BGC), Jena, Germany
Centre for Isotope Research (CIO), Energy
and Sustainability Research Institute Groningen (ESRIG),
University of Groningen, Groningen, the Netherlands
Jürgen M. Richter
Max Planck Institute for Biogeochemistry (MPI-BGC), Jena, Germany
Michael Rothe
Max Planck Institute for Biogeochemistry (MPI-BGC), Jena, Germany
Heike Geilmann
Max Planck Institute for Biogeochemistry (MPI-BGC), Jena, Germany
Carina van der Veen
Institute of
Marine and Atmospheric Science in Utrecht (IMAU), Utrecht, the Netherlands
Thomas Röckmann
Institute of
Marine and Atmospheric Science in Utrecht (IMAU), Utrecht, the Netherlands
Thomas Blunier
Centre for Ice and Climate (CIC), Niels Bohr Institute, University
of Copenhagen, Copenhagen, Denmark
Willi A. Brand
Max Planck Institute for Biogeochemistry (MPI-BGC), Jena, Germany
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- In situ observations of greenhouse gases over Europe during the CoMet 1.0 campaign aboard the HALO aircraft M. Gałkowski et al. 10.5194/amt-14-1525-2021
- Frequency modulation laser spectroscopy method for methane isotopologue ratio and total concentration measurements at 1661 nm E. Curtis et al. 10.1364/JOSAB.482727
- Can we separate industrial CH4 emission sources from atmospheric observations? - A test case for carbon isotopes, PMF and enhanced APCA S. Assan et al. 10.1016/j.atmosenv.2018.05.004
- Characterisation of methane sources in Lutjewad, The Netherlands, using quasi-continuous isotopic composition measurements M. Menoud et al. 10.1080/16000889.2020.1823733
- Interlaboratory comparison of <i>δ</i><sup>13</sup>C and <i>δ</i>D measurements of atmospheric CH<sub>4</sub> for combined use of data sets from different laboratories T. Umezawa et al. 10.5194/amt-11-1207-2018
- An improved method for mobile characterisation of <i>δ</i><sup>13</sup>CH<sub>4</sub> source signatures and its application in Germany A. Hoheisel et al. 10.5194/amt-12-1123-2019
- Street-level methane emissions of Bucharest, Romania and the dominance of urban wastewater. J. Fernandez et al. 10.1016/j.aeaoa.2022.100153
- Methane (CH<sub>4</sub>) sources in Krakow, Poland: insights from isotope analysis M. Menoud et al. 10.5194/acp-21-13167-2021
- In situ observations of the isotopic composition of methane at the Cabauw tall tower site T. Röckmann et al. 10.5194/acp-16-10469-2016
- A Cryogen-Free Automated Measurement System of Stable Carbon Isotope Ratio of Atmospheric Methane T. Umezawa et al. 10.2151/jmsj.2020-007
- Advancing Scientific Understanding of the Global Methane Budget in Support of the Paris Agreement A. Ganesan et al. 10.1029/2018GB006065
- Determining Biogenic Content of Biogas by Measuring Stable Isotopologues 12CH4, 13CH4, and CH3D with a Mid-Infrared Direct Absorption Laser Spectrometer T. Kääriäinen et al. 10.3390/s18020496
- USGS44, a new high‐purity calcium carbonate reference material for δ13C measurements H. Qi et al. 10.1002/rcm.9006
- Advances in reference materials and measurement techniques for greenhouse gas atmospheric observations P. Brewer et al. 10.1088/1681-7575/ab1506
- Cold-Weld Sealing in Argon Atmosphere for High Precision Carbon Isotope Analysis of Co-Processed Biofuels Using a Continuous-Flow Isotope Ratio Mass Spectrometer T. Geeza et al. 10.1021/acs.energyfuels.0c02114
- Source apportionment of methane emissions from the Upper Silesian Coal Basin using isotopic signatures A. Fiehn et al. 10.5194/acp-23-15749-2023
- Six years of continuous carbon isotope composition measurements of methane in Heidelberg (Germany) – a study of source contributions and comparison to emission inventories A. Hoheisel & M. Schmidt 10.5194/acp-24-2951-2024
- CH4 isotopic signatures of emissions from oil and gas extraction sites in Romania M. Menoud et al. 10.1525/elementa.2021.00092
- A robust method for direct calibration of isotope ratios in gases against liquid/solid reference materials, including a laboratory comparison for δ13C‐CH4 P. Sperlich et al. 10.1002/rcm.8944
- Methane mapping, emission quantification, and attribution in two European cities: Utrecht (NL) and Hamburg (DE) H. Maazallahi et al. 10.5194/acp-20-14717-2020
- Atomic spectrometry update – a review of advances in environmental analysis O. Butler et al. 10.1039/C7JA90059G
- Source partitioning of atmospheric methane using stable carbon isotope measurements in the Reuss Valley, Switzerland J. Stieger et al. 10.1080/10256016.2018.1561448
- Automated simultaneous measurement of the δ13C and δ2H values of methane and the δ13C and δ18O values of carbon dioxide in flask air samples using a new multi cryo‐trap/gas chromatography/isotope ratio mass spectrometry system W. Brand et al. 10.1002/rcm.7587
23 citations as recorded by crossref.
