Articles | Volume 11, issue 1
https://doi.org/10.5194/amt-11-1-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-1-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
03 Jan 2018
Research article |
| 03 Jan 2018
| 03 Jan 2018
Measurements of a potential interference with laser-induced fluorescence measurements of ambient OH from the ozonolysis of biogenic alkenes
Pamela Rickly
School of Public and Environmental Affairs, Indiana, University,
Bloomington, IN, USA
School of Public and Environmental Affairs, Indiana, University,
Bloomington, IN, USA
Department of Chemistry, Indiana University, Bloomington, IN, USA
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31 citations as recorded by crossref.
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- Reconciling Observed and Predicted Tropical Rainforest OH Concentrations D. Jeong et al. https://doi.org/10.1029/2020JD032901
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- Simple and sensitive determination of hydroxyl radical in atmosphere based on an electrochemically activated glassy carbon electrode T. Wang et al. https://doi.org/10.1080/03067319.2018.1478968
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- Hydroxyl radical as an indoor oxidant C. Weschler & W. Nazaroff https://doi.org/10.1039/D6EA00074F
- Measurements and model comparisons suggest that HONO is not an important source of OH radical concentrations below a rural forest canopy B. Hoover et al. https://doi.org/10.1039/D5EA00122F
- Radical-induced autoxidation dominates squalene oxidative aging under environmental conditions X. Wang et al. https://doi.org/10.1126/sciadv.aei2144
- ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments? C. Fittschen et al. https://doi.org/10.5194/acp-19-349-2019
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- Intercomparison of OH radical measurement in a complex atmosphere in Chengdu, China G. Zhang et al. https://doi.org/10.1016/j.scitotenv.2022.155924
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31 citations as recorded by crossref.
- Characterization of a chemical modulation reactor (CMR) for the measurement of atmospheric concentrations of hydroxyl radicals with a laser-induced fluorescence instrument C. Cho et al. https://doi.org/10.5194/amt-14-1851-2021
- The reaction of peroxy radicals with OH radicals C. Fittschen https://doi.org/10.1016/j.cplett.2019.04.002
- Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere B. Bottorff et al. https://doi.org/10.5194/amt-14-6039-2021
- Re-assessing hydroxyl radical chemistry in the atmosphere: Instrument interferences may explain previous measurement discrepancies P. Price et al. https://doi.org/10.1038/s43247-025-02308-y
- 中红外波长调制离轴积分腔输出光谱技术应用于OH自由基高灵敏度探测研究 杨. YANG Nana et al. https://doi.org/10.3788/gzxb20235203.0352123
- Measurements of Hydroxyl Radical Concentrations during Indoor Cooking Events: Evidence of an Unmeasured Photolytic Source of Radicals E. Reidy et al. https://doi.org/10.1021/acs.est.2c05756
- High power ultrafast phase-locked laser at 2060 nm from a doubly resonant optical parametric oscillator H. Rao et al. https://doi.org/10.1038/s41598-026-40002-x
- Design of an ultra-compact As2Se3 waveguide for enhanced optical frequency comb generation M. Pournaghdi et al. https://doi.org/10.1007/s11082-025-08117-z
- Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR H. Fuchs et al. https://doi.org/10.5194/acp-18-8001-2018
- Wintertime photochemistry in Beijing: observations of ROx radical concentrations in the North China Plain during the BEST-ONE campaign Z. Tan et al. https://doi.org/10.5194/acp-18-12391-2018
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. https://doi.org/10.5194/amt-13-3119-2020
- OH and HO2 radical chemistry in a midlatitude forest: measurements and model comparisons M. Lew et al. https://doi.org/10.5194/acp-20-9209-2020
- Improved laser-induced fluorescence instrument via chemical modulation for OH radical measurement: High-sensitivity detection and interference evaluation H. Cai et al. https://doi.org/10.1016/j.snb.2025.139418
- Reconciling Observed and Predicted Tropical Rainforest OH Concentrations D. Jeong et al. https://doi.org/10.1029/2020JD032901
- Investigation of Isoprene Dynamics During the Day‐to‐Night Transition Period D. Wei et al. https://doi.org/10.1029/2020JD032784
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. https://doi.org/10.5194/acp-20-3333-2020
- Temperature-dependent kinetics of the atmospheric reaction between CH2OO and acetone P. Wang et al. https://doi.org/10.1039/D2CP01118B
- All-SBS fiber-based setup for optical frequency comb generation utilizing a pump recycling technique and comb line isolation by implementing Brillouin amplification A. Paul & P. Krishnamurthy https://doi.org/10.1364/AO.470532
- Simple and sensitive determination of hydroxyl radical in atmosphere based on an electrochemically activated glassy carbon electrode T. Wang et al. https://doi.org/10.1080/03067319.2018.1478968
- 大气HOx自由基光谱学探测技术进展（特邀） 胡. Hu Renzhi et al. https://doi.org/10.3788/AOS252006
- Evaluation of OH and HO2 concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR A. Novelli et al. https://doi.org/10.5194/acp-18-11409-2018
- Development of a Solid-Phase Microextraction-Surface-Enhanced Raman Scattering Approach to Detect Ferbam S. Wang et al. https://doi.org/10.1088/1757-899X/472/1/012056
- Hydroxyl radical as an indoor oxidant C. Weschler & W. Nazaroff https://doi.org/10.1039/D6EA00074F
- Measurements and model comparisons suggest that HONO is not an important source of OH radical concentrations below a rural forest canopy B. Hoover et al. https://doi.org/10.1039/D5EA00122F
- Radical-induced autoxidation dominates squalene oxidative aging under environmental conditions X. Wang et al. https://doi.org/10.1126/sciadv.aei2144
- ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments? C. Fittschen et al. https://doi.org/10.5194/acp-19-349-2019
- OH and HO2 radical chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 X. Ma et al. https://doi.org/10.5194/acp-22-7005-2022
- Quantitative study on the interference of OH radicalmeasurement in the air pollution complex X. Ma et al. https://doi.org/10.1360/TB-2022-0581
- Ultra-stable erbium-doped fiber optical frequency comb with relative frequency satbility on the order of 10<sup>–21 </sup>within 10000-second timescale J. MA et al. https://doi.org/10.7498/aps.75.20251560
- Intercomparison of OH radical measurement in a complex atmosphere in Chengdu, China G. Zhang et al. https://doi.org/10.1016/j.scitotenv.2022.155924
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. https://doi.org/10.5194/acp-23-10287-2023
Saved (final revised paper)
Latest update: 02 Nov 2026
Short summary
The hydroxyl radical is the primary atmospheric oxidant in the atmosphere, and measurements of its concentration provide a rigorous test of our understanding of atmospheric chemistry. This paper presents measurements of a potential interference with measurements of OH using laser-induced fluorescence techniques, which may contribute to measurements of OH in forested environments. The results may help to explain discrepancies between measurements and model predictions in these environments.
The hydroxyl radical is the primary atmospheric oxidant in the atmosphere, and measurements of...
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