Articles | Volume 9, issue 1
https://doi.org/10.5194/amt-9-41-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-41-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
15 Jan 2016
Research article |
| 15 Jan 2016
Broadband cavity-enhanced absorption spectroscopy in the ultraviolet spectral region for measurements of nitrogen dioxide and formaldehyde
R. A. Washenfelder
CORRESPONDING AUTHOR
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, 216 UCB, Boulder, CO 80309, USA
Chemical
Sciences Division, Earth System Research Laboratory, National Oceanic and
Atmospheric Administration, 325 Broadway, Boulder, CO 80305,
USA
A. R. Attwood
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, 216 UCB, Boulder, CO 80309, USA
Chemical
Sciences Division, Earth System Research Laboratory, National Oceanic and
Atmospheric Administration, 325 Broadway, Boulder, CO 80305,
USA
now at:
Horiba Scientific, Edison, New Jersey, USA
J. M. Flores
Weizmann Institute of Science, Department for Earth and
Planetary Sciences, Rehovot 76100, Israel
K. J. Zarzana
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, 216 UCB, Boulder, CO 80309, USA
Chemical
Sciences Division, Earth System Research Laboratory, National Oceanic and
Atmospheric Administration, 325 Broadway, Boulder, CO 80305,
USA
Y. Rudich
Weizmann Institute of Science, Department for Earth and
Planetary Sciences, Rehovot 76100, Israel
S. S. Brown
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, 216 UCB, Boulder, CO 80309, USA
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Cited
37 citations as recorded by crossref.
- Sensing atmospheric reactive species using light emitting diode by incoherent broadband cavity enhanced absorption spectroscopy H. Yi et al. 10.1364/OE.24.00A781
- A broadband cavity-enhanced spectrometer for atmospheric trace gas measurements and Rayleigh scattering cross sections in the cyan region (470–540 nm) N. Jordan et al. 10.5194/amt-12-1277-2019
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- Improved spherical mirror multipass-cell-based interband cascade laser spectrometer for detecting ambient formaldehyde at parts per trillion by volume levels B. Fang et al. 10.1364/AO.58.008743
- Continuous measurement of NO2 in flue gas employing cavity-enhanced spectroscopy sensing system X. Bian et al. 10.1016/j.measurement.2022.111729
- Absolute density measurement of nitrogen dioxide with cavity-enhanced laser-induced fluorescence Z. Yang et al. 10.1088/1674-1056/27/10/100601
- Monitoring Ambient Nitrate Radical by Open-Path Cavity-Enhanced Absorption Spectroscopy H. Wang & K. Lu 10.1021/acs.analchem.9b01971
- Development of a portable cavity-enhanced absorption spectrometer for the measurement of ambient NO<sub>3</sub> and N<sub>2</sub>O<sub>5</sub>: experimental setup, lab characterizations, and field applications in a polluted urban environment H. Wang et al. 10.5194/amt-10-1465-2017
- Evolution of the Complex Refractive Index of Secondary Organic Aerosols during Atmospheric Aging Q. He et al. 10.1021/acs.est.7b05742
- Broadband near-ultraviolet dual comb spectroscopy L. Fürst et al. 10.1364/OPTICA.516783
- A mini broadband cavity enhanced absorption spectrometer for nitrogen dioxide measurement on the unmanned aerial vehicle platform Z. Zheng et al. 10.1016/j.atmosenv.2024.120361
- Gas-phase broadband spectroscopy using active sources: progress, status, and applications [Invited] K. Cossel et al. 10.1364/JOSAB.34.000104
- Optical Properties of Secondary Organic Aerosol Produced by Nitrate Radical Oxidation of Biogenic Volatile Organic Compounds Q. He et al. 10.1021/acs.est.0c06838
- Sources of Formaldehyde in Bountiful, Utah N. Bhardwaj et al. 10.3390/atmos12030375
- Ultraviolet refractive index values of organic aerosol extracted from deciduous forestry, urban and marine environments C. Barker et al. 10.1039/D3EA00005B
- Ozone Detection via Deep-Ultraviolet Cavity-Enhanced Absorption Spectroscopy with a Laser Driven Light Source A. Puga & A. Yalin 10.3390/s23114989
- Scattering and absorption cross sections of atmospheric gases in the ultraviolet–visible wavelength range (307–725 nm) Q. He et al. 10.5194/acp-21-14927-2021
- A review of experimental techniques for aerosol hygroscopicity studies M. Tang et al. 10.5194/acp-19-12631-2019
- A new laser-based and ultra-portable gas sensor for indoor and outdoor formaldehyde (HCHO) monitoring J. Shutter et al. 10.5194/amt-12-6079-2019
- Comparison of formaldehyde measurements by Hantzsch, CRDS and DOAS in the SAPHIR chamber M. Glowania et al. 10.5194/amt-14-4239-2021