- Boreas: A Sample Preparation-Coupled Laser Spectrometer System for Simultaneous High-Precision In Situ Analysis of δ13C and δ2H from Ambient Air Methane C. Rennick et al. 10.1021/acs.analchem.1c01103
- In situ observations of greenhouse gases over Europe during the CoMet 1.0 campaign aboard the HALO aircraft M. Gałkowski et al. 10.5194/amt-14-1525-2021
- Frequency modulation laser spectroscopy method for methane isotopologue ratio and total concentration measurements at 1661 nm E. Curtis et al. 10.1364/JOSAB.482727
- Can we separate industrial CH4 emission sources from atmospheric observations? - A test case for carbon isotopes, PMF and enhanced APCA S. Assan et al. 10.1016/j.atmosenv.2018.05.004
- Characterisation of methane sources in Lutjewad, The Netherlands, using quasi-continuous isotopic composition measurements M. Menoud et al. 10.1080/16000889.2020.1823733
- Interlaboratory comparison of <i>δ</i><sup>13</sup>C and <i>δ</i>D measurements of atmospheric CH<sub>4</sub> for combined use of data sets from different laboratories T. Umezawa et al. 10.5194/amt-11-1207-2018
- An improved method for mobile characterisation of <i>δ</i><sup>13</sup>CH<sub>4</sub> source signatures and its application in Germany A. Hoheisel et al. 10.5194/amt-12-1123-2019
- Street-level methane emissions of Bucharest, Romania and the dominance of urban wastewater. J. Fernandez et al. 10.1016/j.aeaoa.2022.100153
- Methane (CH<sub>4</sub>) sources in Krakow, Poland: insights from isotope analysis M. Menoud et al. 10.5194/acp-21-13167-2021
- In situ observations of the isotopic composition of methane at the Cabauw tall tower site T. Röckmann et al. 10.5194/acp-16-10469-2016
- A Cryogen-Free Automated Measurement System of Stable Carbon Isotope Ratio of Atmospheric Methane T. Umezawa et al. 10.2151/jmsj.2020-007
- Advancing Scientific Understanding of the Global Methane Budget in Support of the Paris Agreement A. Ganesan et al. 10.1029/2018GB006065
- Determining Biogenic Content of Biogas by Measuring Stable Isotopologues 12CH4, 13CH4, and CH3D with a Mid-Infrared Direct Absorption Laser Spectrometer T. Kääriäinen et al. 10.3390/s18020496
- USGS44, a new high‐purity calcium carbonate reference material for δ13C measurements H. Qi et al. 10.1002/rcm.9006
- Advances in reference materials and measurement techniques for greenhouse gas atmospheric observations P. Brewer et al. 10.1088/1681-7575/ab1506
- Cold-Weld Sealing in Argon Atmosphere for High Precision Carbon Isotope Analysis of Co-Processed Biofuels Using a Continuous-Flow Isotope Ratio Mass Spectrometer T. Geeza et al. 10.1021/acs.energyfuels.0c02114
- Source apportionment of methane emissions from the Upper Silesian Coal Basin using isotopic signatures A. Fiehn et al. 10.5194/acp-23-15749-2023
- Six years of continuous carbon isotope composition measurements of methane in Heidelberg (Germany) – a study of source contributions and comparison to emission inventories A. Hoheisel & M. Schmidt 10.5194/acp-24-2951-2024
- CH4 isotopic signatures of emissions from oil and gas extraction sites in Romania M. Menoud et al. 10.1525/elementa.2021.00092
- A robust method for direct calibration of isotope ratios in gases against liquid/solid reference materials, including a laboratory comparison for δ13C‐CH4 P. Sperlich et al. 10.1002/rcm.8944
- Methane mapping, emission quantification, and attribution in two European cities: Utrecht (NL) and Hamburg (DE) H. Maazallahi et al. 10.5194/acp-20-14717-2020
- Atomic spectrometry update – a review of advances in environmental analysis O. Butler et al. 10.1039/C7JA90059G
- Source partitioning of atmospheric methane using stable carbon isotope measurements in the Reuss Valley, Switzerland J. Stieger et al. 10.1080/10256016.2018.1561448
Latest update: 14 Dec 2024
Short summary
Isotope measurements in atmospheric CH4 are performed since more than 3 decades. However, standard gases to harmonize global measurements are not available to this day. We designed two methods to calibrate a suite of 8 CH4 gases with a wide range in isotopic composition to the VPDB and VSMOW scales with high precision and accuracy. Synthetic air mixtures with ~2 ppm of calibrated CH4 can be provided to the community by the ISOLAB of the Max Planck Institute for Biogeochemistry in Jena, Germany.
Isotope measurements in atmospheric CH4 are performed since more than 3 decades. However,...