- Non-Dispersive Ultra-Violet Spectroscopic Detection of Formaldehyde Gas for Indoor Environments J. Davenport et al. 10.1109/JSEN.2018.2795042
- Absorption cross-sections for the 5th and 6th vibrational overtones in a series of short chained alcohols using incoherent broadband cavity enhanced-absorption spectroscopy (IBBCEAS) C. Flowerday et al. 10.1016/j.jms.2023.111746
- A Demonstration of Broadband Cavity-Enhanced Absorption Spectroscopy at Deep-Ultraviolet Wavelengths: Application to Sensitive Real-Time Detection of the Aromatic Pollutants Benzene, Toluene, and Xylene M. Wang et al. 10.1021/acs.analchem.1c04940
- A new approach for retrieving the UV–vis optical properties of ambient aerosols N. Bluvshtein et al. 10.5194/amt-9-3477-2016
- Laboratory Performance Evaluation of a Low-Cost Electrochemical Formaldehyde Sensor Z. Pei et al. 10.3390/s23177444
- Complex refractive indices in the ultraviolet and visible spectral region for highly absorbing non-spherical biomass burning aerosol C. Womack et al. 10.5194/acp-21-7235-2021
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- A new non-resonant laser-induced fluorescence instrument for the airborne in situ measurement of formaldehyde J. St. Clair et al. 10.5194/amt-10-4833-2017
- Detection of Sulfur Dioxide by Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) R. Thalman et al. 10.3390/s22072626
- Intercomparison of IBBCEAS, NitroMAC and FTIR analyses for HONO, NO<sub>2</sub> and CH<sub>2</sub>O measurements during the reaction of NO<sub>2</sub> with H<sub>2</sub>O vapour in the simulation chamber CESAM H. Yi et al. 10.5194/amt-14-5701-2021
- Separation-dependent near-field effects in Mie scattering spectra of two optically trapped aerosol droplets C. Barker et al. 10.1364/OE.520251
- Sensitive Detection of Ambient Formaldehyde by Incoherent Broadband Cavity Enhanced Absorption Spectroscopy J. Liu et al. 10.1021/acs.analchem.9b04821
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO<sub>2</sub>, RO<sub>2</sub>NO<sub>2</sub>, and RONO<sub>2</sub> in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- NO<sub>2</sub> gas detection based on standard sample regression algorithm and cavity enhanced spectroscopy X. Bian et al. 10.7498/aps.70.20201322
- Incoherent broad-band cavity enhanced absorption spectroscopy for sensitive and rapid molecular iodine detection in the presence of aerosols and water vapour C. Bahrini et al. 10.1016/j.optlastec.2018.06.050
- Intercomparison of NO3 under Humid Conditions with Open-Path and Extractive IBBCEAS in an Atmospheric Reaction Chamber M. Wang et al. 10.3390/rs15030739
37 citations as recorded by crossref.
- Sensing atmospheric reactive species using light emitting diode by incoherent broadband cavity enhanced absorption spectroscopy H. Yi et al. 10.1364/OE.24.00A781
- A broadband cavity-enhanced spectrometer for atmospheric trace gas measurements and Rayleigh scattering cross sections in the cyan region (470–540 nm) N. Jordan et al. 10.5194/amt-12-1277-2019
- 腔增强吸收光谱技术研究与应用进展（特邀） 超. CHAO Xing et al. 10.3788/gzxb20235203.0352102
- Improved spherical mirror multipass-cell-based interband cascade laser spectrometer for detecting ambient formaldehyde at parts per trillion by volume levels B. Fang et al. 10.1364/AO.58.008743
- Continuous measurement of NO2 in flue gas employing cavity-enhanced spectroscopy sensing system X. Bian et al. 10.1016/j.measurement.2022.111729
- Absolute density measurement of nitrogen dioxide with cavity-enhanced laser-induced fluorescence Z. Yang et al. 10.1088/1674-1056/27/10/100601
- Monitoring Ambient Nitrate Radical by Open-Path Cavity-Enhanced Absorption Spectroscopy H. Wang & K. Lu 10.1021/acs.analchem.9b01971
- Development of a portable cavity-enhanced absorption spectrometer for the measurement of ambient NO<sub>3</sub> and N<sub>2</sub>O<sub>5</sub>: experimental setup, lab characterizations, and field applications in a polluted urban environment H. Wang et al. 10.5194/amt-10-1465-2017
- Evolution of the Complex Refractive Index of Secondary Organic Aerosols during Atmospheric Aging Q. He et al. 10.1021/acs.est.7b05742
- Broadband near-ultraviolet dual comb spectroscopy L. Fürst et al. 10.1364/OPTICA.516783
- A mini broadband cavity enhanced absorption spectrometer for nitrogen dioxide measurement on the unmanned aerial vehicle platform Z. Zheng et al. 10.1016/j.atmosenv.2024.120361
- Gas-phase broadband spectroscopy using active sources: progress, status, and applications [Invited] K. Cossel et al. 10.1364/JOSAB.34.000104
- Optical Properties of Secondary Organic Aerosol Produced by Nitrate Radical Oxidation of Biogenic Volatile Organic Compounds Q. He et al. 10.1021/acs.est.0c06838
- Sources of Formaldehyde in Bountiful, Utah N. Bhardwaj et al. 10.3390/atmos12030375
- Ultraviolet refractive index values of organic aerosol extracted from deciduous forestry, urban and marine environments C. Barker et al. 10.1039/D3EA00005B
- Ozone Detection via Deep-Ultraviolet Cavity-Enhanced Absorption Spectroscopy with a Laser Driven Light Source A. Puga & A. Yalin 10.3390/s23114989
- Scattering and absorption cross sections of atmospheric gases in the ultraviolet–visible wavelength range (307–725 nm) Q. He et al. 10.5194/acp-21-14927-2021
- A review of experimental techniques for aerosol hygroscopicity studies M. Tang et al. 10.5194/acp-19-12631-2019
- A new laser-based and ultra-portable gas sensor for indoor and outdoor formaldehyde (HCHO) monitoring J. Shutter et al. 10.5194/amt-12-6079-2019
- Comparison of formaldehyde measurements by Hantzsch, CRDS and DOAS in the SAPHIR chamber M. Glowania et al. 10.5194/amt-14-4239-2021
- Non-Dispersive Ultra-Violet Spectroscopic Detection of Formaldehyde Gas for Indoor Environments J. Davenport et al. 10.1109/JSEN.2018.2795042
- Absorption cross-sections for the 5th and 6th vibrational overtones in a series of short chained alcohols using incoherent broadband cavity enhanced-absorption spectroscopy (IBBCEAS) C. Flowerday et al. 10.1016/j.jms.2023.111746
- A Demonstration of Broadband Cavity-Enhanced Absorption Spectroscopy at Deep-Ultraviolet Wavelengths: Application to Sensitive Real-Time Detection of the Aromatic Pollutants Benzene, Toluene, and Xylene M. Wang et al. 10.1021/acs.analchem.1c04940
- A new approach for retrieving the UV–vis optical properties of ambient aerosols N. Bluvshtein et al. 10.5194/amt-9-3477-2016
- Laboratory Performance Evaluation of a Low-Cost Electrochemical Formaldehyde Sensor Z. Pei et al. 10.3390/s23177444
- Complex refractive indices in the ultraviolet and visible spectral region for highly absorbing non-spherical biomass burning aerosol C. Womack et al. 10.5194/acp-21-7235-2021
- Time-Resolved Broadband Cavity-Enhanced Absorption Spectroscopy behind Shock Waves A. Matsugi et al. 10.1021/acs.jpca.6b01069
- CAFE: a new, improved nonresonant laser-induced fluorescence instrument for airborne in situ measurement of formaldehyde J. St. Clair et al. 10.5194/amt-12-4581-2019
- A new non-resonant laser-induced fluorescence instrument for the airborne in situ measurement of formaldehyde J. St. Clair et al. 10.5194/amt-10-4833-2017
- Detection of Sulfur Dioxide by Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) R. Thalman et al. 10.3390/s22072626
- Intercomparison of IBBCEAS, NitroMAC and FTIR analyses for HONO, NO<sub>2</sub> and CH<sub>2</sub>O measurements during the reaction of NO<sub>2</sub> with H<sub>2</sub>O vapour in the simulation chamber CESAM H. Yi et al. 10.5194/amt-14-5701-2021
- Separation-dependent near-field effects in Mie scattering spectra of two optically trapped aerosol droplets C. Barker et al. 10.1364/OE.520251
- Sensitive Detection of Ambient Formaldehyde by Incoherent Broadband Cavity Enhanced Absorption Spectroscopy J. Liu et al. 10.1021/acs.analchem.9b04821
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO<sub>2</sub>, RO<sub>2</sub>NO<sub>2</sub>, and RONO<sub>2</sub> in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- NO<sub>2</sub> gas detection based on standard sample regression algorithm and cavity enhanced spectroscopy X. Bian et al. 10.7498/aps.70.20201322
- Incoherent broad-band cavity enhanced absorption spectroscopy for sensitive and rapid molecular iodine detection in the presence of aerosols and water vapour C. Bahrini et al. 10.1016/j.optlastec.2018.06.050
- Intercomparison of NO3 under Humid Conditions with Open-Path and Extractive IBBCEAS in an Atmospheric Reaction Chamber M. Wang et al. 10.3390/rs15030739
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Short summary
Formaldehyde is the most abundant aldehyde in the atmosphere and plays an important role in photochemistry. Broadband cavity-enhanced absorption spectroscopy uses a high finesse cavity to obtain effective path lengths of kilometers. We use a diode-pumped plasma lamp and custom cavity mirrors to extend this technique further into the ultraviolet spectral region, and we achieve detection limits of hundreds of parts per trillion in 1 min for formaldehyde and nitrogen dioxide.
Formaldehyde is the most abundant aldehyde in the atmosphere and plays an important role in...
